An experimental study of the performance of a low-cost paper-based membraneless direct hydrogen peroxide fuel cell

Year 2022, , 161 - 165, 15.04.2022

Muhammet Çelik

https://doi.org/10.31127/tuje.891626

Cited By: 6

Abstract

A paper-based membraneless direct hydrogen peroxide fuel cell was developed and tested under different potassium hydroxide concentrations (1 to 7 mol lt-1, stepping by 2), different hydrogen peroxide concentrations (1, 2, 3 mol lt-1) and different temperatures (20, 30, 40oC). Moreover, the developed fuel cell was studied for stability under stopped and continuous flow conditions. From the experiments, it was found that the maximum power density of 6.79 mW cm-2 and the maximum open circuit voltage of 0.87 V at 40oC were obtained when the anode solution consisted 2 mol lt-1 H2O2 and 5 mol lt-1 potassium hydroxide and cathode solution consisted 2 mol lt-1 sulfuric acid and 2 mol lt-1 hydrogen peroxide. It was found that if the reactants were supplied constantly into the fuel cell, a current density of 3.12 mA cm-2 was obtained. The developed fuel cell produced energy for 91 minutes when the reactant flow was stopped.

Keywords

Hydrogen Peroxide Fuel Cell, DHPFC, Fuel Cell Performance, Membraneless Fuel Cell, Paper-based Fuel Cell

