Cevap Yüzey Yöntemi Kullanılarak Eosin Sarısının Renksizleştirilmesi için Aloe Vera Destekli Gümüş Katalizörün Araştırılması

Year 2022, , 269 - 285, 30.08.2022

Şakir Yılmaz

https://doi.org/10.53433/yyufbed.1078950

Abstract

Eosin sarısı (ES) genellikle hem insan sağlığı hem de çevre için toksik bir boyadır. Bu çalışmada Aloe vera destekli gümüş (Ag/AV) katalizörü sodyum borohidrür (NaBH₄) indirgeme yöntemi ile sentezlenmiştir. Sentezlenen malzeme, bir anyonik boya olan ES’nin renk gideriminde potansiyel katalizör olarak kullanılmıştır. Başlangıç ES konsantrasyonu (C_o), zaman ve katalizör miktarı, NaBH4 varlığında ES renk giderimi üzerindeki etkileri araştırıldı ve proses koşulları, cevap yüzey yöntemi (response surface methodology – RSM) kullanılarak optimize edildi. Optimizasyon analizinden, 10.96 mg/L C_o, 73.50 s süre ve 0.78 mg/mL katalizör miktarında %84.99’luk maksimum ES renksizleştirme verimliliği elde edildi. Ayrıca, kinetik çalışmalar, NaBH₄ varlığında Ag/AV üzerinde ES’nin renksizleştirmesinin, yalancı ikinci dereceden bir kinetik modeli takip ettiğini göstermiştir. Termodinamik çalışmalar, ES renk giderme işleminin ekzotermik ve kendiliğinden olduğunu göstermiştir. Sonuç olarak hazırlanan katalizörün ES gibi organik kirleticilerin renksizleştirilmesinde verimli bir şekilde kullanılabileceği sonucuna varılabilir.

Keywords

Aloe vera, Cevap yüzey yöntemi, Eosin sarısı, Gümüş nanopartikül, Renksizleştirme

Investigation of Aloe Vera Supported Silver Catalyst for Decolourization of Eosin Yellow Using Response Surface Methodology

Abstract

Eosin yellow (EY) is generally a toxic dye for both human health and environment. In the present work, Aloe vera supported silver (Ag/AV) catalyst was synthesized by sodium borohydride (NaBH₄) reduction method. The synthesized material was used as potential catalyst for the degradation of ES, an anionic dye. The effects of initial ES concentration (C_o), time, and catalyst amount on ES decolourization in the presence of NaBH₄ were investigated and the process conditions were optimized by using response surface methodology (RSM). From the optimization analysis, a maximum ES decolourization efficiency of 84.99% was obtained at 10.96 mg/L C_o, 73.50 s time, and 0.78 mg/mL catalyst amount. Moreover, the kinetic studies indicated that the decolourization of ES on Ag/AV in the presence of NaBH₄ follows a pseudo second order kinetic model. Thermodynamic studies indicated that the ES decolourization process was exothermic and spontaneous. Finally, it can be concluded that the prepared catalyst could be utilized efficiently in the decolourization of organic contaminants such as ES.

Keywords

Aloe vera, Decolourization, Eosin yellow, Response surface methodology, Silver nanoparticle

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