A New Generation Hybrid Supercapacitor: GO/ZnO

Cihat Aydın; Oktay Emre Yıldız

doi:10.17798/bitlisfen.1743478

A New Generation Hybrid Supercapacitor: GO/ZnO

Abstract

Supercapacitors are energy storage materials used to store higher and larger amounts of charge than known capacitors. Energy density can be increased. Capacity and energy amount can be increased by increasing the amount of surface area used. In this study, graphene oxide (GO) synthesised by Modified Hummers method was reinforced into ZnO synthesised by sol-gel method and hybrid material with supercapacitive properties was produced. XRD, SEM, FTIR, DTA-TGA, UV- Vis-NIR and CV analyses were performed on the produced hybrid nanosupercapacitive composites. It was observed that ZnO particles were located between GO layers and were nano-sized. XRD diffractograms showed hexagonal ZnO crystallographic planes (103), (200), (112), (201), (004) and (202). DTA analyses revealed endothermic peaks due to water loss and organic decomposition. FT-IR analyses confirmed the presence of ZnO and GO in the structure. CV measurements indicate rapid charge transfer at the electrode-electrolyte interface.

Keywords

Supporting Institution

the Management Unit of Scientific Research Projects of Mersin University (BAP) (Project Number: 2020-1- TP2- 4045).

Project Number

the Management Unit of Scientific Research Projects of Mersin University (BAP) (Project Number: 2020-1- TP2- 4045).

Ethical Statement

The study is complied with research and publication ethics.

Thanks

the Management Unit of Scientific Research Projects of Mersin University (BAP) (Project Number: 2020-1- TP2- 4045).

References

Zhang, F., Zhang, T., Yang, X., Zhang, L., Leng, K., Huang, Y., & Chen, Y. "A high-performance supercapacitor-battery hybrid energy storage device based on graphene-enhanced electrode materials with ultrahigh energy density". Energy and Environmental Science, 6(5), 1623- 1632, 2013.
Ma, T., Yang, H., & Lu, L. "Development of hybrid battery-supercapacitor energy storage for remote area renewable energy systems". Applied Energy, 153, 56-62, 2015.
Lu, K., Li, D., Gao, X., Dai, H., Wang, N., & Ma, H. "An advanced aqueous sodium-ion supercapacitor with a manganous hexacyanoferrate cathode and a Fe₃O₄/rGO anode". Journal of Materials Chemistry A, 31 (3), 16013-16019 , 2015.
Simon, P., & Gogotsi, Y. "Materials for electrochemical capacitors." Nanoscience and technology: a collection of reviews from Nature journals, 320-329, 2010.
Lu, X., Yu, M., Wang, G., Tong, Y., & Li, Y. "Flexible solid-state supercapacitors: design, fabrication and applications". Energy and Environmental Science, 7(7), 2160-2181, 2014.
Kim, B. K., Sy, S., Yu, A., & Zhang, J. "Electrochemical supercapacitors for energy storage and conversion". Handbook of clean energy systems, 1-25, 2015.
Fic, K., Meller, M., & Frackowiak, E. "Strategies for enhancing the performance of carbon/carbon supercapacitors in aqueous electrolytes". Electrochimica Acta, 128, 210-217, 2014.
Halper, M. S., & Ellenbogen, J. C. "Supercapacitors: A brief overview". The MITRE Corporation, McLean, Virginia, USA, 1st March 2006

