Green synthesis and structural characterization of ZnO nanoparticle and ZnO@TiO2 nanocomposite by Cinnamomum verum bark extract

Year 2023, , 118 - 123, 29.12.2023

Gökçenur Selva Keleşoğlu Mesut Özdinçer Aslıhan Dalmaz Kübra Zenkin Sefa Durmuş

https://doi.org/10.51435/turkjac.1395817

Abstract

In this work, we present a facile and efficient approach for the green synthesis of ZnO@TiO2 bimetallic oxide nanoparticles by exploiting the potential of Cinnamomum verum bark extract as a biogenic reducing agent. The synthesized nanoparticles were subjected to a comprehensive characterization process comprising various spectroscopic techniques. These techniques include X-ray diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. Based on the results obtained, it highlights the potential of green-synthesized ZnO@TiO2 nanocomposite as a promising material for analytical applications.

Keywords

Cinnamomum verum, ZnO@TiO2 nanocomposite, ZnO NP, Green synthesis.

References

• 1] L. Krishnia, P. Thakur, A. Thakur, Synthesis of nanoparticles by physical route, in synthesis and applications of nanoparticles (1. Edition), 2022, Singapore: Springer Nature.
• [2] L. Soltys, O. Olkhovyy, T. Tatarchuk, M. Naushad, Green synthesis of metal and metal oxide nanoparticles: principles of green chemistry and raw materials, Magnetochem, 7, 2021, 145.
• [3] M. Jamzad, B. Mokhtari, P.S. Mirkhani, Green synthesis of metal nanoparticles mediated by a versatile medicinal plant extract, Chem Pap, 77, 2022, 1457–1467.
• [4] D. Gnanasangeetha, M. Suresh, A review on green synthesis of metal and metal oxide nanoparticles, Nat Environ Pollut Technol, 19, 2020, 1789–1800.
• [5] M.P. Nikolova, M.S. Chavali, Metal oxide nanoparticles as biomedical materials, Biomimetics, 5, 2020, 27.
• [6] J.J. Xu, W.C. Zhang, Y.W. Guo, X.Y. Chen, Y.N. Zhang, Metal nanoparticles as a promising technology in targeted cancer treatment, Drug Deliv, 29, 2022, 664–678.
• [7] P. Prasannalakshmi, N. Shanmugam, Fabrication of TiO2/ZnO nanocomposites for solar energy driven photocatalysis, Mater Sci Semicond Process, 61, 2017, 114–124.
• [8] N. Geetha, S. Sivaranjani, A. Ayeshamariam, M. Kavin Micheal, D. Saravankkumar, S. A. Fowziya, A.M Uduman Mohideen, M. Jayachandran, ZnO/TiO2 nanocomposites semiconductor for bacterial applications and dye-sensitized solar cell applications, J Adv Microsc Res,13, 2018, 3–11.
• [9] G.K. Upadhyay, J.K. Rajput, T.K. Pathak, V. Kumar, L.P. Purohit, Synthesis of ZnO:TiO2 nanocomposites for photocatalyst application in visible light, Vacuum, 160, 2019, 154–163.
• [10] M. Özdinçer, S. Durmuş, Fabrication, characterization and corrosion inhibition properties of SCW-based ZnO nanofluids, Chem Eng Commun, 2023, 1–16.
• [11] K. Akshaya, A. Rajasekar, S. Rajeshkumar, Antioxidant activity of zinc oxide nanoparticles synthesized using grape seed extract: An in vitro study, Plant Cell Biotechnol. Mol Biol, 21, 2020, 21– 29.
• [12] A. Hassanjani-Roshan, M.R. Vaezi, A. Shokuhfar, Z. Rajabali, Synthesis of iron oxide nanoparticles via sonochemical method and their characterization, Particuology, 9, 2011, 95–99.
• [13] M. Darroudi, A. Khorsand Zak, M.R. Muhamad, N.M. Huang, M. Hakimi, Green synthesis of colloidal silver nanoparticles by sonochemical method, Mater Lett, 66, 2012, 117–120.
• [14] P.V. Rao, S.H. Gan, Cinnamon: A multifaceted medicinal plant, Evid Based Complement Alternat Med, 2014, 2014.
