DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ

Müjgan Okur; Çağla Ak; Utku Tümtürk

doi:10.17482/uumfd.383572

Research Article

DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ

Year 2019, Volume: 24 Issue: 2, 405 - 418, 30.08.2019

Müjgan Okur Çağla Ak Utku Tümtürk

https://doi.org/10.17482/uumfd.383572

Abstract

Bu çalışmada Cr(III)’ün tavuk
yumurtası kabuklarına adsorpsiyonu araştırılmıştır. Bu amaçla kalsine edilmiş
(900°C ve 3 saat) ve doğal yumurta kabukları adsorplayıcı olarak
kullanılmıştır. Yumurta kabuğu miktarı (0,6-2,0 g/L), Cr(III) derişimi (50-350
mg/L) ve sıcaklığın (25-55 °C) Cr(III) adsorpsiyonuna etkisi incelenmiştir.
Kalsine edilmiş ve doğal yumurta kabukları X-ışını kırınım (XRD) cihazında
analiz edilmiştir. Doğal yumurta kabukları ile Cr(III) adsorpsiyonunda 25°C’de,
50-350 mg/g Cr(III) derişimi aralığında % 100-16,6 giderim ve 38,23-46,31 mg/g
giderim kapasitesi elde edilmiştir. Kalsine edilmiş yumurta kabukları ile
Cr(III) giderimi çöktürmeyle gerçekleştirilmiştir. Langmuir, Freundlich ve
Temkin adsorpsiyon modelleri deneysel verilere uygulanmış ve her üç modelinde uygun
olduğu belirlenmiştir. Cr(III) adsorpsiyon kinetiğinin Yalancı ikinci derece
kinetik ile daha iyi ifade edildiği bulunmuştur. Bu çalışma atıksularda bulunan
Cr(III) iyonlarının gideriminde doğal ve kalsine tavuk yumurtası kabuklarının
kullanılabileceğini göstermiştir.

Keywords

Tavuk yumurtası kabuğu, Cr (III), Adsorpsiyon, Adsorpsiyon İzotermi, Adsorpsiyon Kinetiği