References

• Arun R K, Halder S, Chanda N & Chakraborty S (2014). A paper based self-pumping and self-breathing fuel cell using pencil stroked graphite electrodes. Lab on a Chip, 14(10), 1661-1664.
• Bandodkar A J, Jia W, Wang J (2015). Tattoo-Based Wearable Electrochemical Devices: A Review. Electroanalysis. 27, 562–572.
• Chino I, Muneeb O, Do E, Ho V & Haan J L (2018). A paper microfluidic fuel cell powered by urea. Journal of Power Sources, 396, 710-714.
• Copenhaver T S, Purohit K H, Domalaon K, Pham L, Burgess B J, Manorothkul N, ... & Haan J L (2015). A microfluidic direct formate fuel cell on paper. Electrophoresis, 36(16), 1825-1829.
• Dector A, Galindo-De-La-Rosa J, Amaya-Cruz D M, Ortíz-Verdín A, Guerra-Balcázar M, Olivares-Ramírez J M, ... & Ledesma-García J (2017). Towards autonomous lateral flow assays: Paper-based microfluidic fuel cell inside an HIV-test using a blood sample as fuel. International Journal of Hydrogen Energy, 42(46), 27979-27986.
• Ehteshami S M M, Asadnia M, Tan S N & Chan S H (2016). Paper-based membraneless hydrogen peroxide fuel cell prepared by micro-fabrication. Journal of Power Sources, 301, 392-395.
• Esquivel J P, Del Campo F J, De La Fuente J G, Rojas S & Sabate N (2014). Microfluidic fuel cells on paper: meeting the power needs of next generation lateral flow devices. Energy & Environmental Science, 7(5), 1744-1749.
• González-Guerrero M J, Del Campo F J, Esquivel J P, Leech D & Sabaté N (2017). based microfluidic biofuel cell operating under glucose concentrations within physiological range. Biosensors and Bioelectronics, 90, 475-480.
• Guo F, Cao D, Du M, Ye K, Wang G, Zhang W, ... & Cheng K (2016). Enhancement of direct urea-hydrogen peroxide fuel cell performance by three-dimensional porous nickel-cobalt anode. Journal of Power Sources, 307, 697-704.
• Hasegawa S, Shimotani K, Kishi K & Watanabe H (2004). Electricity generation from decomposition of hydrogen peroxide. Electrochemical and Solid State Letters, 8(2), A119.
• Han L, Guo S, Wang P & Dong S (2015). Light‐Driven, Membraneless, Hydrogen Peroxide Based Fuel Cells. Advanced Energy Materials, 5(2), 1400424.
• Jung D G & Ahn Y (2020). Microfabricated paper-based vanadium co-laminar flow fuel cell. Journal of Power Sources, 451, 227801.
• Lu X, Yu M, Wang G, Tong Y & Li Y (2014). Flexible solid-state supercapacitors: design, fabrication and applications. Energy & Environmental Science, 7(7), 2160-2181.
• Rathoure A K & Pramanik H (2016). Electrooxidation study of methanol using H2O2 and air as mixed oxidant at cathode in air breathing microfluidic fuel cell. International Journal of Hydrogen Energy, 41(34), 15287-15294.
• Shaegh S A M, Ehteshami S M M, Chan S H, Nguyen N T & Tan S N (2014). Membraneless hydrogen peroxide micro semi-fuel cell for portable applications. RSC advances, 4(70), 37284-37287.
• Shen L L, Zhang G R, Venter T, Biesalski M & Etzold B J (2019). Towards best practices for improving paper-based microfluidic fuel cells. Electrochimica Acta, 298, 389-399.
• Shitanda I, Nohara S, Hoshi Y, Itagaki M & Tsujimura S (2017). A screen-printed circular-type paper-based glucose/O2 biofuel cell. Journal of Power Sources, 360, 516-519.
• Shyu J C, Huang C L, Sheu T S & Ay H (2012). Experimental study of direct hydrogen peroxide microfluidic fuel cells. Micro & Nano Letters, 7(8), 740-743.
• Valdés-Ramírez G, Li Y C, Kim J, Jia W, Bandodkar A J, Nuñez-Flores R, ... & Wang J (2014). Microneedle-based self-powered glucose sensor. Electrochemistry Communications, 47, 58-62.
• Yamada Y, Fukunishi Y, Yamazaki S I & Fukuzumi S (2010). Hydrogen peroxide as sustainable fuel: electrocatalysts for production with a solar cell and decomposition with a fuel cell. Chemical communications, 46(39), 7334-7336.
• Yamazaki S I, Siroma Z, Senoh H, Ioroi T, Fujiwara N & Yasuda K (2008). A fuel cell with selective electrocatalysts using hydrogen peroxide as both an electron acceptor and a fuel. Journal of Power Sources, 178(1), 20-25.
• Yan X, Xu A, Zeng L, Gao P & Zhao T (2018). A paper‐based microfluidic fuel cell with hydrogen peroxide as fuel and oxidant. Energy Technology, 6(1), 140-143.
• Yang F, Cheng K, Mo Y, Yu L, Yin J, Wang G & Cao D (2012). Direct peroxide–peroxide fuel cell–Part 1: The anode and cathode catalyst of carbon fiber cloth supported dendritic Pd. Journal of Power Sources, 217, 562-568.
• Yang F, Cheng K, Liu X, Chang S, Yin J, Du C, ... & Cao D (2012). Direct peroxide–peroxide fuel cell–Part 2: Effects of conditions on the performance. Journal of Power Sources, 217, 569-573.
• Yang Y, Xue Y, Zhang H & Chang H (2019). Flexible H2O2 microfluidic fuel cell using graphene/Prussian blue catalyst for high performance. Chemical Engineering Journal, 369, 813-817.
• Ye K, Guo F, Gao Y, Zhang D, Cheng K, Zhang W, ... & Cao D (2015). Three-dimensional carbon-and binder-free nickel nanowire arrays as a high-performance and low-cost anode for direct hydrogen peroxide fuel cell. Journal of Power Sources, 300, 147-156.
• Zhang L, Zhou M, Wen D, Bai L, Lou B & Dong S (2012). Small-size biofuel cell on paper. Biosensors and Bioelectronics, 35(1), 155-159.
• Zhang Q, Yue F, Xu L, Yao C, Priestley R D & Hou S (2019). Paper based porous graphene/single-walled carbon nanotubes supported Pt nanoparticles as freestanding catalyst for electro-oxidation of methanol. Applied Catalysis B: Environmental, 257, 117886.