One pot synthesis and spectral characterization of 5-Substitutedfuran-2-carbaldehyde N4-cyclohexyl thiosemicarbazones and their Ni(II) complexes

Year 2020, Volume: 2 Issue: 2, 81 - 86, 29.12.2020

Ayşegül İyidoğan , Emine Elçin Oruç-emre , Ülkü Çakır

https://doi.org/10.51435/turkjac.813792

Abstract

In this work, the synthesis of thiosemicarbazones (I-V) was carried out using one pot method, multicomponent and catalyst-free reaction of cyclohexyl isothiocyanate, hydrazine monohydrate and 5-substituted-2-furancarbaldehydes in good yields. The chemical structures of 5-substituted-2-furancarbaldehyde thiosemicarbazones were eludicated using UV‐Vis, IR, 1H NMR, 13C NMR, mass spectra, and elemental analysis. Also, the reaction of NiCl2.6H2O with thiosemicarbazones in 1:2 molar ratio by refluxing gave the nickel (II) complexes (Ia-Va) as binuclear and their structures characterized by UV-Vis, IR, and elemental analysis.

Keywords

one pot synthesis, thiosemicarbazones, nickel complexes

Supporting Institution

Scientific Research Projects Governing Unit Council of Scientific Research Projects

Project Number

Grant no. FEF.08.10

Thanks

This work was supported by Scientific Research Projects Governing Unit Council of Scientific Research Projects (Grant no. FEF.08.10), Gaziantep, Turkey.

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