Year 2025,
Volume: 14 Issue: 4, 2244 - 2262, 31.12.2025
Ecem Torun
,
Ali Yaraş
,
Bilal Demirel
,
Bilal Kurşuncu
References
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C. Vasile and M. Pascu, Practical guide to polyethylene. iSmithers Rapra Publishing, 2005.
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J. J. Cheng, “Mechanical and chemical properties of high density polyethylene: effects of microstructure on creep characteristics,” University of Waterloo, Doctor of Philosophy, Canada, 2008.
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A. H. Awad and M. H. Abdellatif, “Assessment of mechanical and physical properties of LDPE reinforced with marble dust,” Compos. Part B Eng., p. 106948, 2019.
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S. B. Djaffar and A. Kheirreddine, “Effect of Ethylene Vinyl Acetate (EVA) Polymer on Rheological Properties of Bitumen Before and After Ageing,” 3rd Conference on Mechanics of Materials and Structures, November 13–15, 2019, Marrakesh, Morocco.
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I. Suárez-Ruiz and J. C. Crelling, Applied coal petrology: the role of petrology in coal utilization. Academic Press, 2008.
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R. H. Elleithy, I. Ali, M. A. Ali, and S. M. Al‐Zahrani, “High density polyethylene/micro calcium carbonate composites: A study of the morphological, thermal, and viscoelastic properties,” J. Appl. Polym. Sci., vol. 117, no. 4, pp. 2413–2421, 2010.
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B. Trivedi, Maleic anhydride. Springer Science & Business Media, 2013.
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S. Can and A. E. Yılmaz, “Elektrostatik yük boşalımı: elektronik üretim sektöründeki etkileri ve alınan koruyucu önlemler üzerine bir inceleme,” Gazi Univ. J. Sci. Part C Des. Technol., vol. 3, no. 2, pp. 443–455, 2015.
-
M. Burunkaya, “Statik Elektriğe Karşı Koruma için Güvenli Bir Topraklama Sistemi ve Antistatik Çalışma İstasyonunun Kurulması,” Politek. Derg., vol. 11, no. 2, pp. 93–98, 2008.
-
J. E. Vinson and J. J. Liou, “Electrostatic discharge in semiconductor devices: protection techniques,” Proc. IEEE, vol. 88, no. 12, pp. 1878–1902, 2000.
-
K. Nasouri and A. M. Shoushtari, “Designing, modeling and manufacturing of lightweight carbon nanotubes/polymer composite nanofibers for electromagnetic interference shielding application,” Compos. Sci. Technol., vol. 145, pp. 46–54, 2017.
-
M. Arabi, M. Ghaedi, and A. Ostovan, “Development of dummy molecularly imprinted based on functionalized silica nanoparticles for determination of acrylamide in processed food by matrix solid phase dispersion,” Food Chem., vol. 210, pp. 78–84, 2016.
-
L. Wimalasuriya, C. Gunasekara, D. Robert, S. Setunge, and B. O’Donnell, “Waste-Derived High-Density Polyethylene-Glass Composites: A Pathway to Sustainable Structural Materials,” Polymers (Basel), vol. 17, no. 1, p. 35, 2024.
-
T. Guadie and S. Mesfin, “Study on the Mechanical Properties of Water Hyacinth Fiber Reinforced High Density Polyethylene Composite,” Eur. Online J. Nat. Soc. Sci., vol. 10, no. 3, p. 379, 2021.
-
P. Achuthamenon Sylajakumari, R. Ramakrishnasamy, and G. Palaniappan, “Taguchi grey relational analysis for multi-response optimization of wear in co-continuous composite,” Materials (Basel), vol. 11, no. 9, p. 1743, 2018.
-
N. Vidakis et al., “High-density polyethylene/carbon black composites in material extrusion additive manufacturing: conductivity, thermal, rheological, and mechanical responses,” Polymers (Basel), vol. 15, no. 24, p. 4717, 2023.
-
G. J. Lee, K. Do Suh, and S. S. Im, “Study of electrical phenomena in carbon black–filled HDPE composite,” Polym. Eng. Sci., vol. 38, no. 3, pp. 471–477, 1998.
-
L. Travaš, M. Rujnić Havstad, and A. Pilipović, “Optimization of Thermal Conductivity and Tensile properties of high-density polyethylene by addition of expanded graphite and Boron Nitride,” Polymers (Basel), vol. 15, no. 17, p. 3645, 2023.
