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CaCO3 Nanokatkılı Takviye ile FDM Yoluyla Üretilen Sandviç Panellerin Mekanik Performans Optimizasyonu

Year 2025, Volume: 14 Issue: 2, 777 - 793, 30.06.2025
https://doi.org/10.17798/bitlisfen.1592201
https://izlik.org/JA32XX85DB

Abstract

Bu çalışma, değişen CaCO3 nanopartikül konsantrasyonlarına sahip ABS (Akrilonitril Bütadien Stiren) filamentleri kullanılarak üretilen çekirdek-kabuk sandviç panellerinin mekanik performansını araştırmaktadır (%1, 2, 3 ve %5 ağırlık). ABS filamentleri bir ekstrüder kullanılarak üretildi ve bal peteği çekirdek yapıları basmak için Erimiş Biriktirme Modelleme (FDM) işlemi yoluyla çift ekstrüderli bir 3B yazıcıda kullanıldı. Paneller, mukavemet ve deformasyon özelliklerini değerlendirmek için üç noktalı eğme ve sıkıştırma testlerine tabi tutuldu. Sonuçlar, %3 ağırlıkta CaCO3 içeren ABS kompozitlerinin en yüksek ortalama arıza yüklerini sergilediğini ve saf ABS'ye kıyasla mekanik özellikleri önemli ölçüde iyileştirdiğini gösterdi. Ancak, daha yüksek CaCO3 konsantrasyonları (%5 ağırlıkta), nanopartikül aglomerasyonu ve zayıf dispersiyon nedeniyle mukavemetin azalmasına neden oldu ve bu da gerilim yoğunlaştırıcıları ve artan kırılganlığı ortaya çıkardı. Sonlu Elemanlar Analizi (FEA) gerçekleştirildi ve sonuçları deneysel bulgularla yakından uyumluydu ve modelin doğruluğu tespit edildi.

