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The Effect of Aerophine 3418A Collector Dosage on Niğde (Ulukışla-Madenköy) Complex Pb-Zn Sulphide Ore Flotation

Yıl 2021, Cilt 9, Sayı 2, 309 - 313, 28.05.2021
https://doi.org/10.21541/apjes.783976

Öz

In this study, grinding + flotation experiments were performed on the sample of complex Pb-Zn sulphide ore taken from Niğde (Ulukışla-Madenköy) region in Turkey. According to the mineralogical analysis of the ore sample used in experimental studies, it was determined that the ore composition contains calcite, quartz, pyrite, chalcopyrite, hematite, goethite, limonite, gypsum, galena, sphalerite, jarosite, arsenopyrite and marcasite minerals. In addition, Au and Ag grains were found to be inclusions in hematite, goethite and jarosite minerals. The experiments were carried out at a solid ratio of 30%, a flow rate of 10 L/min, a stirring rate of 1250 rpm and pH = 9. In flotation tests, lime is used as the pH regulator, zinc sulphate, sodium silicate as the depressant, sodium isobutyl dithiophosphine as the collector and methyl isobutyl carbinol as the frother. In the flotation studies, the effect of Aerophine 3418A collector dosage on flotation was investigated. As a result, a lead concentrate of 55.13% Pb was obtained and it was found that this concentrate contained 2489 ppm of Ag. The amount of Aerophine 3418A collector was determined as 10 g/t.

Kaynakça

  • [1] S. Temur, “Bolkardağı yöresi (Ulukışla/Niğde) çinko-kurşun yataklarının jeokimyasal incelemesi”. Türkiye Jeoloji Bülteni, Sayı: 35, s: 101–114, 1990.
  • [2] N. Şişman, M.H. Şenocak, S. Dilek, M. Yazgaç, “Bolkardağ yöresinin jeolojisi ve maden yatakları”, MTA Genel Müdürlüğü, Rapor No: 7202, Ankara, (1981).
  • [3] S. Atak, Flotasyon ilkeleri ve uygulaması, İstanbul, 1990.
  • [4] A. M. Gaudin, Flotation, McGraw Hill, New York, 1957.
  • [5] J. S. Laskowski, Frothing in Flotation II, G&B Science, 1998.
  • [6] B.K. Parekh, J. D. Miller, Advances in flotation technology, Soc. for Mining Metallurgy, New York, 1999.
  • [7] L. Leja, Surface Chemistry of Froth Flotation. New York, 1982.
  • [8] N. Arbiter, SME Mineral Processing Handbook, Volume I, New York, 1985.
  • [9] B.A. Wills, Mineral Processing Technology. Fourth Edition,1988.
  • [10] M. Cao, Q. Liu, “Re-examining the functions of zinc sulphate as a selective depressant in differential sulphide flotation the role of coagulation”, Journal of Colloid and Interface Science, vol. 301, pp. 523– 531, 2006.
  • [11] S.M. Bulatovic, Handbook of flotation reagents, chemistry. theory and practice, flotation of sulfide ores, Elsevier, Amsterdam, 2007. [12] S.R. Grano, M. Sollaart, W. Skinner, C.A. Prestidge, J. Ralston, “Surface modifications in the chalcopyrite-sulphite ion system. I. collectorless flotation, XPS and dissolution study” International Journal of Mineral Processing, vol. 50(2), pp. 1-26, 1997.
  • [13] S.R. Grano, N.W. Johnson, J. Ralston, “Control of the solution interaction of meta bisulphite and ethyl xanthate in the flotation of the Hilton ore of Mount Isa Mines Limited, Australia”, Miner. Eng., vol. 10 (1), pp. 17, 1997a.
  • [14] S.R. Grano, C.A. Prestidge, J. Ralston, “Solution interaction of ethyl xanthate and sulphite and its effect on galena flotation and xanthate adsorption”, Int. J. of Miner. Process. Vol. 52, pp. 161-186, 1997b.
  • [15] T.N. Khmeleva, J.K. Chapelet, W.M. Skinner, D.A. Beattie, “Depression mechanisms of sodium bisulphite in the xanthate-induced flotation of copper activated sphalerite”, International Journal of Mineral Processing. Vol.79, pp. 61-75, 2006.
  • [16] N. Acarkan, G. Bulut, A. Gül, O. Kangal, F. Karakaş, O. Kökkılıç, G. Önal, “The effect of collector's type on gold and silver flotation in a complex ore”, Sep. Sci. Technol. Vol. 46, pp. 283–289, 2011.
  • [17] C. Durmaz, “Kuyumculuk kökenli curüflardan fiziksel zenginleştirme yöntemleri ile altının geri kazanımı”, Yüksek Lisans Tezi, İstanbul, 2012. [18] Cytec Mining Chemical Handbook, 2002.
  • [19] A. Ceylan, B. Bulut, “Siirt-Madenköy bakır cevherinin flotasyon yöntemiyle zenginleştirilmesi”, Madencilik, sayı. 55 (1), s. 17-26, 2016.
  • [20] B. B. Yilmaz, “ Niğde (Ulukışla-Madenköy) Bolkardağı sülfürlü kurşun-çinko kompleks cevherinin optimum flotasyon şartlarının belirlenmesi”, Yüksek Lisans Tezi, Konya, 2019.
  • [21] P. Mingione, “Use of AEROPHINE® 3418A promoter for sulphide minerals flotation” in The 120th Annual Meeting of SME/AIME and 75th Annual Meeting of WAAIME, Feb. 25–28, Denver, Colorado, p.54 1991. [22] D.M. Veneu, T.F.M. Brasil, G.G. DeOliveira Junior, W. Phillips, R.B. Gomides, C. L. Schneider, M.B. DeMello Monte, “Recovery of sulphides as by products from a gold flotation circuit”, in 67th abm International Congrees, pp. 1211-1220, 2012.
  • [23] H. Zhong, Z. Huang, G. Zhao, S. Wang, G. Liu, Z. Cao, “The collecting performance and interaction mechanism of sodium diisobutyl dithiophosphinate in sulfide minerals flotation”, J. Mater. Res. Technol. Vol. 4(2), pp. 151–161, 2015.
  • [24] Ş. B. Aydın, D. Aydın, A. Gül, “Refrakter Olmayan Sülfürlü Altin–Gümüş Cevherinin Flotasyon Davranişinin İncelenmesi” NOHU J. Eng. Sci., Vol. 9(2), pp. 1039-1053, 2020.

