Engelli Karıştırmalı Tanklarda Karıştırıcı Hızı Değişiminin Pickering Emülsiyonlarının Damlacık Boyut Dağılımı Üzerine Etkisi

Abstract

Pickering emülsiyonları, katı parçacıklar ile stabilize edilmiş emülsiyonlardır. Sürfaktan bazlı emülsiyonlara potansiyel bir alternatiftirler. Pickering emülsiyonunun kararlığı, dağılmış faz damlacıklarının büyüklüğü ile ilişkilidir. Küçük damlacıklar daha kararlıdır. Pickering emülsiyonlarının kararlığı, emülsiyonları üretmek için kullanılan partiküllerin özelliklerine ve üretim işleminde sağlanan karıştırmaya bağlıdır. Bu araştırma, karıştırıcı hızının değişiminin, karıştırılmalı tankta üretilen Pickering emülsiyonlarının damlacık boyutuna etkisini incelemektedir. Silikon yağı saf su içinde dağıtılmış ve su içinde yağ türü emülsiyonlar oluşturmak için hidrofilik cam parçacıklarla stabilize edilmiştir. İki farklı boyutta farklı makaslama kapasitesine sahip iki farklı karıştırıcı kullanılmıştır: Rushton türbini ve eğimli bıçaklı türbin. Elde edilen damlacık boyut dağılımı Malvern Mastersizer 3000® ile belirlenmiştir. Yeterli akış sağlayabilen karıştırıcılar için, karıştırıcı hızının arttırılmasının emülsiyonun damlacık boyutunu azalttığı görülmüştür. Hızı azaltmanın, mevcut stabilize bir emülsiyonun damlacık boyutunu arttırdığı görülmüştür. Emülsiyon oluşumunda bir hız histerezisi gözlenmiştir. Karıştırma süresi analizi, damlacıkların tankın bazı bölgelerinde kalma süresinin, artan hızla damlacık büyüklüğünün azalmasının nedeni olduğunu doğrulamıştır.

Keywords

• Pickering emülsiyonu,sıvı-sıvı karıştırma,karıştırmalı tank,damlacık birleşimi,emülsifikasyon

The Effect of the Change of Impeller Speed on the Droplet Size Distribution of Pickering Emulsions in a Baffled Stirred Tank

Abstract

Pickering emulsions are emulsions stabilized by solid particles. They are a potential alternative to surfactant-based emulsions. The stability of a Pickering emulsion is related to the size of the dispersed phase droplets. Smaller droplets are more stable.  The stability of Pickering emulsions depends on the properties of the particles used to produce the emulsions and the agitation provided in the production process. This paper investigates the effect of the change of impeller speed on the droplet size of Pickering emulsions produced in a baffled stirred tank. Silicon oil was dispersed into distilled water and stabilized with hydrophilic glass beads to form oil in water Pickering emulsions. Two different impellers with different shearing capacities at two different sizes were used: the Rushton turbine and the pitched blade turbine. The resulting droplet size distribution was determined with Malvern Mastersizer 3000®. For impellers with adequate flow, increasing the impeller speed decreases the droplet size of the emulsion. Decreasing the speed increases the droplet size of the emulsion. A speed hysteresis was observed in the emulsion formation. Mixing time analysis confirmed that the residence time of droplets in parts of the tank was the reason of the droplet size decrease with increasing speed.

Keywords

• Pickering emulsions,liquid-liquid mixing,stirred tank,droplet coalescence,emulsification

