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Biosorption of Methylene Blue into Pumpkin Seed: Isotherm, Kinetic and Thermodynamics Studies

Yıl 2024, Cilt: 13 Sayı: 3, 519 - 529, 26.09.2024
https://doi.org/10.17798/bitlisfen.1328584

Öz

This work has demonstrated the potential utility of raw pumpkin seed shells (PSS) as a low-cost solid adsorbent for methylene blue (MB) adsorption. PSS have investigated surface functional groups with FTIR (after and before adsorption), crystal structure with XRD, and surface morphology with SEM-EDX. Biosorption parameters were examined contact time, pH, solution temperature, and initial concentration. This research was conducted to analyze adsorption processes involved in adsorption of MB onto crude PSS by gaining essential knowledge from the study of equilibrium adsorption kinetics, isotherms, and thermodynamics. It was determined whether four models-Langmuir, Temkin, Freundlich, and D-R models-fit experimental data derived from adsorption isotherms. In addition, the accuracy of fits of three models to experimental data derived from adsorption kinetics were tested, namely, the Elovich, pseudo-first order, and pseudo-second order models. Biosorption of MB on PSS is exothermic and spontaneous according to thermodynamic analysis. FTIR (Fourier transform infrared spectroscopy) studies show significant changes in the absorption values, shapes and positions of bands both before and after solute adsorption. It was found that there are two MB adsorption mechanisms: electrostatic attraction and hydrogen bonding.