References

  • J. Banhart and H. W. Seeliger, “Aluminium Foam Sandwich Panels: Manufacture,” Metallurgy and Applications. Advanced Engineering Materials, vol. 10, no. 9, pp. 793-802, September 2008, doi.org/10.1002/adem.200800091.
  • J. F. Davalos, P. Qiao, X.F. Xu, J. Robinson and K. E. Barth, “Modeling and characterization of fiber-reinforced plastic honeycomb sandwich panels for highway bridge applications,” Composite Structures, vol. 52, no. 3-4, pp. 441-452, May 2001, doi.org/10.1016/S0263-8223(01)00034-4.
  • T. Sharaf and A. Fam, “Experimental Investigation of Large-Scale Cladding Sandwich Panels under Out-of-Plane Transverse Loading for Building Applications,” Journal of Composites for Construction, vol. 15, no. 3, pp. 422-430, Oct. 2010, doi.org/10.1061/(ASCE)CC.1943-5614.0000176.
  • W. Ahmed, S. Ahmed, F. Alnajjar and E. Zaneldin, “Mechanical performance of three-dimensional printed sandwich composite with a high-flexible core,” Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, vol. 235, no. 6, pp. 1382-1400, April 2021, doi.org/10.1177/14644207211011729.
  • K. Sugiyama, R. Matsuzaki, M. Ueda, A. Todoroki and Y. Hirano, “3D printing of composite sandwich structures using continuous carbon fiber and fiber tension,” Composites Part A: Applied Science and Manufacturing, vol. 113, pp. 114-121, October 2018, doi.org/10.1016/j.compositesa.2018.07.029.
  • X. Wang, M. Jiang, Z. Zhou, J. Gou and D. Hui, “3D printing of polymer matrix composites: A review and prospective,” Composites Part B: Engineering, vol. 110, pp. 442-458, February 2017, doi.org/10.1016/j.compositesb.2016.11.034.
  • S. F. Kabir, K. Mathur and A. F. M. Seyam, “A critical review on 3D printed continuous fiber-reinforced composites: History, mechanism, materials and properties,” Composite Structures, vol. 232, 111476, January 2020, doi.org/10.1016/j.compstruct.2019.111476.
  • Z. Quan, A. Wu, M. Keefe, X. Qin, J. Yu, J. Suhr, J. H. Byun, B. S. Kim and T. W. Chou, “Additive manufacturing of multi-directional preforms for composites: opportunities and challenges,” Materials Today, vol. 18, no. 9, pp. 503-512, November 2015, doi.org/10.1016/j.mattod.2015.05.001.
  • L. Sang, S. Han, X. Peng, X. Jian and J. Wang, “Development of 3D-printed basalt fiber reinforced thermoplastic honeycombs with enhanced compressive mechanical properties” Composites Part A: Applied Science and Manufacturing, vol. 125, 105518, October 2019, doi.org/10.1016/j.compositesa.2019.105518.
  • K. Çava, “Investigation of the usage characteristics of FDM type 3 dimensional printer thermoplastic honeycomb / auxetic core material design, production and sandwich composites,” Karadeniz Teknik Üniversitesi, Fen Bilimleri Enstitüsü, Metalurji ve Malzeme Mühendisliği Ana Bilim Dalı, p. 67, 2019.
  • S. S. Yao, F. L. Jin, K. Y. Rhee, D. Hui and S. J. Park, “Recent advances in carbon fiber-reinforced thermoplastic composites: A review,” Composites Part B: Engineering, vol. 142, no. 1, pp. 241-250, June 2018, doi.org/10.1016/j.compositesb.2017.12.007.
  • B. Wetzel, F. Haupert and M. Q. Zhang, “Epoxy nanocomposites with high mechanical and tribological performance,” Composites Science and Technology, vol. 63, no. 14, pp. 2055-2067, November 2003, doi.org/10.1016/S0266-3538(03)00115-5.
  • B. Wetzel, P. Rosso, F. Haupert and K. Friedrich, “Epoxy nanocomposites–fracture and toughening mechanisms,” Engineering Fracture Mechanics, vol. 73, no. 16, pp. 2375-2398, November 2006, doi.org/10.1016/j.engfracmech.2006.05.018.
  • A. Christy, R. Purohit, R. S. Rana, S. K. Singh and S. Rana, “Development and analysis of epoxy/nano SiO2 polymer matrix composite fabricated by ultrasonic vibration assisted processing,” Materials Today: Proceedings, vol. 4, no. 2, pp. 2748-2754, April 2017, doi.org/10.1016/j.matpr.2017.02.152.
  • P. A. Zapata, H. Palza, B. Díaz, A. Armijo, F. Sepúlveda, J. A. Ortiz, M. P. Ramírez and C. Oyarzún, “Effect of CaCO3 nanoparticles on the mechanical and photo-degradation properties of LDPE,” Molecules, vol. 24, no. 1, 126, December 2018, doi.org/10.3390/molecules24010126.
  • R. Bai, J. Guo, Z. Lei, D. Liu, Y. Ma and C. Yan, “Compression after impact behavior of composite foam-core sandwich panels,” Composite Structures, vol. 225, 111181, October 2019, doi.org/10.1016/j.compstruct.2019.111181.
  • G. Sun, X. Huo, D. Chen and Q. Li, “Experimental and numerical study on honeycomb sandwich panels under bending and in-panel compression,” Materials & Design, vol. 133, pp. 154-168, November 2017, doi.org/10.1016/j.matdes.2017.07.057.
  • C. C. Foo, G. B. Chai and L. K. Seah, “Mechanical properties of Nomex material and Nomex honeycomb structure,” Composite Structures, vol. 80, no. 4, pp. 588-594, October 2007, doi.org/10.1016/j.compstruct.2006.07.010.
  • M. Seyedzavvar and C. Boğa, “A study on the effects of internal architecture on the mechanical properties and mixed-mode fracture behavior of 3D printed CaCO3/ABS nanocomposite samples,” Rapid Prototyping Journal, vol. 29, no. 1, pp. 185-206, January 2023, doi.org/10.1108/RPJ-09-2021-0244.
  • W.Y. Wang, G. Q. Wang, X. F. Zeng, J. R. Song, and J. F. Chen, “Study on the micro structure and mechanical properties of nano-CaCO3/ABS composites,” Solid State Phenomena, pp. 1459–1462, March 2007, doi.org/ 10.4028/www.scientific.net/SSP.121-123.1459.
  • J. J. Zhang, J. L. Zhao, K. Li, S. Zhang, and Y. Ma, “High impact toughness ABS/CaCO3 nanocomposites prepared through pressure induced flow moulding.” Applied Mechanics and Materials, pp. 175–178, October 2015, doi.org/10.4028/www.scientific.net/amm.799-800.175.
  • D. Vrsaljko, I. Šmit and V. Kovačević, “Effect of calcium carbonate particle size and surface pretreatment on polyurethane composite Part 2 - Phase behaviour.” Materials Research Innovations, vol. 12, pp. 72‒77, 2008, DOI: 10.1179/143307508X304264.
  • D. Eirasa and L. A. Pessan, “Mechanical properties of polypropylene/calcium carbonate nanocomposites.” Materials Research, vol. 12, pp. 517‒522, 2009, DOI: 10.1590/s1516-14392009000400023.
  • S. S. Sonawane, S. Mishra, N. G. Shimpi, “Effect of nano-CaCO3 mechanical and thermal properties of polyamide Nanocomposites.” Polymer - Plastics Technology and Engineering, vol. 49, pp. 38–44, 2010, DOI: 10.1080/03602550903204220.
  • T. Bhatnagar, P. Baxi, K. Sharma, G. Nijhawan, S. Jugran, K. Satyanarayana, L. Sharma, M. Alhadrawi, “Unlocking the strength of nanocomposites: Mitigating the ımpact of nanoparticle agglomeration on tensile performance.” E3S Web of Conferences, SNE2-2024, 588, 2024, 01007. Doi: 10.1051/e3sconf/202458801007.
  • Q. Chen, S. Gong, J. Moll, D. Zhao, S. K. Kumar, R. H. Colby, “Mechanical reinforcement of polymer nanocomposites from percolation of a nanoparticle network.” ACS Macro Letters, vol. 4(4), pp. 398–402, 2015, Doi: 10.1021/acsmacrolett.5b00002.
  • S. P. Kautilya, B. S. Dhaval, J. J. Shashikant, K. A. Faisal and K. Mohamed, “Effect of process parameters on the mechanical performance of FDM printed carbon fiber reinforced PETG,” Journal of Materials Research and Technology, vol. 30, pp. 8006-8018, May–June 2024, doi.org/10.1016/j.jmrt.2024.05.184.
  • S. Meng, H. He, Y. Jia, P. Yu, B. Huang and J. Chen, “Effect of nanoparticles on the mechanical properties of acrylonitrile–butadiene–styrene specimens fabricated by fused deposition modeling” Journal of Applied Polzmer Science, October 2017. Doi: 10.1002/APP.44470.