References

1. [1] Chen, G., & Tao, D. (2005). An experimental study of stability of oil–water emulsion. Fuel Processing Technology, 86(5), 499-508. doi:10.1016/j.fuproc.2004.03.010
2. [2] Pickering, S.U., 1907. Emulsions. J. Chem. Soc. 91, 2001.
3. [3] Binks, B. P. (2002). Particles as surfactants - Similarities and differences. Current Opinion in Colloid and Interface Science, 7(1–2), 21–41. http://doi.org/10.1016/S1359-0294(02)00008-0
4. [4] Binks, B. P., & Lumsdon, S. O. (2000). Influence of particle wettability on the type and stability of surfactant-free emulsions. Langmuir, 16(23), 8622–8631. http://doi.org/10.1021/la000189s
5. [5] Binks, B. P., & Lumsdon, S. O. (2001). Pickering emulsions stabilized by monodisperse latex particles: Effects of particle size. Langmuir, 17(15), 4540–4547. http://doi.org/10.1021/la0103822
6. [6] Aveyard, R., Binks, B. P., & Clint, J. H. (2003). Emulsions stabilised solely by colloidal particles. Advances in Colloid and Interface Science, 100–102(SUPPL.), 503–546. http://doi.org/10.1016/S0001-8686(02)00069-6
7. [7] Tsabet, È., & Fradette, L. (2015). Effect of the properties of oil, particles, and water on the production of Pickering emulsions. Chemical Engineering Research and Design, 97(1), 9–17. http://doi.org/10.1016/j.cherd.2015.02.016
8. [8] Arditty, S., Whitby, C. P., Binks, B. P., Schmitt, V., & Leal-Calderon, F. (2003). Some general features of limited coalescence in solid-stabilized emulsions. European Physical Journal E, 11(3), 273–281. http://doi.org/10.1140/epje/i2003-10018-6

9. [9] Madivala, B., Vandebril, S., Fransaer, J., & Vermant, J. (2009). Exploiting particle shape in solid stabilized emulsions. Soft Matter, 5(8), 1717. doi:10.1039/b816680c
10. [10] Kaptay, G. (2006). On the equation of the maximum capillary pressure induced by solid particles to stabilize emulsions and foams and on the emulsion stability diagrams, 283, 387–401. http://doi.org/10.1016/j.colsurfa.2005.12.021
11. [11] Walstra, P. (1993). Principles of emulsion formation. Chemical Engineering Science, 48(2), 333–349. http://doi.org/10.1016/0009-2509(93)80021-H
12. [12] Leng, D. E., & Calabrese, R. V. (2004). Immiscible Liquid – Liquid Systems. Handbook of Industrial Mixing: Science and Practice
13. [13] Zhou, G., & Kresta, S. M. (1998). Evolution of drop size distribution in liquid-liquid dispersions for various impellers. Chemical Engineering Science, 53(11), 2099–2113. http://doi.org/10.1016/S0009-2509(97)00437-5
14. [14] Siddiqui, S. W., & Norton, I. T. (2012). Oil-in-water emulsification using confined impinging jets. Journal of Colloid and Interface Science, 377(1), 213–221. http://doi.org/10.1016/j.jcis.2012.03.062
15. [15] Hemrajani, R., & Tatterson, G. (2004). Mechanically Stirred Vessels. Handbook of Industrial Mixing: Science and Practice. http://doi.org/10.1002/0471451452.ch6
16. [16] Wichterle, K. (1995). Drop breakup by impellers. Chemical Engineering Science, 50(22), 3581–3586. http://doi.org/10.1016/0009-2509(95)00208-M
17. [17] Skelland, A. H. P., & Kanel, J. S. (1990). Minimum Impeller Speeds for Complete Dispersion of Non-Newtonian Liquid-Liquid Systems in Baffled Vessels. Industrial and Engineering Chemistry Research, 29(7), 1300–1306. http://doi.org/10.1021/ie00103a032
18. [18] Bhattacharya, S., Hebert, D., & Kresta, S. M. (2007). Air entrainment in baffled stirred tanks. Chemical Engineering Research and Design, 85(5 A), 654–664. http://doi.org/10.1205/cherd06184
19. [19] Rawle, A. (1993). Basic principles of particle size analysis, 44(0), 1–8. http://doi.org/10.1016/j.apgeochem.2015.02.008
20. [20] Cabaret, F., Bonnot, S., Fradette, L., & Tanguy, P. A. (2007). Mixing Time Analysis Using Colorimetric Methods and Image Processing. Industrial & Engineering Chemistry Research, 46(14), 5032–5042. http://doi.org/10.1021/ie0613265
21. [21] Tolosa, L. I., Forgiarini, A., Moreno, P., & Salager, J. L. (2006). Combined effects of formulation and stirring on emulsion drop size in the vicinity of three-phase behavior of surfactant-oil water systems. Industrial and Engineering Chemistry Research, 45(11), 3810–3814. http://doi.org/10.1021/ie060102j