The Effect of Aerophine 3418A Collector Dosage on Niğde (Ulukışla-Madenköy) Complex Pb-Zn Sulphide Ore Flotation

Yıl 2021, Cilt 9, Sayı 2, 309 - 313, 28.05.2021
https://doi.org/10.21541/apjes.783976

Öz

In this study, grinding + flotation experiments were performed on the sample of complex Pb-Zn sulphide ore taken from Niğde (Ulukışla-Madenköy) region in Turkey. According to the mineralogical analysis of the ore sample used in experimental studies, it was determined that the ore composition contains calcite, quartz, pyrite, chalcopyrite, hematite, goethite, limonite, gypsum, galena, sphalerite, jarosite, arsenopyrite and marcasite minerals. In addition, Au and Ag grains were found to be inclusions in hematite, goethite and jarosite minerals. The experiments were carried out at a solid ratio of 30%, a flow rate of 10 L/min, a stirring rate of 1250 rpm and pH = 9. In flotation tests, lime is used as the pH regulator, zinc sulphate, sodium silicate as the depressant, sodium isobutyl dithiophosphine as the collector and methyl isobutyl carbinol as the frother. In the flotation studies, the effect of Aerophine 3418A collector dosage on flotation was investigated. As a result, a lead concentrate of 55.13% Pb was obtained and it was found that this concentrate contained 2489 ppm of Ag. The amount of Aerophine 3418A collector was determined as 10 g/t.

