İÇ VE DIŞ ORTAM HAVA ÖRNEKLERİNDE POLİAROMATİK HİDROKARBONLARIN (PAH’ların) İNCELENMESİ: BURSA ÖRNEĞİ

Abstract

Bu çalışmada, Bursa ilindeki on iki farklı ev ortamından alınan iç ve dış ortam hava örneklerinde Poliaromatik (PAH’ların) konsantrasyonları belirlenmiştir. Örnekleme kapı ve pencerelerin açık olduğu yaz ve havaların soğumaya başladığı sonbahar dönemini yansıtması bakımından 2014 yılı Temmuz ve Aralık ayları arasında gerçekleştirilmiştir. PAH konsantrasyonları pasif örnekleyiciler kullanılarak toplanmıştır. Yaz dönemi için toplam ortalama PAH konsantrasyonu oturma odası, mutfak ve dış ortam havasında sırasıyla 20±17, 22±28, 10±6 ng/m³ olarak belirlenmiştir. Sonbahar dönemi için ise toplam ortalama PAH konsantrasyonu oturma odası, mutfak ve dış ortamda sırasıyla 27±19, 21±10, 20±11 ng/m³ değerlerini almıştır. Yaz dönemi oturma odası ve mutfak örneklerinde çocukların kanser potansiyellerinin yetişkinlere göre iki kat daha fazla olduğu hesaplanmıştır. Sonbahar döneminde çocukların kanser olma potansiyelleri yetişkinlerden yaklaşık 2,5 kat daha fazla olduğu belirlenmiştir. Hesaplanan tanı oranlarına göre yaz ve sonbahar dönemleri için PAH kirletici kaynağının yanma kökenli olduğu tespit edilmiştir.

Keywords

• iç ortam,PAH,Bursa

Investigation of Polyaromatic Hydrocarbons (PAHs) in Indoor and Outdoor Air Samples: Bursa Case

Abstract

In this study, the concentrations of polyaromatic hydrocarbons (PAHs) were determined at indoor and outdoor air samples taken from twelve different home environments in Bursa province. The sampling was carried out between July and December 2014 to reflect the autumn when the doors and windows were open and the ambient air began to cool off. The samples were were collected using passive samplers for PAH analysis. The PAH concentrations for the summer period were 20 ± 17, 22 ± 28, 10 ± 6 ng / m³ in the living room, kitchen and outdoor environment, respectively. For the autumn period, PAH concentrations were 27 ± 19, 21 ± 10, 20 ± 11 ng / m³ in the living room, kitchen and outdoor environment, respectively. It has been estimated that the cancer potentials for children in the summer period at the living room and kitchen samples were two times higher than for adults. In the autumn, children's cancer potentials were found to be about 2.5 times higher than the ones for adults. Based on the calculated diagnostic ratio, it was determined that the PAH contaminant source for summer and autumn seasons was the combustion.

Keywords

• indoor,PAH,Bursa,cancer risk

References

1. 1. Pekey, B., Karakas, D., Ayberk, S. (2007) Atmospheric deposition of polycyclic aromatic hydrocarbons to İzmit Bay, Turkey, Chemosphere, 67(3), 537-547.
2. 2. Çetin, B., Odabasi, M. (2008) Atmospheric concentrations and phase partitioning of polybrominated diphenyl ethers (pbdes) in İzmir, Turkey, Chemosphere, 71, 1067-1078.
3. 3. Bozlaker, A., Muezzinoglu, A. and Odabasi, M. (2008) Atmospheric concentrations, dry deposition and air–soil exchange of polycyclic aromatic hydrocarbons (pahs) in an industrial region in Turkey, Journal of Hazardous Materials, 153, 1093-1102.
4. 4. Cindoruk, S.S., Birgül, A., Taşdemir , Y. (2008) Islak çökelmenin büyük su kütleleri üzerine olan etkisi ve bir ıslak çökelme örnekleyicisinin geliştirilmesi, Van Gölü Hidrolojisi ve Kirliliği Konferansı, 21–22 Ağustos 2008, Van, 147-155.
5. 5. Esen, F., Tasdemir, Y., Cindoruk, S.S. (2010) Dry deposition, concentration and gas/particle partitioning of atmospheric carbazole, Atmospheric Research, 95, 379-385.
6. 6. Gaga, E.O., Ari, A., (2011) Gas-Particle partitioning of polycyclic aromatic hydrocarbons (PAHs) in an urban traffic site in Eskişehir, Turkey, Atmospheric Research, 99, 207- 216.
7. 7. Robinson, J., Nelson, WC. (1995) National human activity pattern survey data base. United States Environmental Protection Agency, Research Triangle Park.
8. 8. Cheng, H., Deng, Z., Chakraborty, P., Liu, D., Zhang, R., Xu, Y., Luo, C., Zhang, G., Li, J, (2013) A comparison study of atmospheric polycyclic aromatic hydrocarbons in three Indiana cities using puf disk passive air samplers, Atmospheric Environment, 73, 16-21.