Kaynakça

  • [1] Y. Zhou, J. Lu, Y. Zhou, and Y. Liu, “Recent advances for dyes removal using novel adsorbents: A review,” Environ. Pollut., vol. 252, pp. 352–365, 2019.
  • [2] M. Rafatullah, O. Sulaiman, R. Hashim, and A. Ahmad, “Adsorption of methylene blue on low-cost adsorbents: A review,” J. Hazard. Mater., vol. 177, no. 1–3, pp. 70–80, 2010.
  • [3] A. M. Elgarahy, K. Z. Elwakeel, S. H. Mohammad, and G. A. Elshoubaky, “A critical review of biosorption of dyes, heavy metals and metalloids from wastewater as an efficient and green process,” Clean. Eng. Technol., vol. 4, no. 100209, p. 100209, 2021.
  • [4] Y. Wang, Q. Peng, N. Akhtar, X. Chen, and Y. Huang, “Microporous carbon material from fish waste for removal of methylene blue from wastewater,” Water Sci. Technol., vol. 81, no. 6, pp. 1180–1190, 2020.
  • [5] M. Onay and Ç. Sarici Özdemi̇r, “Equilibrium studies for dye adsorption onto Red Clay,” Naturengs MTU Journal of Engineering and Natural Sciences Malatya Turgut Ozal University,vol.3, no. 2, pp. 36-45, 2022.
  • [6] N. Kaya, Z. Yıldız, and S. Ceylan, “Preparation and characterisation of biochar from hazelnut shell and its adsorption properties for methylene blue dye,” J. Polytech., vol. 21, no. 4, pp. 765-776, 2018.
  • [7] S. Savcı and F. Karadağ, “Fast adsorption of methylene blue by filter coffee waste,” NWSA-Eng. Sci., vol. 15, no. 4, pp. 111–120, 2020.
  • [8] Z. Ciğeroğlu and E. Yildirir, “Vermicompost as a Potential Adsorbent for the Adsorption of Methylene Blue Dye from Aqueous Solutions,” JOTCSA, vol. 7, no. 3, pp. 893–902, 2020.
  • [9] T. Satır and İ. Erol, “Calcined Eggshell for the Removal of Victoria Blue R Dye from Wastewater Medium by Adsorption,” JOTCSA, vol. 8, no. 1, pp. 31–40, 2021.
  • [10] V. Krstić, T. Urošević, and B. Pešovski, “A review on adsorbents for treatment of water and wastewaters containing copper ions,” Chem. Eng. Sci., vol. 192, pp. 273–287, 2018.
  • [11] N. K. Gupta, A. Gupta, P. Ramteke, H. Sahoo, and A. Sengupta, “Biosorption-a green method for the preconcentration of rare earth elements (REEs) from waste solutions: A review,” J. Mol. Liq., vol. 274, pp. 148–164, 2019.
  • [12] A. Stavrinou, C. A. Aggelopoulos, and C. D. Tsakiroglou, “Exploring the adsorption mechanisms of cationic and anionic dyes onto agricultural waste peels of banana, cucumber and potato: Adsorption kinetics and equilibrium isotherms as a tool,” J. Environ. Chem. Eng., vol. 6, no. 6, pp. 6958–6970, 2018.
  • [13] K. Komnitsas, D. Zaharaki, I. Pyliotis, D. Vamvuka, and G. Bartzas, “Assessment of pistachio shell biochar quality and its potential for adsorption of heavy metals,” Waste Biomass Valorization, vol. 6, no. 5, pp. 805–816, 2015.
  • [14] D. Angın, T. E. Köse, and U. Selengil, “Production and characterization of activated carbon prepared from safflower seed cake biochar and its ability to absorb reactive dyestuff,” Appl. Surf. Sci., vol. 280, pp. 705–710, 2013.
  • [15] B. Hu et al., “Efficient elimination of organic and inorganic pollutants by biochar and biochar-based materials,” Biochar, vol. 2, no. 1, pp. 47–64, 2020.
  • [16] Z. Zhang, M. Zhu, and D. Zhang, “A Thermogravimetric study of the characteristics of pyrolysis of cellulose isolated from selected biomass,” Appl. Energy, vol. 220, pp. 87–93, 2018.
  • [17] M. Naushad, A. A. Alqadami, Z. A. AlOthman, I. H. Alsohaimi, M. S. Algamdi, and A. M. Aldawsari, “Adsorption kinetics, isotherm and reusability studies for the removal of cationic dye from aqueous medium using arginine modified activated carbon,” J. Mol. Liq., vol. 293, no. 111442, p. 111442, 2019.
  • [18] R. Foroutan, S. J. Peighambardoust, S. H. Peighambardoust, M. Pateiro, and J. M. Lorenzo, “Adsorption of crystal Violet dye using activated carbon of lemon wood and activated carbon/Fe3O4 magnetic nanocomposite from aqueous solutions: A kinetic, equilibrium and thermodynamic study,” Molecules, vol. 26, no. 8, p. 2241, 2021
  • [19] S. Manna, D. Roy, P. Saha, D. Gopakumar, and S. Thomas, “Rapid methylene blue adsorption using modified lignocellulosic materials,” Process Saf. Environ. Prot., vol. 107, pp. 346–356, 2017.
  • [20] P. M. Thabede, N. D. Shooto, and E. B. Naidoo, “Removal of methylene blue dye and lead ions from aqueous solution using activated carbon from black cumin seeds,” S. Afr. J. Chem. Eng., vol. 33, pp. 39–50, 2020.
  • [21] M. Choudhary, R. Kumar, and S. Neogi, “Activated biochar derived from Opuntia ficus-indica for the efficient adsorption of malachite green dye, Cu+2 and Ni+2 from water,” J. Hazard. Mater., vol. 392, no. 122441, p. 122441, 2020.
  • [22] K. Y. Foo and B. H. Hameed, “Insights into the modeling of adsorption isotherm systems,” Chem. Eng. J., vol. 156, no. 1, pp. 2–10, 2010.
  • [23] E. Ajenifuja, J. A. Ajao, and E. O. B. Ajayi, “Adsorption isotherm studies of Cu (II) and Co (II) in high concentration aqueous solutions on photocatalytically modified diatomaceous ceramic adsorbents,” Appl. Water Sci., vol. 7, no. 7, pp. 3793–3801, 2017.
  • [24] J. Wang and X. Guo, “Adsorption kinetic models: Physical meanings, applications, and solving methods,” J. Hazard. Mater., vol. 390, no. 122156, p. 122156, 2020.
  • [25] A. Pholosi, E. B. Naidoo, and A. E. Ofomaja, “Intraparticle diffusion of Cr(VI) through biomass and magnetite coated biomass: A comparative kinetic and diffusion study,” S. Afr. J. Chem. Eng., vol. 32, pp. 39–55, 2020.
  • [26] P. Nautiyal, K. A. Subramanian, and M. G. Dastidar, “Kinetic and thermodynamic studies on biodiesel production from Spirulina platensis algae biomass using single stage extraction–transesterification process,” Fuel (Lond.), vol. 135, pp. 228–234, 2014.
  • [27] M. Toprak, A. Salci, and A. R. Demirkiran, “Comparison of adsorption performances of vermiculite and clinoptilolite for the removal of pyronine Y dyestuff,” React. Kinet. Mech. Catal., vol. 111, no. 2, pp. 791–804, 2014.
Yıl 2024, Cilt: 13 Sayı: 3, 519 - 529, 26.09.2024
https://doi.org/10.17798/bitlisfen.1328584

