METAL-ORGANIC FRAMEWORKS (MOFs) DERIVED FROM CARBOXYLATE LIGAND AS POTENTIAL MATERIALS FOR REMEDIATION OF Cu (II) AND Pb (II) FROM AQUEOUS SOLUTION
Abstract
The remediation of cadmium and lead ions from their respective aqueous solutions was carried out with the use of metal-organic frameworks (MOFs) developed from copper and zinc with benzene-1,4-dicarboxylic acid (BDC). The experimental adsorption process was done in batches to determine the equilibrium characteristics, thermodynamics and kinetics of the sorption processes. The result was then tested using Langmuir, Freundlich, and Temkin isotherm equations with Langmuir being the best fitted isotherm, while the kinetics isotherm used were pseudo first order and pseudo second order. The result obtained shows that the MOFs are great potential adsorbent for the studied metals.
Keywords
References
- 1. Okoro HK, Ige JO, Iyiola OA, Ngila JC. Fractionation profile, mobility patterns and correlations of heavy metals in estuary sediments from olonkoro river, in tede catchment of western region, Nigeria. Environmental nanotechnology, monitoring & management. 2017;8:53–62.
- 2. Gielar A, Helios-Rybicka E, Möller S, Einax JW. Multivariate analysis of sediment data from the upper and middle Odra River (Poland). Applied Geochemistry. 2012;27(8):1540–5.
- 3. Mobasherpour I, Salahi E, Asjodi A. Research on the batch and fixed-bed column performance of red mud adsorbents for lead removal. soil and water. 2014;4:5.
- 4. Okoro HK, Adeyinka A, Jondiko OE, Ximba BJ. Physico-chemical analysis of selected groundwater samples of Ilorin town in Kwara State, Nigeria. Scientific Research and Essays. 2012;7(23):2063–9.
- 5. Aguayo-Villarreal IA, Bonilla-Petriciolet A, Hernández-Montoya V, Montes-Morán MA, Reynel-Avila HE. Batch and column studies of Zn2+ removal from aqueous solution using chicken feathers as sorbents. Chemical Engineering Journal. 2011;167(1):67–76.
- 6. Venkatesham V, Madhu G, Satyanarayana S, Preetham H. Adsorption of lead on gel combustion derived nano ZnO. Procedia Engineering. 2013;51:308–13.
- 7. Yang H, Rose N. Distribution of Hg inthe lake sediments across the UK. Science of the Total Environment. 2003;304:391–404.
- 8. Okoro HK, Fatoki OS, Adekola FA, Ximba BJ, Snyman RG. Geochemical assessment of sediment in Cape Town harbour, South Africa. Bulletin of the Chemical Society of Ethiopia. 2014;28(1):17–28.
Details
Primary Language
English
Subjects
Chemical Engineering
Journal Section
Research Article
Authors
Oluwaseyi Ayika
This is me
0000-0002-7501-6870
Nigeria
Adedibu Tella
0000-0003-2090-4747
Nigeria
Jane Ngila
This is me
0000-0002-0121-4567
South Africa
Publication Date
June 15, 2019
Submission Date
August 17, 2018
Acceptance Date
April 5, 2019
Published in Issue
Year 2019 Volume: 6 Number: 2
Cited By
Fabrication of Zn(II) and Cu(II) supported metal-organic frameworks for removal of some 3d metals from aqueous solutions
International Journal of Environmental Science and Technology
https://doi.org/10.1007/s13762-019-02459-4Synthesis, Crystal Structure and Catalytic Performance of a novel Five‐Coordinated Energetic Copper(II) Compound
Zeitschrift für anorganische und allgemeine Chemie
https://doi.org/10.1002/zaac.202100106
