Farklı Substitue Grouplu Yeni Metalli Ftalosiyaninlerin Sentezi

Year 2011, Volume: 16 Issue: 2, 40 - 44, 01.12.2011

Safiye Özkaya M.Salih Ağırtaş

Abstract

New metallophthalocyanines have been synthesized from 4-(2-dimethylaminoethylsulfanyl) phthalonitrile and diethyl 3, 4 dicyanophenylmalonate. Metallophthalocyanines (Co II, Ni II and Zn II) were prepared by cyclotetramerization of i and ii with metal salts. The phthalocyanines were separated and washed using different solvents. The newly synthesized compounds have been characterized by elemental analyses, UV-Visible and IR spectra.

Keywords

Phthalocyanine; Characterization;Complex; Synthesis; Metal

Synthesis of New Metallophthalocyanines Substituted with Dissimilar Groups

Abstract

Yeni metalli ftalosiyaninler 4-(2-dimetilaminoetilsulfanil)ftalonitril ve dietil 3,4 disiyanofenilmalonat'dan sentezlendi. Metalli ftalosiyaninler (Co II,Ni II and Zn II) i ve ii nın metal tuzlar ile siklotetramerizasiyondan hazırlandı. Ftalosiyaninler farklı çözücüler ile yıkandı ve izole edildi. Yeni sentezlenen bileşikler elemental analiz, UV-Vis ve IR spektrumu ile karakterize edilmiştir.

Keywords

Ftalosiyanin; Karakterizasyon;Kompleks; Sentez; Metal.