Mechanical Performance Optimization of ABS Core-Shell Sandwich Panels Fabricated via FDM with CaCO3 Nanoadditive Reinforcement

Year 2025, Volume: 14 Issue: 2, 777 - 793, 30.06.2025
https://doi.org/10.17798/bitlisfen.1592201
https://izlik.org/JA32XX85DB

Abstract

This study explores the mechanical performance of core-shell sandwich panels fabricated using ABS (Acrylonitrile Butadiene Styrene) filaments with varying concentrations of CaCO3 nanoparticles (1, 2, 3, and 5wt%). The ABS filaments were produced using an extruder and utilized in a dual extruder 3D printer via the Fused Deposition Modeling (FDM) process to print honeycomb core structures. The panels were subjected to three-point bending and compression tests to assess their strength and deformation characteristics. The results indicated that the panels with 3 wt% CaCO3 nanoparticles achieved the highest average failure loads, enhancing the mechanical properties significantly over pure ABS. Specifically, the maximum bending stress for the 3 wt% added nanoparticle sample was recorded at 33.23 MPa. Conversely, increasing the CaCO3 concentration to 5 wt% diminished the strength, as nanoparticle agglomeration and poor dispersion acted as stress concentrators and enhanced brittleness. However, higher CaCO3 concentrations (5wt%) led to reduced strength due to nanoparticle agglomeration and poor dispersion, which introduced stress concentrators and increased brittleness. Finite Element Analysis (FEA) was performed, and its results closely aligned with the experimental findings, validating the accuracy of the model.

Ethical Statement

The study is complied with research and publication ethics.

Supporting Institution

Adana Alparslan Turkes Science and Technology University

Thanks

This work was supported by Scientific Research Coordination Unit of Adana Alparslan Turkes Science and Technology University with project number of 20332003.