Conway, B. E. "Electrochemical supercapacitors: scientific fundamentals and technological applications". Springer Science and Business Media, 2013.
Kötz, R., & Carlen, M. J. E. A. "Principles and applications of electrochemical capacitors". Electrochimica Acta, 45(15-16), 2483-2498, 2000.
Burke, A. "Ultracapacitors: why, how, and where is the technology". Journal of power sources, 91(1), 37-50, 2000.
Masaud, T. M., Lee, K., & Sen, P. K. "An overview of energy storage technologies in electric power systems: What is the future?". In North American Power Symposium 2010 (pp. 1-6), 2010, September.
Peng, C., Zhang, S., Jewell, D., & Chen, G. Z. "Carbon nanotube and conducting polymer composites for supercapacitors". Progress In Natural Science, 18(7), 777-788, 2008.
Arbizzani, C., Mastragostino, M., & Soavi, F. "New trends in electrochemical supercapacitors". Journal Of Power Sources, 100(1-2), 164-170, 2001.
Wang, G., Zhang, L., & Zhang, J. "A review of electrode materials for electrochemical supercapacitors". Chemical Society Reviews, 41(2), 797-828, 2012.
Zhang, Y., Feng, H., Wu, X., Wang, L., Zhang, A., Xia, T., Zhang, L. "Progress of electrochemical capacitor electrode materials: A review". International Journal of Hydrogen Energy, 34(11), 4889-4899, 2009.
Pandolfo, A. G., & Hollenkamp, A. F. "Carbon properties and their role in supercapacitors". Journal of Power Sources, 157(1), 11-27, 2006.
C. Aydın, "A different approach to graphene-doped MnO Supercapacitor production: synthesis with different solvents", Journal of Physical Chemistry and Functional Materials, vol. 7, no. 2, pp. 137-147, 2024,
Simon, P., Gogotsi, Y., & Dunn, B. "Where do batteries end and supercapacitors begin?". Science, 343(6176), 1210-1211, 2014.
Frackowiak, E., & Beguin, F. "Carbon materials for the electrochemical storage of energy in capacitors". Carbon, 39(6), 937-950, 2001.
Buchsteiner, A., Lerf, A., & Pieper, J. "Water dynamics in graphite oxide investigated with neutron scattering". The Journal of Physical Chemistry B, 110(45), 22328-22338, 2006.
Szabó, T., Berkesi, O., Forgó, P., Josepovits, K., Sanakis, Y., Petridis, D., & Dékány, I. "Evolution of surface functional groups in a series of progressively oxidised graphite oxides". Chemistry of Materials, 18(11), 2740-2749, 2006.
Hofmann, U., & Holst, RÜber die Säurenatur und die Methylierung von Graphitoxyd. Berichte der deutschen chemischen Gesellschaft (A and B Series), 72(4), 754-771, 1939.
Ruess, G. "Zur Wasserbindung im Halloysite. Monatshefte für Chemie und verwandte" Teile anderer Wissenschaften, 76(2), 168-173, 1946.
Aydin C., Yildiz O. E., "The behaviour of NiO/GO nanoelectroseramics in different solvents: Synthesis, structural, thermal and electro-optical properties", Journal of Ceramic Processing Research Vol.25 No.1, 131 - 137 , 2024.
C. Aydın and O. E. Yıldız, "Synthesis, Morphological and Structural Properties of Graphene Oxide Based Hybrid Supercapacitive GO/Sn Nanocomposites with Different Solvents", Journal of Physical Chemistry and Functional Materials, vol. 6, no. 2, pp. 86-91, 2023.

Details

Primary Language

English

Subjects

Composite and Hybrid Materials

Journal Section

Research Article

Authors

Cihat Aydın ^*
0000-0001-9997-6326
Türkiye

Oktay Emre Yıldız
0000-0002-6397-916X
Türkiye

Publication Date

March 24, 2026

Submission Date

July 16, 2025

Acceptance Date

October 1, 2025

Published in Issue

Year 2026 Volume: 15 Number: 1

DOI

https://doi.org/10.17798/bitlisfen.1743478

IZ

https://izlik.org/JA28LF67UL

Cite

RIS / Bibtex

APA

Aydın, C., & Yıldız, O. E. (2026). A New Generation Hybrid Supercapacitor: GO/ZnO. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 15(1), 62-73. https://doi.org/10.17798/bitlisfen.1743478

AMA

1.Aydın C, Yıldız OE. A New Generation Hybrid Supercapacitor: GO/ZnO. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2026;15(1):62-73. doi:10.17798/bitlisfen.1743478

Chicago

Aydın, Cihat, and Oktay Emre Yıldız. 2026. “A New Generation Hybrid Supercapacitor: GO ZnO”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 15 (1): 62-73. https://doi.org/10.17798/bitlisfen.1743478.

EndNote

Aydın C, Yıldız OE (March 1, 2026) A New Generation Hybrid Supercapacitor: GO/ZnO. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 15 1 62–73.

IEEE

[1]C. Aydın and O. E. Yıldız, “A New Generation Hybrid Supercapacitor: GO/ZnO”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 15, no. 1, pp. 62–73, Mar. 2026, doi: 10.17798/bitlisfen.1743478.

ISNAD

Aydın, Cihat - Yıldız, Oktay Emre. “A New Generation Hybrid Supercapacitor: GO ZnO”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 15/1 (March 1, 2026): 62-73. https://doi.org/10.17798/bitlisfen.1743478.

JAMA

1.Aydın C, Yıldız OE. A New Generation Hybrid Supercapacitor: GO/ZnO. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2026;15:62–73.

MLA

Aydın, Cihat, and Oktay Emre Yıldız. “A New Generation Hybrid Supercapacitor: GO ZnO”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 15, no. 1, Mar. 2026, pp. 62-73, doi:10.17798/bitlisfen.1743478.

Vancouver

1.Cihat Aydın, Oktay Emre Yıldız. A New Generation Hybrid Supercapacitor: GO/ZnO. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2026 Mar. 1;15(1):62-73. doi:10.17798/bitlisfen.1743478