-
W. Zheng, X. Lu, and S. Wong, “Electrical and mechanical properties of expanded graphite‐reinforced high‐density polyethylene,” J. Appl. Polym. Sci., vol. 91, no. 5, pp. 2781–2788, 2004.
-
Q. Gao, J. Liu, and X. Liu, “Electrical conductivity and rheological properties of carbon black based conductive polymer composites prior to and after annealing,” Polym. Polym. Compos., vol. 29, no. 9_suppl, pp. S288–S295, 2021.
-
C. Barone, S. Pagano, and H. C. Neitzert, “Transport and noise spectroscopy of MWCNT/HDPE composites with different nanotube concentrations,” J. Appl. Phys., vol. 110, no. 11, 2011.
-
S. Kwon et al., “Tensile property and interfacial dewetting in the calcite filled HDPE, LDPE, and LLDPE composites,” Polymer (Guildf)., vol. 43, no. 25, pp. 6901–6909, 2002.
-
D. Viljoen, M. Fischer, I. Kühnert, and J. Labuschagné, “The tensile behaviour of highly filled high-density polyethylene quaternary composites: weld-line effects, DIC curiosities and shifted deformation mechanisms,” Polymers (Basel), vol. 13, no. 4, p. 527, 2021.
-
“High Density polyethylene (HDPE) Technical Data Sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.chemorbis.com/marketplace/tmDocument.do?method=showTmDoc&tmProductSpecId=1281
-
“Ethylene Vinyl Acetate Copolymer Product Datasheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://exxonmobilchemical.ulprospector.com/datasheet.aspx?CULTURE=en-US&E=243661&FMT=PDF&I=58933&PS=PE&utm
-
“Graphite product data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.asbury.com/KsandCore/media/document-library/Graphite%20PDS%20Sheets/A625-PDS.pdf
-
“Calcium carbonate product technical data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.lafarge.com.ng/sites/nigeria/files/docs/product-technical-data-gcc.pdf
-
“Maleic anhydride safety data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.sigmaaldrich.com/TR/en/sds/sial/63200
-
M. S. Hassanien and A. I. Seedahmed, “Mechanical and rheological properties of polypropylene (PP)/linear low density polyethylene (LDPE) blend filled with talc and calcium carbonate compositions,” Int. J. Eng. Sci. Res. Technol., vol. 2277, pp. 383–387, 2015.
-
A. Mahfoudh, A. Cloutier, and D. Rodrigue, “Characterization of UHMWPE/wood composites produced via dry‐blending and compression molding,” Polym. Compos., vol. 34, no. 4, pp. 510–516, 2013.
-
B. N. R. Kumar, B. Suresha, and M. Venkataramareddy, “Effect of particulate fillers on mechanical and abrasive wear behaviour of polyamide 66/polypropylene nanocomposites,” Mater. Des., vol. 30, no. 9, pp. 3852–3858, 2009.
-
G. Srinath and R. Gnanamoorthy, “Sliding wear performance of polyamide 6–clay nanocomposites in water,” Compos. Sci. Technol., vol. 67, no. 3–4, pp. 399–405, 2007.
-
R. H. Myers, D. C. Montgomery, and C. M. Anderson-Cook, Response surface methodology: process and product optimization using designed experiments. John Wiley & Sons, 2016.
Statistical Analysis of Physico-Mechanical Properties and Electrical Conductivity of High Density Polyethylene Composites
Year 2025,
Volume: 14 Issue: 4, 2244 - 2262, 31.12.2025
Ecem Torun
,
Ali Yaraş
,
Bilal Demirel
,
Bilal Kurşuncu
Abstract
Polymer composites are widely employed in engineering and industrial applications owing to their tunable properties, lightweight structure, and enhanced performance achieved through the incorporation of fillers and additives. High-density polyethylene (HDPE) composites are of particular interest due to their chemical resistance and mechanical strength; however, their non-polar nature often results in weak interfacial bonding with polar additives. This challenge highlights the need for systematic investigations of filler-matrix interactions.
