The new tetra substituted metallophthalocyanines bearing four Schiff bases on periphery: Synthesis, spectroscopic properties and investigation of the effect of various central metals on aggregation properties

Year 2020, Volume: 2 Issue: 1, 29 - 36, 23.06.2020

Halise Yalazan , Ayşe Aktaş Kamiloğlu , Halit Kantekin , Ümmühan Ocak

Abstract

In the present study, new Schiff base compound (Z)-4-((quinolin-2-ylmethyleneamino)methyl)phenol (3), its phthalonitrile derivative (Z)-4-(4-((quinolin-2-ylmethyleneamino)methyl)phenoxy)phthalonitrile (4) were synthesized in the first step. Then, zinc(II) (Pc‒5), cobalt(II) (Pc‒6) and copper(II) (Pc‒7) phthalocyanines containing Schiff base group with quinolin moiety on peripheral positions were synthesized. All new compounds were characterized by general spectroscopic techniques. Aggregation properties of the obtained metallophthalocyanines were researched in polar and apolar solvents.

Keywords

Aggregation, Metallophthalocyanine, Phthalocyanine, Schiff base

Supporting Institution

Karadeniz Technical University

Thanks

This study was supported by the Research Fund of Karadeniz Technical University

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