Öz

Kaynakça

  • [1] Y. Zhou, J. Lu, Y. Zhou, and Y. Liu, “Recent advances for dyes removal using novel adsorbents: A review,” Environ. Pollut., vol. 252, pp. 352–365, 2019.
  • [2] M. Rafatullah, O. Sulaiman, R. Hashim, and A. Ahmad, “Adsorption of methylene blue on low-cost adsorbents: A review,” J. Hazard. Mater., vol. 177, no. 1–3, pp. 70–80, 2010.
  • [3] A. M. Elgarahy, K. Z. Elwakeel, S. H. Mohammad, and G. A. Elshoubaky, “A critical review of biosorption of dyes, heavy metals and metalloids from wastewater as an efficient and green process,” Clean. Eng. Technol., vol. 4, no. 100209, p. 100209, 2021.
  • [4] Y. Wang, Q. Peng, N. Akhtar, X. Chen, and Y. Huang, “Microporous carbon material from fish waste for removal of methylene blue from wastewater,” Water Sci. Technol., vol. 81, no. 6, pp. 1180–1190, 2020.
  • [5] M. Onay and Ç. Sarici Özdemi̇r, “Equilibrium studies for dye adsorption onto Red Clay,” Naturengs MTU Journal of Engineering and Natural Sciences Malatya Turgut Ozal University,vol.3, no. 2, pp. 36-45, 2022.
  • [6] N. Kaya, Z. Yıldız, and S. Ceylan, “Preparation and characterisation of biochar from hazelnut shell and its adsorption properties for methylene blue dye,” J. Polytech., vol. 21, no. 4, pp. 765-776, 2018.
  • [7] S. Savcı and F. Karadağ, “Fast adsorption of methylene blue by filter coffee waste,” NWSA-Eng. Sci., vol. 15, no. 4, pp. 111–120, 2020.
  • [8] Z. Ciğeroğlu and E. Yildirir, “Vermicompost as a Potential Adsorbent for the Adsorption of Methylene Blue Dye from Aqueous Solutions,” JOTCSA, vol. 7, no. 3, pp. 893–902, 2020.
  • [9] T. Satır and İ. Erol, “Calcined Eggshell for the Removal of Victoria Blue R Dye from Wastewater Medium by Adsorption,” JOTCSA, vol. 8, no. 1, pp. 31–40, 2021.
  • [10] V. Krstić, T. Urošević, and B. Pešovski, “A review on adsorbents for treatment of water and wastewaters containing copper ions,” Chem. Eng. Sci., vol. 192, pp. 273–287, 2018.
  • [11] N. K. Gupta, A. Gupta, P. Ramteke, H. Sahoo, and A. Sengupta, “Biosorption-a green method for the preconcentration of rare earth elements (REEs) from waste solutions: A review,” J. Mol. Liq., vol. 274, pp. 148–164, 2019.
  • [12] A. Stavrinou, C. A. Aggelopoulos, and C. D. Tsakiroglou, “Exploring the adsorption mechanisms of cationic and anionic dyes onto agricultural waste peels of banana, cucumber and potato: Adsorption kinetics and equilibrium isotherms as a tool,” J. Environ. Chem. Eng., vol. 6, no. 6, pp. 6958–6970, 2018.
  • [13] K. Komnitsas, D. Zaharaki, I. Pyliotis, D. Vamvuka, and G. Bartzas, “Assessment of pistachio shell biochar quality and its potential for adsorption of heavy metals,” Waste Biomass Valorization, vol. 6, no. 5, pp. 805–816, 2015.
  • [14] D. Angın, T. E. Köse, and U. Selengil, “Production and characterization of activated carbon prepared from safflower seed cake biochar and its ability to absorb reactive dyestuff,” Appl. Surf. Sci., vol. 280, pp. 705–710, 2013.
  • [15] B. Hu et al., “Efficient elimination of organic and inorganic pollutants by biochar and biochar-based materials,” Biochar, vol. 2, no. 1, pp. 47–64, 2020.
  • [16] Z. Zhang, M. Zhu, and D. Zhang, “A Thermogravimetric study of the characteristics of pyrolysis of cellulose isolated from selected biomass,” Appl. Energy, vol. 220, pp. 87–93, 2018.