This study examines the mechanical and electrical performance of HDPE-based composites incorporating calcite, graphite, ethyl vinyl acetate (EVA), elastomer, and crosslinker. The significance of this work lies in its multi-factorial approach, which evaluates the synergistic effects of multiple additives rather than relying on single-variable analyses. A total of twenty-six HDPE composite samples were fabricated using extrusion and injection molding processes designed through a statistical experimental plan. Samples were characterized by tensile strength, hardness, and electrical conductivity tests, alongside surface morphology analyses (SEM-EDS). Statistical evaluation was performed using analysis of variance (ANOVA) and response surface methodology (RSM) to determine the significance of parameters and their interactions. Results revealed that yield strength was best explained by the second-order model (quadratic), hardness by the first-order model (linear), while electrical conductivity did not fit the tested models. SEM-EDS further indicated poor dispersion and weak interfacial bonding between the HDPE matrix and additives. In conclusion, the findings emphasize the critical influence of additive type and proportion on the performance of HDPE composites.
Ethical Statement
The study is complied with research and publication ethics.
Thanks
This article was produced from the master's thesis of Ecem Torun (Aydın).
References
-
C. Vasile and M. Pascu, Practical guide to polyethylene. iSmithers Rapra Publishing, 2005.
-
J. J. Cheng, “Mechanical and chemical properties of high density polyethylene: effects of microstructure on creep characteristics,” University of Waterloo, Doctor of Philosophy, Canada, 2008.
-
A. H. Awad and M. H. Abdellatif, “Assessment of mechanical and physical properties of LDPE reinforced with marble dust,” Compos. Part B Eng., p. 106948, 2019.
-
S. B. Djaffar and A. Kheirreddine, “Effect of Ethylene Vinyl Acetate (EVA) Polymer on Rheological Properties of Bitumen Before and After Ageing,” 3rd Conference on Mechanics of Materials and Structures, November 13–15, 2019, Marrakesh, Morocco.
-
I. Suárez-Ruiz and J. C. Crelling, Applied coal petrology: the role of petrology in coal utilization. Academic Press, 2008.
-
R. H. Elleithy, I. Ali, M. A. Ali, and S. M. Al‐Zahrani, “High density polyethylene/micro calcium carbonate composites: A study of the morphological, thermal, and viscoelastic properties,” J. Appl. Polym. Sci., vol. 117, no. 4, pp. 2413–2421, 2010.
-
B. Trivedi, Maleic anhydride. Springer Science & Business Media, 2013.
-
S. Can and A. E. Yılmaz, “Elektrostatik yük boşalımı: elektronik üretim sektöründeki etkileri ve alınan koruyucu önlemler üzerine bir inceleme,” Gazi Univ. J. Sci. Part C Des. Technol., vol. 3, no. 2, pp. 443–455, 2015.
-
M. Burunkaya, “Statik Elektriğe Karşı Koruma için Güvenli Bir Topraklama Sistemi ve Antistatik Çalışma İstasyonunun Kurulması,” Politek. Derg., vol. 11, no. 2, pp. 93–98, 2008.
-
J. E. Vinson and J. J. Liou, “Electrostatic discharge in semiconductor devices: protection techniques,” Proc. IEEE, vol. 88, no. 12, pp. 1878–1902, 2000.
-
K. Nasouri and A. M. Shoushtari, “Designing, modeling and manufacturing of lightweight carbon nanotubes/polymer composite nanofibers for electromagnetic interference shielding application,” Compos. Sci. Technol., vol. 145, pp. 46–54, 2017.
-
M. Arabi, M. Ghaedi, and A. Ostovan, “Development of dummy molecularly imprinted based on functionalized silica nanoparticles for determination of acrylamide in processed food by matrix solid phase dispersion,” Food Chem., vol. 210, pp. 78–84, 2016.
-
L. Wimalasuriya, C. Gunasekara, D. Robert, S. Setunge, and B. O’Donnell, “Waste-Derived High-Density Polyethylene-Glass Composites: A Pathway to Sustainable Structural Materials,” Polymers (Basel), vol. 17, no. 1, p. 35, 2024.
-
T. Guadie and S. Mesfin, “Study on the Mechanical Properties of Water Hyacinth Fiber Reinforced High Density Polyethylene Composite,” Eur. Online J. Nat. Soc. Sci., vol. 10, no. 3, p. 379, 2021.
