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Year 2018, Volume: 2 Issue: 3, 107 - 112, 01.09.2018
https://doi.org/10.31127/tuje.395259

Abstract

References

  • Abedin, M. R., Abedin, S., Mahbub, H. A., Nandini, D., Khan, M. S. (2017). “A Hydrometallurgical Approach to Recover Zinc and Manganese from Spent Zn-C Batteries", Materials Science Forum, Vol. 886, pp. 117-121.
  • Baba, A. A., Adekola, A. F., Bale, R. B. (2009). “Development of a combined pyro– and hydro–metallurgical route to treat spent zinc–carbon batteries. Journal of Hazardous Mat., Vol. 171, pp. 838–844.
  • Bernardes, A. M., Espınosa, D. C. R., Tenorıo J. A. S. (2004). “Recycling of batteries: a review of current processes and Technologies” Journal of Power Sources, Vol. 130, pp.291–298.
  • Buzatu, M., Saceanu, S., Petrescu, M. I., Ghica, G. V., Buzatu, T. (2014). “Recovery of zinc and manganese from spent batteries by reductive leaching in acidic media” Journal of Power Sources, Vol. 247, pp. 612–617.
  • Chen, W. S., Chin, T.L., Kuan, Y. L. (2017). “Recovery Zinc and Manganese from Spent Battery Powder by Hydrometallurgical Route” Energy Procedia, Vol. 107, pp. 167–174.
  • Ferella, F., DeMichelis, I., Veglio, F. (2008). “Process for the recycling of alkaline and zinc–carbon spent batteries” Journal of Power Sources, Vol.183, 805–811.
  • Gęga, J., Walkowiak, W. (2011). “Leaching of zinc and manganese from used up zinc–carbon batteries using aqueous sulfuric acid solutions” Physicochem. Probl. Miner. Process., Vol. 46, pp. 155–162.
  • Habashi, F. (1969). Principles of extractive metallurgy New York: Gordon and Breach.
  • Kursunoglu, S, Kaya, M. (2014). “Dissolution and precipitation of zinc and manganese obtained from spent zinc–carbon and alkaline battery powder” Physicochem. Prob. Miner. Process., Vol. 50, No.1, pp. 41–55.
  • Levenspiel, O. (1999). Chemical reaction engineering, New York: John Wiley & Sons.
  • Park, J., Kang, J., Sohn, J., Yang, D., Shin, S. (2006). “Physical treatment for recycling commercialization of spent household batteries” J. Korean Inst. Resour. Recycl., Vol:15 No:6, pp. 48–55.
  • Sayilgan, E., Kukrer, T., Yigit, N. O., Civelekoglu, G., Kitis, M. (2010). “Acidic leaching and precipitation of zinc and manganese from spent battery powders using various reductants” J. Hazard. Mater., Vol. 173, pp.137–143.
  • Shin, S., Senanayake, G., Sohn J., Park, J., Kang, J., Yang D., Kim T. (2009). “Separation of zinc from spent zinc–carbon batteries by selective leaching with sodium hydroxide”, Hydrometallurgy, Vol. 96, pp. 349–353.
  • Sohn, H. Y., Wadsworth, M. E. (1986). Cr'nética de los procesos de la Metalurgia Extractiva (translated from English Version). Ed. Trillas, Mexico.
  • Takeno, N., (2005) “Atlas of Eh-pH diagrams Intercomparison of thermodynamic databases”, National Institute of Advanced Industrial Science and Technology, Japan.
  • Taner, H. A., Aras, A., Agacayak, T. (2016). “Determination of dissolution kinetics of manganese and zinc from spent zinc–carbon batteries in acidic media” 1. International Academic Research Congress, Ines 2016, Anyalya/Side/ Turkey, pp. 379-383.

INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION

Year 2018, Volume: 2 Issue: 3, 107 - 112, 01.09.2018
https://doi.org/10.31127/tuje.395259

Abstract

The aim of this study is to examine the dissolution kinetics of zinc and manganese from spent zinc-carbon battery in sulphuric acid solution. The leaching experiments were carried under the following conditions: leaching temperatures of 30°C, 40°C and 50°C; sulphuric acid concentration of 0.5 M; stirring speed of 400 rpm; solid/liquid ratio of 5/500 g/mL and particle size of -53 µm. In these conditions, while all of the zinc was dissolved, about 69 % of manganese was dissolved. To determine the kinetics of dissolution of the zinc and manganese in sulphuric acid medium, different shrinking core models were applied to the dissolution recoveries obtained at variable temperatures. Kinetics analysis showed that the zinc and manganese dissolution from spent zinc-carbon battery could be described by diffusion from product layer. The activation energies (Ea) and Arrhenius constants for the dissolution reactions were calculated. Activation energies (Ea) were determined for Zn and Mn as 94.53 kJ/mol and 1.41 kJ/mol, respectively.