References

  • J. Banhart and H. W. Seeliger, “Aluminium Foam Sandwich Panels: Manufacture,” Metallurgy and Applications. Advanced Engineering Materials, vol. 10, no. 9, pp. 793-802, September 2008, doi.org/10.1002/adem.200800091.
  • J. F. Davalos, P. Qiao, X.F. Xu, J. Robinson and K. E. Barth, “Modeling and characterization of fiber-reinforced plastic honeycomb sandwich panels for highway bridge applications,” Composite Structures, vol. 52, no. 3-4, pp. 441-452, May 2001, doi.org/10.1016/S0263-8223(01)00034-4.
  • T. Sharaf and A. Fam, “Experimental Investigation of Large-Scale Cladding Sandwich Panels under Out-of-Plane Transverse Loading for Building Applications,” Journal of Composites for Construction, vol. 15, no. 3, pp. 422-430, Oct. 2010, doi.org/10.1061/(ASCE)CC.1943-5614.0000176.
  • W. Ahmed, S. Ahmed, F. Alnajjar and E. Zaneldin, “Mechanical performance of three-dimensional printed sandwich composite with a high-flexible core,” Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, vol. 235, no. 6, pp. 1382-1400, April 2021, doi.org/10.1177/14644207211011729.
  • K. Sugiyama, R. Matsuzaki, M. Ueda, A. Todoroki and Y. Hirano, “3D printing of composite sandwich structures using continuous carbon fiber and fiber tension,” Composites Part A: Applied Science and Manufacturing, vol. 113, pp. 114-121, October 2018, doi.org/10.1016/j.compositesa.2018.07.029.
  • X. Wang, M. Jiang, Z. Zhou, J. Gou and D. Hui, “3D printing of polymer matrix composites: A review and prospective,” Composites Part B: Engineering, vol. 110, pp. 442-458, February 2017, doi.org/10.1016/j.compositesb.2016.11.034.
  • S. F. Kabir, K. Mathur and A. F. M. Seyam, “A critical review on 3D printed continuous fiber-reinforced composites: History, mechanism, materials and properties,” Composite Structures, vol. 232, 111476, January 2020, doi.org/10.1016/j.compstruct.2019.111476.
  • Z. Quan, A. Wu, M. Keefe, X. Qin, J. Yu, J. Suhr, J. H. Byun, B. S. Kim and T. W. Chou, “Additive manufacturing of multi-directional preforms for composites: opportunities and challenges,” Materials Today, vol. 18, no. 9, pp. 503-512, November 2015, doi.org/10.1016/j.mattod.2015.05.001.
  • L. Sang, S. Han, X. Peng, X. Jian and J. Wang, “Development of 3D-printed basalt fiber reinforced thermoplastic honeycombs with enhanced compressive mechanical properties” Composites Part A: Applied Science and Manufacturing, vol. 125, 105518, October 2019, doi.org/10.1016/j.compositesa.2019.105518.
  • K. Çava, “Investigation of the usage characteristics of FDM type 3 dimensional printer thermoplastic honeycomb / auxetic core material design, production and sandwich composites,” Karadeniz Teknik Üniversitesi, Fen Bilimleri Enstitüsü, Metalurji ve Malzeme Mühendisliği Ana Bilim Dalı, p. 67, 2019.
  • S. S. Yao, F. L. Jin, K. Y. Rhee, D. Hui and S. J. Park, “Recent advances in carbon fiber-reinforced thermoplastic composites: A review,” Composites Part B: Engineering, vol. 142, no. 1, pp. 241-250, June 2018, doi.org/10.1016/j.compositesb.2017.12.007.
  • B. Wetzel, F. Haupert and M. Q. Zhang, “Epoxy nanocomposites with high mechanical and tribological performance,” Composites Science and Technology, vol. 63, no. 14, pp. 2055-2067, November 2003, doi.org/10.1016/S0266-3538(03)00115-5.
  • B. Wetzel, P. Rosso, F. Haupert and K. Friedrich, “Epoxy nanocomposites–fracture and toughening mechanisms,” Engineering Fracture Mechanics, vol. 73, no. 16, pp. 2375-2398, November 2006, doi.org/10.1016/j.engfracmech.2006.05.018.
  • A. Christy, R. Purohit, R. S. Rana, S. K. Singh and S. Rana, “Development and analysis of epoxy/nano SiO2 polymer matrix composite fabricated by ultrasonic vibration assisted processing,” Materials Today: Proceedings, vol. 4, no. 2, pp. 2748-2754, April 2017, doi.org/10.1016/j.matpr.2017.02.152.
  • P. A. Zapata, H. Palza, B. Díaz, A. Armijo, F. Sepúlveda, J. A. Ortiz, M. P. Ramírez and C. Oyarzún, “Effect of CaCO3 nanoparticles on the mechanical and photo-degradation properties of LDPE,” Molecules, vol. 24, no. 1, 126, December 2018, doi.org/10.3390/molecules24010126.
  • R. Bai, J. Guo, Z. Lei, D. Liu, Y. Ma and C. Yan, “Compression after impact behavior of composite foam-core sandwich panels,” Composite Structures, vol. 225, 111181, October 2019, doi.org/10.1016/j.compstruct.2019.111181.