References

1. Ali, A., Saeed, K., Mabood, F. (2016) Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent, Alexandria Engineering Journal, 55(3), 2933-2942. Doi : 10.1016/j.aej.2016.05.011
2. Chatterjee, N., Luo, Z., Malghani, S., Lian, J.J., Zheng, W.L. (2009) Uptake and distribution of chromium in Saccharomyces cerevisae exposed to Cr (III)-organic compounds, Chemical Speciation & Bioavailability, 21(4), 245-255. Doi : 10.3184/095422909X12554538843778
3. Chojnacka, K. (2005) Biosorption of Cr (III) ions by eggshells, Journal of Hazardous Materials, 121(1), 167-173. Doi : 10.1016/j.jhazmat.2005.02.004
4. Chojnacka, K. (2010) Biosorption and bioaccumulation – the prospects for practical applications, Environment International, 36(3), 299-307. Doi:10.1016/j.envint.2009.12.001
5. Çetinkaya, F., Çetinkaya, Y. (2010) Derinin tabaklanması işleminde maskeleme maddeleri kullanımının krom alımı üzerine etkisinin araştırılması, Hayvansal Üretim, 51(1), 40-47.
6. Daraei, H., Mittal, A., Noorisepehr, M., Mittal, J. (2015) Separation of chromium from water samples using eggshell powder as a low-cost sorbent: Kinetic and thermodynamic studies, Desalination and Water Treatment, 53(1), 214-220. Doi : 10.1080/19443994.2013.837011
7. Elabbas, S., Mandi, L., Berrekhis, F., Pons, M.N., Leclerc, J.P., Ouazzani, N. (2016) Removal of Cr (III) from chrome tanning wastewater by adsorption using two natural carbonaceous materials: Eggshell and powdered marble, Journal of Environmental Management, 166, 589-595. Doi : 10.1016/j.jenvman.2015.11.012
8. Elkady, M.F., Ibrahim, A.M., Abd El-Latif, M.M. (2011) Assessment of the adsorption kinetics, equilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads, Desalination, 278(1), 412-423. Doi:10.1016/j.desal.2011.05.063
9. Fonseca-Correa, R., Giraldo, L., Moreno-Pirajan, J.C. (2013) Trivalent Chromium removal from aqueous solution with physically and chemical modified corncob waste, Journal of Analytical and Applied Pyrolysis, 101, 132-141. Doi : 10.1016/j.jaap.2013.01.019
10. Juvera-Espinosa, J., Morales-Barrera, L., Cristiani-Urbina, E. (2006) Isolation and characterization of a yeast strain capable of removing Cr (VI), Enzyme and Microbial Technology, 40(1), 114-121. Doi : 10.1016/j.enzmictec.2005.10.045
11. Long, M., Zhou, C., Xia, S., Guadiea, A. (2017) Concominant Cr(VI) reduction and Cr(III) precipitation with nitrate in a methane/oxygen-based membrane biofilm reactor, Chemical Engineering Journal, 315, 58-65. Doi : 10.1016/j.cej.2017.01.018
12. Mahmoud, M.S., Mohamed, S.A., (2017) Calcium alginate as an eco-friendly supporting material for Baker's yeast strain in chromium bioremediation, HBRC Journal, 13 (3), 245-254. Doi : 10.1016/j.hbrcj.2015.06.003
13. Mohan, D., Pittman Jr, C.U. (2006) Activated carbons and low cost adsorbents for remediation of tri and hexavalent chromium from water, Journal of Hazardous Materials, 137(2), 762-811. Doi : 10.1016/j.jhazmat.2006.06.060
14. Pan, J., Jiang, J., Xu, R., (2013) Adsorption of Cr(III) from acidic solutions by crop straw derived biochars, Journal of Environmental Sciences, 25(10), 1957-1965. Doi : 10.1016/S1001-0742(12)60305-2
15. Park, H.J., Jeong, S.W., Yang, J.K., Kim, B.G., Lee, S.M. (2007) Removal of heavy metals using waste eggshell, Journal of Environmental Sciences, 19(12), 1436-1441. Doi : 10.1016/S1001-0742(07)60234-4
16. Rajendran, A., Mansiya, C. (2011) Extraction of Chromium from Tannery Effluents Using Waste Egg Shell Material as an Adsorbent, British Journal of Environment and Climate Change, 1(2), 44-52. Doi : 10.9734/BJECC/2011/262
17. Tan, C., Zeyu, Z., Sai, X., Hongtao, W., Wenjing, L. (2015) Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipial sludge, Bioresource Technology, 190, 388-394. Doi : 10.1016/j.biortech.2015.04.115
18. Turan, P., Doğan, M., Alkan, M. (2007) Uptake of trivalent chromium ions from aqueous solutions using kaolinite, Journal of Hazardous Materials, 148, 56-63. Doi : 10.1016/j.jhazmat.2007.02.007
19. Wang, D., He,S., Shan, C., Ye, Y., Ma, H., Zhang, X., Zhang, W., Pan, B. (2016) Chromium speciation in tannery effluent after alkaline precipitation: Isolation and characterization, Journal of Hazardous Materials, 316, 169-177. Doi : 10.1016/j.jhazmat.2016.05.021
20. Wang, D., Ye,Y., Liu, H., Ma, H., Zhang, W. (2018) Effect of alkaline precipitation on Cr species of Cr(III)-bearing complexes typically used in the tannery industry, Chemosphere, 193, 42-49. Doi : 10.1016/j.chemosphere.2017.11.006
21. Yang, Z.H., Xiong, S., Wang, B., Li, Q., Yang, W.C. (2013) Cr(III) adsorption by sugarcane pulp residue and biochar, Journal of Central South University, 20 (5), 1319–1325. Doi : 10.1007/s11771-013-1618-4
22. Zou, J., Guo, C., Zhou, X., Sun, Y., Yang, Z. (2018) Sorption capacity and mechanism of Cr+3 on tobermorite derived from fly ash acid residue and carbide slag, Colloids and Surfaces A, 538, 825-833. Doi : 10.1016/j.colsurfa.2017.11.073

