Catalytic Use of Pd(II) Complex Bearing 2-(thiophen-2-yl)-1H-Benzimidazole Ligand for The Reduction / Degradation of Multiple Mixtures Containing 4-NP, RhB and MB Organic Pollutants

Year 2023, Volume: 28 Issue: 1, 271 - 284, 30.04.2023

Melek Tercan

https://doi.org/10.53433/yyufbed.1167004

Abstract

In this study, the catalytic use of [Pd(L1)2]Cl2 complex is aimed for the reduction / degradation reactions of organic pollutants in water sources which pose a threat to the environment. For this purpose, 2-(thiophen-2-yl)-1H-benzimidazole ligand (L1) and its Pd(II) complex (C1) were synthesized and characterized by FT-IR, 1H-NMR, 13C-NMR, ESI-MS spectroscopic techniques. The catalytic efficiency of the C1 complex on the reduction of 4-nitro phenol compound (4-NP) and the degradation of rhodamine B (RhB), methylene blue (MB) dyes was investigated in the presence of NaBH4 in aqueous medium. The catalytic performance was examined with single solutions of these substrates (4-NP and RhB, MB dyes) and at the end of 5 minutes, over 92% conversion was observed for all three substrates. In the catalytic trials with 4-NP + RhB + MB triple substrate mixture, 84, 94 and 93% conversion values were obtained, respectively, after 5 minutes. C1 complex catalyst is very effective in the simultaneous reduction / degradation of these toxic organic compounds from aqueous environments without any competition or selectivity.

Keywords

Catalysis, Methylene blue, Pd complexes, Rhodamine B, 4-Nitro phenol

2-(tiyofen-2-il)-1H-Benzimidazol Ligandı Taşıyan Pd Kompleksinin 4-NP, RhB ve MB Organik Kirleticileri İçeren Çoklu Karışımların İndirgenmesi / Bozunmasında Katalitik Kullanımı

Abstract

Bu çalışmada, çevre için tehdit oluşturan organik kirleticilerin indirgeme / bozunma reaksiyonları ile su kaynaklarından uzaklaştırılması için [Pd(L1)2]Cl2 kompleksinin katalitik kullanımı amaçlanmıştır. Bu amaçla 2-(thiophen-2-yl)-1H-benzimidazole ligandı (L1) ve onun Pd(II) kompleksi (C1) sentezlenmiş ve FT-IR, 1H-NMR, 13C-NMR, ESI-MS spectroscopic teknikleri ile karakterize edilmiştir. C1 kompleksinin rhodamine B (RhB) ve methylene blue (MB) boyalarının bozunmasındaki ve 4-nitro phenol (4-NP) bileşiğinin indirgenmesindeki katalitik etkinliği NaBH4 varlığında, sulu ortamda incelenmiştir. Bu substratların (4-NP ve RhB, MB boyaları) tekli çözeltileri ile katalitik performans incelenmiş ve 5 dakikanın sonunda her üç substrat için de 92% üzerinde dönüşüm gözlenmiştir. 4-NP + RhB + MB üçlü substrat karışımı ile yapılan katalitik denemelerde 5 dakikanın sonunda sırasıyla 84, 94 ve 93% dönüşüm değerleri elde edilmiştir. Çevre için oldukça toksik bu organik bileşikleri çoklu olarak içeren sulu ortamlardan bu bileşiklerin aynı anda ayrılmasında C1 kompleks katalizörü oldukça etkindir.

Keywords

Metilen mavisi, Organik kirleticiler, Pd kompleksleri, Rodamin B, 4-Nitro fenol

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