Kaynakça

  • [1] S. Temur, “Bolkardağı yöresi (Ulukışla/Niğde) çinko-kurşun yataklarının jeokimyasal incelemesi”. Türkiye Jeoloji Bülteni, Sayı: 35, s: 101–114, 1990.
  • [2] N. Şişman, M.H. Şenocak, S. Dilek, M. Yazgaç, “Bolkardağ yöresinin jeolojisi ve maden yatakları”, MTA Genel Müdürlüğü, Rapor No: 7202, Ankara, (1981).
  • [3] S. Atak, Flotasyon ilkeleri ve uygulaması, İstanbul, 1990.
  • [4] A. M. Gaudin, Flotation, McGraw Hill, New York, 1957.
  • [5] J. S. Laskowski, Frothing in Flotation II, G&B Science, 1998.
  • [6] B.K. Parekh, J. D. Miller, Advances in flotation technology, Soc. for Mining Metallurgy, New York, 1999.
  • [7] L. Leja, Surface Chemistry of Froth Flotation. New York, 1982.
  • [8] N. Arbiter, SME Mineral Processing Handbook, Volume I, New York, 1985.
  • [9] B.A. Wills, Mineral Processing Technology. Fourth Edition,1988.
  • [10] M. Cao, Q. Liu, “Re-examining the functions of zinc sulphate as a selective depressant in differential sulphide flotation the role of coagulation”, Journal of Colloid and Interface Science, vol. 301, pp. 523– 531, 2006.
  • [11] S.M. Bulatovic, Handbook of flotation reagents, chemistry. theory and practice, flotation of sulfide ores, Elsevier, Amsterdam, 2007. [12] S.R. Grano, M. Sollaart, W. Skinner, C.A. Prestidge, J. Ralston, “Surface modifications in the chalcopyrite-sulphite ion system. I. collectorless flotation, XPS and dissolution study” International Journal of Mineral Processing, vol. 50(2), pp. 1-26, 1997.
  • [13] S.R. Grano, N.W. Johnson, J. Ralston, “Control of the solution interaction of meta bisulphite and ethyl xanthate in the flotation of the Hilton ore of Mount Isa Mines Limited, Australia”, Miner. Eng., vol. 10 (1), pp. 17, 1997a.
  • [14] S.R. Grano, C.A. Prestidge, J. Ralston, “Solution interaction of ethyl xanthate and sulphite and its effect on galena flotation and xanthate adsorption”, Int. J. of Miner. Process. Vol. 52, pp. 161-186, 1997b.
  • [15] T.N. Khmeleva, J.K. Chapelet, W.M. Skinner, D.A. Beattie, “Depression mechanisms of sodium bisulphite in the xanthate-induced flotation of copper activated sphalerite”, International Journal of Mineral Processing. Vol.79, pp. 61-75, 2006.
  • [16] N. Acarkan, G. Bulut, A. Gül, O. Kangal, F. Karakaş, O. Kökkılıç, G. Önal, “The effect of collector's type on gold and silver flotation in a complex ore”, Sep. Sci. Technol. Vol. 46, pp. 283–289, 2011.
  • [17] C. Durmaz, “Kuyumculuk kökenli curüflardan fiziksel zenginleştirme yöntemleri ile altının geri kazanımı”, Yüksek Lisans Tezi, İstanbul, 2012. [18] Cytec Mining Chemical Handbook, 2002.
  • [19] A. Ceylan, B. Bulut, “Siirt-Madenköy bakır cevherinin flotasyon yöntemiyle zenginleştirilmesi”, Madencilik, sayı. 55 (1), s. 17-26, 2016.
  • [20] B. B. Yilmaz, “ Niğde (Ulukışla-Madenköy) Bolkardağı sülfürlü kurşun-çinko kompleks cevherinin optimum flotasyon şartlarının belirlenmesi”, Yüksek Lisans Tezi, Konya, 2019.
  • [21] P. Mingione, “Use of AEROPHINE® 3418A promoter for sulphide minerals flotation” in The 120th Annual Meeting of SME/AIME and 75th Annual Meeting of WAAIME, Feb. 25–28, Denver, Colorado, p.54 1991. [22] D.M. Veneu, T.F.M. Brasil, G.G. DeOliveira Junior, W. Phillips, R.B. Gomides, C. L. Schneider, M.B. DeMello Monte, “Recovery of sulphides as by products from a gold flotation circuit”, in 67th abm International Congrees, pp. 1211-1220, 2012.
  • [23] H. Zhong, Z. Huang, G. Zhao, S. Wang, G. Liu, Z. Cao, “The collecting performance and interaction mechanism of sodium diisobutyl dithiophosphinate in sulfide minerals flotation”, J. Mater. Res. Technol. Vol. 4(2), pp. 151–161, 2015.
  • [24] Ş. B. Aydın, D. Aydın, A. Gül, “Refrakter Olmayan Sülfürlü Altin–Gümüş Cevherinin Flotasyon Davranişinin İncelenmesi” NOHU J. Eng. Sci., Vol. 9(2), pp. 1039-1053, 2020.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Tevfik AĞAÇAYAK (Sorumlu Yazar)
Konya Teknik Üniversitesi, Maden Müh. Cevher Hazırlama
0000-0001-8120-8804
Türkiye


Nur YILMAZ Bu kişi benim
Gümüştaş Madencilik ve Ticaret A.Ş
0000-0003-2523-1967
Türkiye

Yayımlanma Tarihi 28 Mayıs 2021
Başvuru Tarihi 22 Ağustos 2020
Kabul Tarihi 16 Nisan 2021
Yayınlandığı Sayı Yıl 2021, Cilt 9, Sayı 2

Kaynak Göster

IEEE T. Ağaçayak ve N. Yılmaz , "The Effect of Aerophine 3418A Collector Dosage on Niğde (Ulukışla-Madenköy) Complex Pb-Zn Sulphide Ore Flotation", Academic Platform - Journal of Engineering and Science, c. 9, sayı. 2, ss. 309-313, May. 2021, doi:10.21541/apjes.783976