Year 2019, Volume: 24 Issue: 2, 405 - 418, 30.08.2019

Müjgan Okur Çağla Ak Utku Tümtürk

https://doi.org/10.17482/uumfd.383572

Abstract

References

1. Ali, A., Saeed, K., Mabood, F. (2016) Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent, Alexandria Engineering Journal, 55(3), 2933-2942. Doi : 10.1016/j.aej.2016.05.011
2. Chatterjee, N., Luo, Z., Malghani, S., Lian, J.J., Zheng, W.L. (2009) Uptake and distribution of chromium in Saccharomyces cerevisae exposed to Cr (III)-organic compounds, Chemical Speciation & Bioavailability, 21(4), 245-255. Doi : 10.3184/095422909X12554538843778
3. Chojnacka, K. (2005) Biosorption of Cr (III) ions by eggshells, Journal of Hazardous Materials, 121(1), 167-173. Doi : 10.1016/j.jhazmat.2005.02.004
4. Chojnacka, K. (2010) Biosorption and bioaccumulation – the prospects for practical applications, Environment International, 36(3), 299-307. Doi:10.1016/j.envint.2009.12.001
5. Çetinkaya, F., Çetinkaya, Y. (2010) Derinin tabaklanması işleminde maskeleme maddeleri kullanımının krom alımı üzerine etkisinin araştırılması, Hayvansal Üretim, 51(1), 40-47.
6. Daraei, H., Mittal, A., Noorisepehr, M., Mittal, J. (2015) Separation of chromium from water samples using eggshell powder as a low-cost sorbent: Kinetic and thermodynamic studies, Desalination and Water Treatment, 53(1), 214-220. Doi : 10.1080/19443994.2013.837011
7. Elabbas, S., Mandi, L., Berrekhis, F., Pons, M.N., Leclerc, J.P., Ouazzani, N. (2016) Removal of Cr (III) from chrome tanning wastewater by adsorption using two natural carbonaceous materials: Eggshell and powdered marble, Journal of Environmental Management, 166, 589-595. Doi : 10.1016/j.jenvman.2015.11.012
8. Elkady, M.F., Ibrahim, A.M., Abd El-Latif, M.M. (2011) Assessment of the adsorption kinetics, equilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads, Desalination, 278(1), 412-423. Doi:10.1016/j.desal.2011.05.063
9. Fonseca-Correa, R., Giraldo, L., Moreno-Pirajan, J.C. (2013) Trivalent Chromium removal from aqueous solution with physically and chemical modified corncob waste, Journal of Analytical and Applied Pyrolysis, 101, 132-141. Doi : 10.1016/j.jaap.2013.01.019
10. Juvera-Espinosa, J., Morales-Barrera, L., Cristiani-Urbina, E. (2006) Isolation and characterization of a yeast strain capable of removing Cr (VI), Enzyme and Microbial Technology, 40(1), 114-121. Doi : 10.1016/j.enzmictec.2005.10.045
11. Long, M., Zhou, C., Xia, S., Guadiea, A. (2017) Concominant Cr(VI) reduction and Cr(III) precipitation with nitrate in a methane/oxygen-based membrane biofilm reactor, Chemical Engineering Journal, 315, 58-65. Doi : 10.1016/j.cej.2017.01.018
12. Mahmoud, M.S., Mohamed, S.A., (2017) Calcium alginate as an eco-friendly supporting material for Baker's yeast strain in chromium bioremediation, HBRC Journal, 13 (3), 245-254. Doi : 10.1016/j.hbrcj.2015.06.003
13. Mohan, D., Pittman Jr, C.U. (2006) Activated carbons and low cost adsorbents for remediation of tri and hexavalent chromium from water, Journal of Hazardous Materials, 137(2), 762-811. Doi : 10.1016/j.jhazmat.2006.06.060
14. Pan, J., Jiang, J., Xu, R., (2013) Adsorption of Cr(III) from acidic solutions by crop straw derived biochars, Journal of Environmental Sciences, 25(10), 1957-1965. Doi : 10.1016/S1001-0742(12)60305-2
15. Park, H.J., Jeong, S.W., Yang, J.K., Kim, B.G., Lee, S.M. (2007) Removal of heavy metals using waste eggshell, Journal of Environmental Sciences, 19(12), 1436-1441. Doi : 10.1016/S1001-0742(07)60234-4
16. Rajendran, A., Mansiya, C. (2011) Extraction of Chromium from Tannery Effluents Using Waste Egg Shell Material as an Adsorbent, British Journal of Environment and Climate Change, 1(2), 44-52. Doi : 10.9734/BJECC/2011/262
17. Tan, C., Zeyu, Z., Sai, X., Hongtao, W., Wenjing, L. (2015) Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipial sludge, Bioresource Technology, 190, 388-394. Doi : 10.1016/j.biortech.2015.04.115
18. Turan, P., Doğan, M., Alkan, M. (2007) Uptake of trivalent chromium ions from aqueous solutions using kaolinite, Journal of Hazardous Materials, 148, 56-63. Doi : 10.1016/j.jhazmat.2007.02.007
19. Wang, D., He,S., Shan, C., Ye, Y., Ma, H., Zhang, X., Zhang, W., Pan, B. (2016) Chromium speciation in tannery effluent after alkaline precipitation: Isolation and characterization, Journal of Hazardous Materials, 316, 169-177. Doi : 10.1016/j.jhazmat.2016.05.021
20. Wang, D., Ye,Y., Liu, H., Ma, H., Zhang, W. (2018) Effect of alkaline precipitation on Cr species of Cr(III)-bearing complexes typically used in the tannery industry, Chemosphere, 193, 42-49. Doi : 10.1016/j.chemosphere.2017.11.006
21. Yang, Z.H., Xiong, S., Wang, B., Li, Q., Yang, W.C. (2013) Cr(III) adsorption by sugarcane pulp residue and biochar, Journal of Central South University, 20 (5), 1319–1325. Doi : 10.1007/s11771-013-1618-4
22. Zou, J., Guo, C., Zhou, X., Sun, Y., Yang, Z. (2018) Sorption capacity and mechanism of Cr+3 on tobermorite derived from fly ash acid residue and carbide slag, Colloids and Surfaces A, 538, 825-833. Doi : 10.1016/j.colsurfa.2017.11.073