References

  • Abedin, M. R., Abedin, S., Mahbub, H. A., Nandini, D., Khan, M. S. (2017). “A Hydrometallurgical Approach to Recover Zinc and Manganese from Spent Zn-C Batteries", Materials Science Forum, Vol. 886, pp. 117-121.
  • Baba, A. A., Adekola, A. F., Bale, R. B. (2009). “Development of a combined pyro– and hydro–metallurgical route to treat spent zinc–carbon batteries. Journal of Hazardous Mat., Vol. 171, pp. 838–844.
  • Bernardes, A. M., Espınosa, D. C. R., Tenorıo J. A. S. (2004). “Recycling of batteries: a review of current processes and Technologies” Journal of Power Sources, Vol. 130, pp.291–298.
  • Buzatu, M., Saceanu, S., Petrescu, M. I., Ghica, G. V., Buzatu, T. (2014). “Recovery of zinc and manganese from spent batteries by reductive leaching in acidic media” Journal of Power Sources, Vol. 247, pp. 612–617.
  • Chen, W. S., Chin, T.L., Kuan, Y. L. (2017). “Recovery Zinc and Manganese from Spent Battery Powder by Hydrometallurgical Route” Energy Procedia, Vol. 107, pp. 167–174.
  • Ferella, F., DeMichelis, I., Veglio, F. (2008). “Process for the recycling of alkaline and zinc–carbon spent batteries” Journal of Power Sources, Vol.183, 805–811.
  • Gęga, J., Walkowiak, W. (2011). “Leaching of zinc and manganese from used up zinc–carbon batteries using aqueous sulfuric acid solutions” Physicochem. Probl. Miner. Process., Vol. 46, pp. 155–162.
  • Habashi, F. (1969). Principles of extractive metallurgy New York: Gordon and Breach.
  • Kursunoglu, S, Kaya, M. (2014). “Dissolution and precipitation of zinc and manganese obtained from spent zinc–carbon and alkaline battery powder” Physicochem. Prob. Miner. Process., Vol. 50, No.1, pp. 41–55.
  • Levenspiel, O. (1999). Chemical reaction engineering, New York: John Wiley & Sons.
  • Park, J., Kang, J., Sohn, J., Yang, D., Shin, S. (2006). “Physical treatment for recycling commercialization of spent household batteries” J. Korean Inst. Resour. Recycl., Vol:15 No:6, pp. 48–55.
  • Sayilgan, E., Kukrer, T., Yigit, N. O., Civelekoglu, G., Kitis, M. (2010). “Acidic leaching and precipitation of zinc and manganese from spent battery powders using various reductants” J. Hazard. Mater., Vol. 173, pp.137–143.
  • Shin, S., Senanayake, G., Sohn J., Park, J., Kang, J., Yang D., Kim T. (2009). “Separation of zinc from spent zinc–carbon batteries by selective leaching with sodium hydroxide”, Hydrometallurgy, Vol. 96, pp. 349–353.
  • Sohn, H. Y., Wadsworth, M. E. (1986). Cr'nética de los procesos de la Metalurgia Extractiva (translated from English Version). Ed. Trillas, Mexico.
  • Takeno, N., (2005) “Atlas of Eh-pH diagrams Intercomparison of thermodynamic databases”, National Institute of Advanced Industrial Science and Technology, Japan.
  • Taner, H. A., Aras, A., Agacayak, T. (2016). “Determination of dissolution kinetics of manganese and zinc from spent zinc–carbon batteries in acidic media” 1. International Academic Research Congress, Ines 2016, Anyalya/Side/ Turkey, pp. 379-383.
There are 16 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Tevfik Ağaçayak 0000-0001-8120-8804

Ali Aras 0000-0001-8111-6176

Publication Date September 1, 2018
Published in Issue Year 2018 Volume: 2 Issue: 3

Cite

APA Ağaçayak, T., & Aras, A. (2018). INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION. Turkish Journal of Engineering, 2(3), 107-112. https://doi.org/10.31127/tuje.395259
AMA Ağaçayak T, Aras A. INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION. TUJE. September 2018;2(3):107-112. doi:10.31127/tuje.395259
Chicago Ağaçayak, Tevfik, and Ali Aras. “INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION”. Turkish Journal of Engineering 2, no. 3 (September 2018): 107-12. https://doi.org/10.31127/tuje.395259.
EndNote Ağaçayak T, Aras A (September 1, 2018) INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION. Turkish Journal of Engineering 2 3 107–112.
IEEE T. Ağaçayak and A. Aras, “INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION”, TUJE, vol. 2, no. 3, pp. 107–112, 2018, doi: 10.31127/tuje.395259.
ISNAD Ağaçayak, Tevfik - Aras, Ali. “INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION”. Turkish Journal of Engineering 2/3 (September 2018), 107-112. https://doi.org/10.31127/tuje.395259.
JAMA Ağaçayak T, Aras A. INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION. TUJE. 2018;2:107–112.
MLA Ağaçayak, Tevfik and Ali Aras. “INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION”. Turkish Journal of Engineering, vol. 2, no. 3, 2018, pp. 107-12, doi:10.31127/tuje.395259.
Vancouver Ağaçayak T, Aras A. INVESTIGATION OF DISSOLUTION KINETICS OF Zn AND Mn FROM SPENT ZINC-CARBON BATTERIES IN SULPHURIC ACID SOLUTION. TUJE. 2018;2(3):107-12.
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