Electroanalytical characterization of chloroquinoline substituted redox-active phthalocyanines

Year 2023, , 25 - 31, 30.06.2023

Asiye Nas , Gülsev Dilber , Zekeriya Bıyıklıoğlu

https://doi.org/10.51435/turkjac.1307391

Cited By: 1

Abstract

In the first part of this study, the synthesis and characterization of organosoluble 5-chloroquinolin-8-yloxy substituted iron(II) (2) and oxo-titanium (IV) phthalocyanines (3) are reported for the first time. These compounds have been characterized by elemental analysis, Fourier transform infrared, electronic spectroscopy, and mass spectra. Electrochemical behaviors of metal-free and cobalt phthalocyanines and further new types of iron and oxo-titanium phthalocyanines were investigated using electroanalytical methods, such as cyclic (CV) and square wave voltammetry (SWV). According to the electrochemical results, phthalocyanines by and large showed one-electron metal- and/or ligand-based reversible or quasi-reversible reduction and oxidation processes.
All in all, this study's results inevitably create a useful way to use them in possible future studies, which will particularly attempt to use the compound investigated in potential areas of use.

Keywords

Iron, Titanium, Electrochemistry, Redox-active

Supporting Institution

KARADENİZ TEKNİK ÜNİVERSİTESİ BİLİMSEL ARAŞTIRMA FONU

Project Number

FHD-2018-7631

Thanks

This study was supported by the Karadeniz Technical University Research Fund, Project No: FHD-2018-7631 (Trabzon-Turkey).

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