9. 9. Krugly, E., M. D. (2013) Characterization of particulate and vapor phase polycyclic aromatic hydrocarbons in ındoor and outdoor air of primary schools, Atmospheric Environment, 82, 298-306.
10. 10. Kulkarni, P., Venkataraman, C. (2000) Atmospheric polycyclic aromatic hydrocarbons in Mumbai, India, Atmospheric Environment, 34, 2785-2790.
11. 11. Esen, F., Cindoruk, S.S., Taşdemir , Y. (2006) Ambient concentrations and gas/particle partitioning of polycyclic aromatic hydrocarbons in an urban site in Turkey, Environmental Forensics, 7, 303-312.
12. 12. Taşdemir, Y., Esen, F. (2007) Urban air pahs: concentrations, temporal changes and gas/particle partitioning at a traffic site in Turkey, Atmospheric Research, 84, 1-12.
13. 13. Masih, J., Masih, A., Kulshrestha, A., Singhvi, R., Taneja, A. (2010) Characteristics of polycyclic aromatic hydrocarbons in ındoor and outdoor atmosphere in the north central part in India, Journal of Hazardous Materials, 177,190-198.
14. 14. Shen, H., Huang, Y., Wang, R., Zhu, D., Li, W., Shen, G., Lu, Y. (2013) Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions, Environmental Science and Technology, 47, 6415-6424.
15. 15. Zhang, K., Wang, Y.S., Wen, T.W., Meslmani, Y., Murray, F. (2007) Properties of nitrate, sulfate and ammonium in typical polluted atmospheric aerosols (PM10) in Beijing, Atmospheric Research, 84, 67-77.
16. 16. Nisbet, C. and LaGoy, P. (1992) Toxic equivalency factors (TEFs) for polycyclic aromatic hydrocarbons (PAHs), Regulatory Toxicology Pharmacology, 16, 290-300.
17. 17. World Health organization (WHO) (1998) Environmental health criteria 202. Selected non-heterocyclic polycyclic aromatic hydrocarbons.
18. 18. Hanedar, A. (2009) İstanbul’da polisiklik aromatik hidrokarbonların atmosferik birikiminin ve konsantrasyon dağılımının belirlenmesi, İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, İstanbul.
19. 19. Agarwal, T., Khillare, P. S., Shridhar, V., & Ray, S. (2009) Pattern, sources and toxicpotential of pahs in the agricultural soils of Delhi, India, Journal of Hazardous Materials, 163(2), 1033–1039.
20. 20. Sangün, L. (2007) Temel bileşenler analizi, ayırma analizi, kümeleme analizleri ve ekolojik verilere uygulanması üzerine bir araştırma, Çukurova Üniversitesi, Fen Bilimleri Enstitüsü Doktora Tezi, Adana.
21. 21. Khalili, N.R., Scheff, P.A., Holsen, T.M. (1995) PAH source fingerprints for coke ovens, diesel and, gasoline engines, highway tunnels, and wood combustion emissions, Atmospheric Environment, 29, 533-542.
22. 22. Gupta, S., Kumar, K., Srivastava, A., Srivastava, A., & Jain, V. K. (2011) Sizedistribution and source apportionment of polycyclic aromatic hydrocarbons (pahs) in aerosol particle samples from the atmospheric environment of delhi ,India. Science of the Total Environment, 409(22), 4674–4680.
23. 23. Harrison, R.M., Smith, D.J.T., Luhana, L. (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location İn Birmingham, UK. Environmental Science and Technology, 30, 825-832.