-
P. Achuthamenon Sylajakumari, R. Ramakrishnasamy, and G. Palaniappan, “Taguchi grey relational analysis for multi-response optimization of wear in co-continuous composite,” Materials (Basel), vol. 11, no. 9, p. 1743, 2018.
-
N. Vidakis et al., “High-density polyethylene/carbon black composites in material extrusion additive manufacturing: conductivity, thermal, rheological, and mechanical responses,” Polymers (Basel), vol. 15, no. 24, p. 4717, 2023.
-
G. J. Lee, K. Do Suh, and S. S. Im, “Study of electrical phenomena in carbon black–filled HDPE composite,” Polym. Eng. Sci., vol. 38, no. 3, pp. 471–477, 1998.
-
L. Travaš, M. Rujnić Havstad, and A. Pilipović, “Optimization of Thermal Conductivity and Tensile properties of high-density polyethylene by addition of expanded graphite and Boron Nitride,” Polymers (Basel), vol. 15, no. 17, p. 3645, 2023.
-
W. Zheng, X. Lu, and S. Wong, “Electrical and mechanical properties of expanded graphite‐reinforced high‐density polyethylene,” J. Appl. Polym. Sci., vol. 91, no. 5, pp. 2781–2788, 2004.
-
Q. Gao, J. Liu, and X. Liu, “Electrical conductivity and rheological properties of carbon black based conductive polymer composites prior to and after annealing,” Polym. Polym. Compos., vol. 29, no. 9_suppl, pp. S288–S295, 2021.
-
C. Barone, S. Pagano, and H. C. Neitzert, “Transport and noise spectroscopy of MWCNT/HDPE composites with different nanotube concentrations,” J. Appl. Phys., vol. 110, no. 11, 2011.
-
S. Kwon et al., “Tensile property and interfacial dewetting in the calcite filled HDPE, LDPE, and LLDPE composites,” Polymer (Guildf)., vol. 43, no. 25, pp. 6901–6909, 2002.
-
D. Viljoen, M. Fischer, I. Kühnert, and J. Labuschagné, “The tensile behaviour of highly filled high-density polyethylene quaternary composites: weld-line effects, DIC curiosities and shifted deformation mechanisms,” Polymers (Basel), vol. 13, no. 4, p. 527, 2021.
-
“High Density polyethylene (HDPE) Technical Data Sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.chemorbis.com/marketplace/tmDocument.do?method=showTmDoc&tmProductSpecId=1281
-
“Ethylene Vinyl Acetate Copolymer Product Datasheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://exxonmobilchemical.ulprospector.com/datasheet.aspx?CULTURE=en-US&E=243661&FMT=PDF&I=58933&PS=PE&utm
-
“Graphite product data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.asbury.com/KsandCore/media/document-library/Graphite%20PDS%20Sheets/A625-PDS.pdf
-
“Calcium carbonate product technical data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.lafarge.com.ng/sites/nigeria/files/docs/product-technical-data-gcc.pdf
-
“Maleic anhydride safety data sheet.” Accessed: Aug. 21, 2025. [Online]. Available: https://www.sigmaaldrich.com/TR/en/sds/sial/63200
-
M. S. Hassanien and A. I. Seedahmed, “Mechanical and rheological properties of polypropylene (PP)/linear low density polyethylene (LDPE) blend filled with talc and calcium carbonate compositions,” Int. J. Eng. Sci. Res. Technol., vol. 2277, pp. 383–387, 2015.
-
A. Mahfoudh, A. Cloutier, and D. Rodrigue, “Characterization of UHMWPE/wood composites produced via dry‐blending and compression molding,” Polym. Compos., vol. 34, no. 4, pp. 510–516, 2013.
-
B. N. R. Kumar, B. Suresha, and M. Venkataramareddy, “Effect of particulate fillers on mechanical and abrasive wear behaviour of polyamide 66/polypropylene nanocomposites,” Mater. Des., vol. 30, no. 9, pp. 3852–3858, 2009.
-
G. Srinath and R. Gnanamoorthy, “Sliding wear performance of polyamide 6–clay nanocomposites in water,” Compos. Sci. Technol., vol. 67, no. 3–4, pp. 399–405, 2007.
-
R. H. Myers, D. C. Montgomery, and C. M. Anderson-Cook, Response surface methodology: process and product optimization using designed experiments. John Wiley & Sons, 2016.