There are 22 citations in total.

Details

Primary Language	Turkish
Subjects	Engineering
Journal Section	Research Articles
Authors	Müjgan Okur Çağla Ak This is me Utku Tümtürk This is me
Publication Date	August 30, 2019
Submission Date	March 29, 2018
Acceptance Date	May 29, 2019
Published in Issue	Year 2019 Volume: 24 Issue: 2

Cite

APA	Okur, M., Ak, Ç., & Tümtürk, U. (2019). DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 24(2), 405-418. https://doi.org/10.17482/uumfd.383572
AMA	Okur M, Ak Ç, Tümtürk U. DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. UUJFE. August 2019;24(2):405-418. doi:10.17482/uumfd.383572
Chicago	Okur, Müjgan, Çağla Ak, and Utku Tümtürk. “DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 24, no. 2 (August 2019): 405-18. https://doi.org/10.17482/uumfd.383572.
EndNote	Okur M, Ak Ç, Tümtürk U (August 1, 2019) DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 24 2 405–418.
IEEE	M. Okur, Ç. Ak, and U. Tümtürk, “DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ”, UUJFE, vol. 24, no. 2, pp. 405–418, 2019, doi: 10.17482/uumfd.383572.
ISNAD	Okur, Müjgan et al. “DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 24/2 (August 2019), 405-418. https://doi.org/10.17482/uumfd.383572.
JAMA	Okur M, Ak Ç, Tümtürk U. DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. UUJFE. 2019;24:405–418.
MLA	Okur, Müjgan et al. “DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, vol. 24, no. 2, 2019, pp. 405-18, doi:10.17482/uumfd.383572.
Vancouver	Okur M, Ak Ç, Tümtürk U. DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. UUJFE. 2019;24(2):405-18.

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