Research Article

Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite

Volume: 7 Number: 2 December 28, 2018

Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite

Abstract

In this study, adsorption of undesirable copper (II) ion with bentonite in industrial wastewater was investigated at different temperature, pH and time intervals. Adsorption experiments were started with an adsorbent amount of 0.5 grams. Optimum pH determination experiments were carried out in the first stage of the adsorption experiments. The optimum pH determined after the experiments was determined as 5.0. Adsorption rates and adsorbed metal ions concentration increased with increasing concentrations of starting copper (II) ions up to 25 mg / L and 500 mg / L in a medium containing 0.5 g of adsorbent. In the isotherm studies, isotherms were plotted and isotherm constants were calculated and it was clearly observed that the adsorption system, Langmuir and Freundlich isotherms. When the Gibbs free energy (ΔG) values ​​calculated at different temperatures are taken into consideration, it is observed that the copper (II) ions have negative values, especially at low concentrations, and thus the reactions take place spontaneously. The compatibility of the adsorption system with the Langmuir and Freundlich isotherms was investigated, and it was observed that the adenomatoid system adhered to Langmuir and Freundlich. Based on these results, it is concluded that the amount of metal retained on the surface increases with temperature increase. Values (n> 1) were obtained for the experiments performed at each concentration of copper (II) ions (up to 500 mg / L at 25 mg / L).

Keywords

References

  1. 1. Smith, J. M., 1981. Chemical Engineering Kinetics. McGraw Hill Int. 327s.
  2. 2. Çokadar, H., İleri, R. 2003. Removal of Nickel (II) Ion from Sulfuric Acid by Granular Activated Carbon (GAK), Pamukkale University, Faculty of Education, Department of Science Education, İncilipınar, Denizli.
  3. 3. Karapınar, G., Kargı, F., 1998. Removal of Waste Textile Textile Materials by Adsorption Biological Treatment, Dokuz Eylül University, Department of Environmental Engineering, Tınaztepe, İzmir.
  4. 4. DeZuane, J. 1997. Handbook of Drinking Water Quality, John Wiley & Sons, Canada, 72-85.
  5. 5. Güler, Ç. 1997. Water Quality, Environmental Health Basic Resource Series, Ankara.
  6. 6. Üstün, N. (2005). Pelletization of fly ash and its use in zinc (II), copper (II) (I) and chromium (III) adsorption, Master Thesis, Institute of Science and Technology, 89s, Istanbul.
  7. 7. Anirudhan, TS, Manohar, DM, Noeline, BF, 2005. Adsorption performance of Al-pillared bentonite clay for the removal of cobalt (II) from aqueous phase, Department of Chemistry, University of Kerala, Kariavattom, Trivandrum-695 581, India .
  8. 8. Snell, F. D. and Snell, C. T., 1959, Colorimetric Methods of Analysis, 3rd edition, Vol. 2, D. Van Nostrand Company, Canada.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Publication Date

December 28, 2018

Submission Date

May 2, 2018

Acceptance Date

August 10, 2018

Published in Issue

Year 2018 Volume: 7 Number: 2

APA
Şenol, H., & Açıkel, Ü. (2018). Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 7(2), 231-242. https://doi.org/10.17798/bitlisfen.420210
AMA
1.Şenol H, Açıkel Ü. Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2018;7(2):231-242. doi:10.17798/bitlisfen.420210
Chicago
Şenol, Halil, and Ünsal Açıkel. 2018. “Investigation of Adsorption of Cu (II) Heavy Metal With Bentonite”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 7 (2): 231-42. https://doi.org/10.17798/bitlisfen.420210.
EndNote
Şenol H, Açıkel Ü (December 1, 2018) Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 7 2 231–242.
IEEE
[1]H. Şenol and Ü. Açıkel, “Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 7, no. 2, pp. 231–242, Dec. 2018, doi: 10.17798/bitlisfen.420210.
ISNAD
Şenol, Halil - Açıkel, Ünsal. “Investigation of Adsorption of Cu (II) Heavy Metal With Bentonite”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 7/2 (December 1, 2018): 231-242. https://doi.org/10.17798/bitlisfen.420210.
JAMA
1.Şenol H, Açıkel Ü. Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2018;7:231–242.
MLA
Şenol, Halil, and Ünsal Açıkel. “Investigation of Adsorption of Cu (II) Heavy Metal With Bentonite”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 7, no. 2, Dec. 2018, pp. 231-42, doi:10.17798/bitlisfen.420210.
Vancouver
1.Halil Şenol, Ünsal Açıkel. Investigation of Adsorption of Cu (II) Heavy Metal with Bentonite. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2018 Dec. 1;7(2):231-42. doi:10.17798/bitlisfen.420210

Cited By

Bitlis Eren University

Journal of Science Editor

Bitlis Eren University Graduate Institute

Bes Minare Mah. Ahmet Eren Bulvari, Merkez Kampus, 13000 BITLIS

E-mail: fbe@beu.edu.tr