• [15] H.H. Phu, K. Pham Van, T.H. Tran, D.T.N. Pham, Extraction, chemical compositions and biological activities of essential oils of Cinnamomum verum cultivated in Vietnam, Process, 10, 2022, 1713.
• [16] M.A. Alghuthaymi, A.M. Diab, A.F. Elzahy, K.E. Mazrou, A.A. Tayel, S.H. Moussa, Green biosynthesized selenium nanoparticles by cinnamon extract and their antimicrobial activity and application as edible coatings with nano-chitosan, J Food Qual, 2021, 2021,1–10.
• [17] X. Zhu, K. Pathakoti, H.M. Hwang, Green synthesis of titanium dioxide and zinc oxide nanoparticles and their usage for antimicrobial applications and environmental remediation, Keleşoğlu et al. Turk J Anal Chem, 5(2), 2023, 119–123
• [18] H. Özcan, A. Dalmaz, M. Özdinçer, K. Zenkin, S. Durmuş, Biosynthesis and characterization of α-FeOOH nanoparticles using Isabella grape (Vitis labrusca L.) extract, Turk J Anal Chem, 5, 2023, 43–49.
• [19] F. Mojarrad, A. Asadi, A. Abdolmaleki, S. Mirzaee, S. Zahri, Preparation of cinnamon-coated cerium oxide nanoparticles and evaluation of their anticonvulsant effect in rats, Pharm Chem J, 57, 2023, 648–655.
• [20] A. Sameen, S. Fathima, S. Ramlal, S. Kumar, F. Khanum, Nanopackaging of silver using spice extract and their characterization, Sci Technol Arts Res J, 3, 2014, 52–56.
• [21] R. Bekem, S. Durmuş, A. Dalmaz, G. Dülger, Agaricus bisporus Ekstraktı Kullanılarak ZnO Nanopartiküllerinin Yeşil Sentezi: Yapısal Karakterizasyonu ve Biyolojik Aktivitelerinin İncelenmesi, DÜBİTED, 11, 2023, 551–562.
• [22] S.N. Gençay, S. Durmuş, A. Dalmaz, G. Dülger, Ticari Bal Kullanılarak ZnO Nanopartiküllerinin Yeşil Sentezi, Yapısal Karakterizasyonu ve Biyolojik Aktivitelerinin İncelenmesi, DÜBİTED, 11, 2023, 1437–1445.
• [23] T. Bezrodna, G. Puchkovska, V. Shymanovska, J. Baran, H. Ratajczak, IR-analysis of H-bonded H2O on the pure TiO2 surface, J Mol Struct, 700, 2004, 175–181. [24] F.A. Alharthi, A.A. Alghamdi, N. Al-Zaqri, H.S. Alanazi, A.A. Alsyahi, A.E. Marghany, N. Ahmad, Facile one-pot green synthesis of Ag–ZnO nanocomposites using potato peeland their Ag concentration dependent photocatalytic properties, Sci Rep, 10, 2020, 20229.
• [25] S. Kumar, D. Arora, A. Dhupar, V. Sharma, J.K. Sharma, S.K. Sharma, A. Gaur, Structural and optical properties of polycrystalline ZnO nanopowder synthesized by direct precipitation technique, J Nano-Electron Phys, 12, 2020, 04027-1- 04027–5.
• [26] R. Nawaz, H. Ullah, A.A.J. Ghanim, M. Irfan, M. Anjum, S. Rahman, S. Ullah, Z.A. Baki, V. Kumar Oad, Green synthesis of ZnO and black TiO2 materials and their application in photodegradation of organic pollutants, ACS Omega, 8, 2023, 36076–36087.
• [27] D. Negrea, E. David, V. Malinovschi, S. Moga, C. Ducu, X-ray analysis of spent catalysts and recovered metals, Environ Eng Manag J, 9, 2010, 1235–1241.
• [28] D. Ramírez-Ortega, A.M. Meléndez, P. Acevedo-Peña, I. González, R. Arroyo, Semiconducting properties of ZnO/TiO2 composites by electrochemical measurements and their relationship with photocatalytic activity, Electrochim Acta, 140, 2014, 541–549.
• [29] A. Hossain, Y. Abdallah, M.A. Ali, M.M.I. Masum, B. Li, G. Sun, Y. Meng, Y. Weng, Q. An, Lemon-fruit-based green synthesis of zinc oxide nanoparticles and titanium dioxide nanoparticles against soft rot bacterial pathogen Dickeya dadantii, Biomol, 9, 2019, 863.
• [30] M. Zamani, M. Rostami, M. Aghajanzadeh, H. Kheiri Manjili, K. Rostamizadeh, H. Danafar, Mesoporous titanium dioxide@zinc oxide–graphene oxide nanocarriers for colon-specific drug delivery, J Mater Sci, 53, 2018, 1634–1645.