Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri

Mehmet Salih Keskin; Mehmet Salih Ağırtaş; Orhan Baytar; Mehmet Sait İzgi; Ömer Şahin

doi:10.17798/bitlisfen.623941

Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri

Abstract

For the production of hydrogen in the hydrolysis of potassium boron hydride of this product, a high performance Ni-B-P catalyst was synthesized. Catalysts in the unknown state of the chemical industry FTIR, EDS, XRD and SEM analyzes of the catalysts were used to determine the characteristics of the catalysts. Also for potassium boron hydrolysis of Ni2P catalyst; The best Ni / P ratio, optimum KOH concentration, KBH4 concentration, catalyst capacity and kinetic parameters were investigated at different temperatures. The hydrogen production rate of the catalyst was determined to be 665 mL / min * g and the best Ni / P ratio was 0.184. In addition, the reaction rate range n was determined to be 0.2 degrees, so the activation energy value in the arhenius equation was 58,528 kJ / mol.

Keywords

: Ni-B-P,Katalizör,Hidrojen,Potasyum Borhidrür,Hidroliz

Supporting Institution

Yüzüncü Yıl Üniversitesi

Project Number

FDK-2017-6256

Thanks

Bu çalışma Van YYÜ Bilimsel Araştırma Projeleri Başkanlığı tarafından FDK-2017-6256 projesi kapsamında desteklenmiştir.

References

1. Zhang, D. et al. 2017. Present situation and future prospect of renewable energy in China. Renew. Sustain. Energy Rev. 76, 865–871
2. Datta, A. 2009. Modelling doped (Ni, Pd, Pt) sulfur-nitrolic systems as new motifs for storage of hydrogen. Phys. Chem. Chem. Phys. 11, 11054–11059.
3. Tamburic, B., 2013. Dechatiwongse, P., Zemichael, F. W., Maitland, G. C. & Hellgardt, K. Process and reactor design for biophotolytic hydrogen production. Phys. Chem. Chem. Phys. 15, 10783–10794 .
4. İzgi, M. S. 2016. Effect of microwave irritated Co-B-Cr catalyst on the hydrolysis of sodium borohydride. Energy Sources, Part A Recover. Util. Environ. Eff. 38, 2590–2597.
5. Wee, J. H., Lee, K. Y. & Kim, S. H. 2006. Sodium borohydride as the hydrogen supplier for proton exchange membrane fuel cell systems. Fuel Process. Technol. 87, 811–819 .
6. Chen, B. et al. 2018. Cobalt nanoparticles supported on magnetic core-shell structured carbon as a highly efficient catalyst for hydrogen generation from NaBH4hydrolysis. Int. J. Hydrogen Energy 43, 9296–9306 .
7. Çelik Kazici, H., Yildiz, F., İzgi, M. S., Ulaş, B. & Kivrak, H. 2019. Novel activated carbon supported trimetallic PdCoAg nanoparticles as efficient catalysts for the hydrolytic dehydrogenation of ammonia borane. Int. J. Hydrogen Energy doi:10.1016/j.ijhydene.2019.02.198
8. Rakap, M. 2015. Hydrolysis of Sodium Borohydride and Ammonia Borane for Hydrogen Generation Using Highly Efficient Poly(N-Vinyl-2-Pyrrolidone)-Stabilized Ru-Pd Nanoparticles as Catalysts. Int. J. Green Energy 12, 1288–1300.

9. Demirci, U. B. & Miele, P. 2009. Sodium borohydride versus ammonia borane, in hydrogen storage and direct fuel cell applications. Energy Environ. Sci. 2, 627–637.
10. Eigen, N., Kunowsky, M., Klassen, T. & Bormann, R. 2007. Synthesis of NaAlH4-based hydrogen storage material using milling under low pressure hydrogen atmosphere. J. Alloys Compd. 430, 350–355.
11. Şahin, Ö., Izgi, M. S., Onat, E. & Saka, C. 2016. Influence of the using of methanol instead of water in the preparation of Co-B-TiO2catalyst for hydrogen production by NaBH4hydrolysis and plasma treatment effect on the Co-B-TiO2catalyst. Int. J. Hydrogen Energy 41, 2539–2546
12. Zahmakiran, M. & Özkar, S. 2009. Zeolite framework stabilized rhodium(0) nanoclusters catalyst for the hydrolysis of ammonia-borane in air: Outstanding catalytic activity, reusability and lifetime. Appl. Catal. B Environ. 89, 104–110.
13. Fernandes, R., Patel, N. & Miotello, A. 2009. Efficient catalytic properties of Co-Ni-P-B catalyst powders for hydrogen generation by hydrolysis of alkaline solution of NaBH4. Int. J. Hydrogen Energy. doi:10.1016/j.ijhydene.2009.02.007
14. Xu, Q. & Chandra, M. 2006. Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature. J. Power Sources 163, 364–370.
15. Ma, Y., Li, W., Zhang, M., Zhou, Y. & Tao, K. 2003. Preparation and catalytic properties of amorphous alloys in hydrogenation of sulfolene. Appl. Catal. A Gen. 243, 215–223.
16. İzgİ, M. S., Şahİn, Ö., Ödemİş, Ö. & Horoz, S. 2018. Microwave Treatment on Co–B–P Catalyst to Enhance Catalytic Activity for Hydrogen Production by Hydrolysis of Nabh4. Adv. Mater. Sci. Eng. 2, 2–7.
17. Sait Izgi, M., Şahin, Ö. & Saka, C. 2019. γ-Al 2 O 3 supported/Co-Cr-B catalyst for hydrogen evolution via NH 3 BH 3 hydrolysis. Mater. Manuf. Process. 1–7.
18. Peng, C. Y. et al. 2015. Nanostructured Ni2P as a Robust Catalyst for the Hydrolytic Dehydrogenation of Ammonia-Borane. Angew. Chemie - Int. Ed. 54, 15725–15729.
19. Wei, Y. et al. 2017. Hydrogen generation from alkaline NaBH4 solution using a dandelion-like Co–Mo–B catalyst supported on carbon cloth. Int. J. Hydrogen Energy 42.
20. Zhang, J. et al. 2017. Highly dispersed Pt nanoparticles supported on carbon nanotubes produced by atomic layer deposition for hydrogen generation from hydrolysis of ammonia borane. Catal. Sci. Technol. 7, 322–329 .
21. Baytar, O., Horoz, S. & Nar, S. 2019. Al2O3 supported Co-Cu-B ( Co-Cu-B/Al2O3) catalyst for hydrogen generatıon by hydrolysıs of aqueous sodıum borohydrıde. 14, 673–681.

Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Mehmet Salih Keskin
Türkiye

Mehmet Salih Ağırtaş
Türkiye

Orhan Baytar
Türkiye

Mehmet Sait İzgi
0000-0003-4575-3762
Türkiye

Ömer Şahin
Türkiye

Publication Date

June 15, 2020

Submission Date

September 24, 2019

Acceptance Date

April 8, 2020

Published in Issue

Year 2020 Volume: 9 Number: 2

DOI

https://doi.org/10.17798/bitlisfen.623941

IZ

https://izlik.org/JA32DU52JA

Cite

RIS / Bibtex

APA

Keskin, M. S., Ağırtaş, M. S., Baytar, O., İzgi, M. S., & Şahin, Ö. (2020). Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 9(2), 599-608. https://doi.org/10.17798/bitlisfen.623941

AMA

1.Keskin MS, Ağırtaş MS, Baytar O, İzgi MS, Şahin Ö. Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2020;9(2):599-608. doi:10.17798/bitlisfen.623941

Chicago

Keskin, Mehmet Salih, Mehmet Salih Ağırtaş, Orhan Baytar, Mehmet Sait İzgi, and Ömer Şahin. 2020. “Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 9 (2): 599-608. https://doi.org/10.17798/bitlisfen.623941.

EndNote

Keskin MS, Ağırtaş MS, Baytar O, İzgi MS, Şahin Ö (June 1, 2020) Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 9 2 599–608.

IEEE

[1]M. S. Keskin, M. S. Ağırtaş, O. Baytar, M. S. İzgi, and Ö. Şahin, “Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 9, no. 2, pp. 599–608, June 2020, doi: 10.17798/bitlisfen.623941.

ISNAD

Keskin, Mehmet Salih - Ağırtaş, Mehmet Salih - Baytar, Orhan - İzgi, Mehmet Sait - Şahin, Ömer. “Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 9/2 (June 1, 2020): 599-608. https://doi.org/10.17798/bitlisfen.623941.

JAMA

1.Keskin MS, Ağırtaş MS, Baytar O, İzgi MS, Şahin Ö. Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2020;9:599–608.

MLA

Keskin, Mehmet Salih, et al. “Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri”. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 9, no. 2, June 2020, pp. 599-08, doi:10.17798/bitlisfen.623941.

Vancouver

1.Mehmet Salih Keskin, Mehmet Salih Ağırtaş, Orhan Baytar, Mehmet Sait İzgi, Ömer Şahin. Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2020 Jun. 1;9(2):599-608. doi:10.17798/bitlisfen.623941

Pvp ile Kararlaştırılmış Rodyum Demir Bimetalik Nanokümelerinin Hazırlanması, Karakterizasyonu ve DMAB Hidrolizindeki Katalitik Etkinliğinin İncelenmesi

Journal of the Institute of Science and Technology

https://doi.org/10.21597/jist.1278345

Revolutionary carbon quantum dot supported-Co catalyst for record-breaking hydrogen production rate

Journal of the Australian Ceramic Society

https://doi.org/10.1007/s41779-023-00988-3

KBH4 Hidrolizi için Aktif karbon Destekli Nano Metal Ru-Ni-B Katalizörün Sentezi ve Kinetik Değerlendirilmesi

Türkiye Teknoloji ve Uygulamalı Bilimler Dergisi

https://doi.org/10.70562/tubid.1687520

Catalytic dehydrogenation efficiency of carbon quantum supported Ni nanoparticles and synthesized via dimethylformamide (DMF)

International Journal of Hydrogen Energy

https://doi.org/10.1016/j.ijhydene.2025.152801

Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri

Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

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Subjects

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Published in Issue

DOI

IZ

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Cited By

Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@MOF

Efficiency of TiO2-supported Ni-Mo-Ru–B catalyst for hydrogen production from potassium borohydride hydrolysis

Catalytic activites of a biomaterial (sumac) catalyst in sodium borohyride methanolysis reactions

Optimizing hydrogen production from alkali hydrides using supported metal catalysts

Pvp ile Kararlaştırılmış Rodyum Demir Bimetalik Nanokümelerinin Hazırlanması, Karakterizasyonu ve DMAB Hidrolizindeki Katalitik Etkinliğinin İncelenmesi

Revolutionary carbon quantum dot supported-Co catalyst for record-breaking hydrogen production rate

KBH4 Hidrolizi için Aktif karbon Destekli Nano Metal Ru-Ni-B Katalizörün Sentezi ve Kinetik Değerlendirilmesi

Catalytic dehydrogenation efficiency of carbon quantum supported Ni nanoparticles and synthesized via dimethylformamide (DMF)