  • [17] M. Naushad, A. A. Alqadami, Z. A. AlOthman, I. H. Alsohaimi, M. S. Algamdi, and A. M. Aldawsari, “Adsorption kinetics, isotherm and reusability studies for the removal of cationic dye from aqueous medium using arginine modified activated carbon,” J. Mol. Liq., vol. 293, no. 111442, p. 111442, 2019.
  • [18] R. Foroutan, S. J. Peighambardoust, S. H. Peighambardoust, M. Pateiro, and J. M. Lorenzo, “Adsorption of crystal Violet dye using activated carbon of lemon wood and activated carbon/Fe3O4 magnetic nanocomposite from aqueous solutions: A kinetic, equilibrium and thermodynamic study,” Molecules, vol. 26, no. 8, p. 2241, 2021
  • [19] S. Manna, D. Roy, P. Saha, D. Gopakumar, and S. Thomas, “Rapid methylene blue adsorption using modified lignocellulosic materials,” Process Saf. Environ. Prot., vol. 107, pp. 346–356, 2017.
  • [20] P. M. Thabede, N. D. Shooto, and E. B. Naidoo, “Removal of methylene blue dye and lead ions from aqueous solution using activated carbon from black cumin seeds,” S. Afr. J. Chem. Eng., vol. 33, pp. 39–50, 2020.
  • [21] M. Choudhary, R. Kumar, and S. Neogi, “Activated biochar derived from Opuntia ficus-indica for the efficient adsorption of malachite green dye, Cu+2 and Ni+2 from water,” J. Hazard. Mater., vol. 392, no. 122441, p. 122441, 2020.
  • [22] K. Y. Foo and B. H. Hameed, “Insights into the modeling of adsorption isotherm systems,” Chem. Eng. J., vol. 156, no. 1, pp. 2–10, 2010.
  • [23] E. Ajenifuja, J. A. Ajao, and E. O. B. Ajayi, “Adsorption isotherm studies of Cu (II) and Co (II) in high concentration aqueous solutions on photocatalytically modified diatomaceous ceramic adsorbents,” Appl. Water Sci., vol. 7, no. 7, pp. 3793–3801, 2017.
  • [24] J. Wang and X. Guo, “Adsorption kinetic models: Physical meanings, applications, and solving methods,” J. Hazard. Mater., vol. 390, no. 122156, p. 122156, 2020.
  • [25] A. Pholosi, E. B. Naidoo, and A. E. Ofomaja, “Intraparticle diffusion of Cr(VI) through biomass and magnetite coated biomass: A comparative kinetic and diffusion study,” S. Afr. J. Chem. Eng., vol. 32, pp. 39–55, 2020.
  • [26] P. Nautiyal, K. A. Subramanian, and M. G. Dastidar, “Kinetic and thermodynamic studies on biodiesel production from Spirulina platensis algae biomass using single stage extraction–transesterification process,” Fuel (Lond.), vol. 135, pp. 228–234, 2014.
  • [27] M. Toprak, A. Salci, and A. R. Demirkiran, “Comparison of adsorption performances of vermiculite and clinoptilolite for the removal of pyronine Y dyestuff,” React. Kinet. Mech. Catal., vol. 111, no. 2, pp. 791–804, 2014.
Toplam 27 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Analitik Kimya (Diğer)
Bölüm Araştırma Makalesi
Yazarlar

İlhan Küçük 0000-0003-2876-3942

Erken Görünüm Tarihi 20 Eylül 2024
Yayımlanma Tarihi 26 Eylül 2024
Gönderilme Tarihi 17 Temmuz 2023
Kabul Tarihi 15 Ağustos 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 13 Sayı: 3

Kaynak Göster

IEEE İ. Küçük, “Biosorption of Methylene Blue into Pumpkin Seed: Isotherm, Kinetic and Thermodynamics Studies”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, c. 13, sy. 3, ss. 519–529, 2024, doi: 10.17798/bitlisfen.1328584.



Bitlis Eren Üniversitesi
Fen Bilimleri Dergisi Editörlüğü

Bitlis Eren Üniversitesi Lisansüstü Eğitim Enstitüsü        
Beş Minare Mah. Ahmet Eren Bulvarı, Merkez Kampüs, 13000 BİTLİS        
E-posta: fbe@beu.edu.tr