  • G. Sun, X. Huo, D. Chen and Q. Li, “Experimental and numerical study on honeycomb sandwich panels under bending and in-panel compression,” Materials & Design, vol. 133, pp. 154-168, November 2017, doi.org/10.1016/j.matdes.2017.07.057.
  • C. C. Foo, G. B. Chai and L. K. Seah, “Mechanical properties of Nomex material and Nomex honeycomb structure,” Composite Structures, vol. 80, no. 4, pp. 588-594, October 2007, doi.org/10.1016/j.compstruct.2006.07.010.
  • M. Seyedzavvar and C. Boğa, “A study on the effects of internal architecture on the mechanical properties and mixed-mode fracture behavior of 3D printed CaCO3/ABS nanocomposite samples,” Rapid Prototyping Journal, vol. 29, no. 1, pp. 185-206, January 2023, doi.org/10.1108/RPJ-09-2021-0244.
  • W.Y. Wang, G. Q. Wang, X. F. Zeng, J. R. Song, and J. F. Chen, “Study on the micro structure and mechanical properties of nano-CaCO3/ABS composites,” Solid State Phenomena, pp. 1459–1462, March 2007, doi.org/ 10.4028/www.scientific.net/SSP.121-123.1459.
  • J. J. Zhang, J. L. Zhao, K. Li, S. Zhang, and Y. Ma, “High impact toughness ABS/CaCO3 nanocomposites prepared through pressure induced flow moulding.” Applied Mechanics and Materials, pp. 175–178, October 2015, doi.org/10.4028/www.scientific.net/amm.799-800.175.
  • D. Vrsaljko, I. Šmit and V. Kovačević, “Effect of calcium carbonate particle size and surface pretreatment on polyurethane composite Part 2 - Phase behaviour.” Materials Research Innovations, vol. 12, pp. 72‒77, 2008, DOI: 10.1179/143307508X304264.
  • D. Eirasa and L. A. Pessan, “Mechanical properties of polypropylene/calcium carbonate nanocomposites.” Materials Research, vol. 12, pp. 517‒522, 2009, DOI: 10.1590/s1516-14392009000400023.
  • S. S. Sonawane, S. Mishra, N. G. Shimpi, “Effect of nano-CaCO3 mechanical and thermal properties of polyamide Nanocomposites.” Polymer - Plastics Technology and Engineering, vol. 49, pp. 38–44, 2010, DOI: 10.1080/03602550903204220.
  • T. Bhatnagar, P. Baxi, K. Sharma, G. Nijhawan, S. Jugran, K. Satyanarayana, L. Sharma, M. Alhadrawi, “Unlocking the strength of nanocomposites: Mitigating the ımpact of nanoparticle agglomeration on tensile performance.” E3S Web of Conferences, SNE2-2024, 588, 2024, 01007. Doi: 10.1051/e3sconf/202458801007.
  • Q. Chen, S. Gong, J. Moll, D. Zhao, S. K. Kumar, R. H. Colby, “Mechanical reinforcement of polymer nanocomposites from percolation of a nanoparticle network.” ACS Macro Letters, vol. 4(4), pp. 398–402, 2015, Doi: 10.1021/acsmacrolett.5b00002.
  • S. P. Kautilya, B. S. Dhaval, J. J. Shashikant, K. A. Faisal and K. Mohamed, “Effect of process parameters on the mechanical performance of FDM printed carbon fiber reinforced PETG,” Journal of Materials Research and Technology, vol. 30, pp. 8006-8018, May–June 2024, doi.org/10.1016/j.jmrt.2024.05.184.
  • S. Meng, H. He, Y. Jia, P. Yu, B. Huang and J. Chen, “Effect of nanoparticles on the mechanical properties of acrylonitrile–butadiene–styrene specimens fabricated by fused deposition modeling” Journal of Applied Polzmer Science, October 2017. Doi: 10.1002/APP.44470.
There are 28 citations in total.

Details

Primary Language English
Subjects Solid Mechanics, Optimization Techniques in Mechanical Engineering, Numerical Methods in Mechanical Engineering
Journal Section Research Article
Authors

Onur Selek 0009-0006-1111-8081

Cem Boğa 0000-0002-9467-1141

Mirsadegh Seyedzavvar 0000-0002-3324-7689

Submission Date November 27, 2024
Acceptance Date April 10, 2025
Early Pub Date June 27, 2025
Publication Date June 30, 2025
DOI https://doi.org/10.17798/bitlisfen.1592201
IZ https://izlik.org/JA32XX85DB
Published in Issue Year 2025 Volume: 14 Issue: 2

Cite

IEEE [1]O. Selek, C. Boğa, and M. Seyedzavvar, “Mechanical Performance Optimization of ABS Core-Shell Sandwich Panels Fabricated via FDM with CaCO3 Nanoadditive Reinforcement”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 14, no. 2, pp. 777–793, June 2025, doi: 10.17798/bitlisfen.1592201.

Bitlis Eren University
Journal of Science Editor
Bitlis Eren University Graduate Institute
Bes Minare Mah. Ahmet Eren Bulvari, Merkez Kampus, 13000 BITLIS