Synthesis, Homopolymerization and Coplymerization of 9-antryl methyl metacrylate and β-naphtyl metacrylate
Öz
Abstract. 9-antryl methyl metacrylate is synthesized by reaction of 9-anthracene methanol and methcryloyl chloride in the peresence of Et3N in THF as solvent. After characterization of this monomer, by IR and NMR spectroscopic technique, we report the homopolymerization and copolymerization 9-antryl methyl metacrylate using the reaction of styrene in the presence of AIBN as initiator. The structure of all target compounds was characterized by spectral analyses. The thermal behavior of the polymers is studied by TGA.
Anahtar Kelimeler
9-anthracene methanol methcryloyl chloride Copolymerization β-naphthol
Kaynakça
- Bevinton, J. C., Malpass, B. W. (1965) " Reactivity ratios for the copolymerization of acrylates and methacrylates by nuclear magnetic resonance spectroscopy "European polymer journal, 1, pp.55
- Coustantinova, T. N., Garbechev, I. K., (1998) polymer International, 43, pp. 49
- Rouhallah B., Ali-asghar, M. (1998) Synthesis of methyl methacrylate-n-butylacrylate copolymers: Study of the paint properties ""J. Appl. Polym. Sci 70, pp. 367-372
- Vijayanand P.S, Aron Prasath R., Balaji R., Nanjundan S., (2002) " Synthesis, spectral properties, and thermal properties of homo- and copolymers of 3,5-dimethylphenyl acrylate with glycidyl methacrylate and determination of reactivity ratios "J Appl Polym Sci 85, pp. 2261-2270
- Ajmal, A., Mideen, A. S., Quraishi, M. A. (1994) " Green seed extract of Tectona grandis as corrosion inhibitor for mild steel in acid medium" Corros. Sci 36, pp. 79
- Singh, I. (1993) "Synthesis, characterization, and corrosion protection properties of poly(N-(methacryloyloxymethyl) benzotriazole-co-methyl methacrylate) on mild steel " Corrosion, 49, pp. 122
- Vijayanand, P. S., Sreekuttan Unnithan, C., Penlidis, A., Nanjundan, S. (2007), " Copolymerization of 4-Acetylphenyl Methacrylate with Ethyl Methacrylate: Synthesis, Characterization, Monomer Reactivity Ratios, and Thermal Properties " Journal of macromolecular science, 42, pp. 555-569
- Mizognchi, K. Hasegawa, E., (1996) "Studies on photocrosslinkable copolymers of 4- methacryloyloxyphenyl-3′,4′-dimethoxystyryl ketone and methyl methacrylate."Polym. Adv. Technol. 7 pp. 471.
- Patel R. J., Patel Z. H., Patel B. C., Bhavesh P. D. (2013) "Synthesis of acrylic copolymers and their antimicrobial screening" Der Pharma Chemica, 5, pp. 63-72
- Reis A. V., Cavalcanti O.A., Rubira A. F., Muniz E. C., (2003)," Synthesis and characterization of hydrogels formed from a glycidyl methacrylate derivative of galactomannan " Int J Pharm, 267, pp.13-25
- Marton, O. R. Varnishes and Lacquers, European Polymer Journal, 1968
Öz
Kaynakça
- Bevinton, J. C., Malpass, B. W. (1965) " Reactivity ratios for the copolymerization of acrylates and methacrylates by nuclear magnetic resonance spectroscopy "European polymer journal, 1, pp.55
- Coustantinova, T. N., Garbechev, I. K., (1998) polymer International, 43, pp. 49
- Rouhallah B., Ali-asghar, M. (1998) Synthesis of methyl methacrylate-n-butylacrylate copolymers: Study of the paint properties ""J. Appl. Polym. Sci 70, pp. 367-372
- Vijayanand P.S, Aron Prasath R., Balaji R., Nanjundan S., (2002) " Synthesis, spectral properties, and thermal properties of homo- and copolymers of 3,5-dimethylphenyl acrylate with glycidyl methacrylate and determination of reactivity ratios "J Appl Polym Sci 85, pp. 2261-2270
- Ajmal, A., Mideen, A. S., Quraishi, M. A. (1994) " Green seed extract of Tectona grandis as corrosion inhibitor for mild steel in acid medium" Corros. Sci 36, pp. 79
- Singh, I. (1993) "Synthesis, characterization, and corrosion protection properties of poly(N-(methacryloyloxymethyl) benzotriazole-co-methyl methacrylate) on mild steel " Corrosion, 49, pp. 122
- Vijayanand, P. S., Sreekuttan Unnithan, C., Penlidis, A., Nanjundan, S. (2007), " Copolymerization of 4-Acetylphenyl Methacrylate with Ethyl Methacrylate: Synthesis, Characterization, Monomer Reactivity Ratios, and Thermal Properties " Journal of macromolecular science, 42, pp. 555-569
- Mizognchi, K. Hasegawa, E., (1996) "Studies on photocrosslinkable copolymers of 4- methacryloyloxyphenyl-3′,4′-dimethoxystyryl ketone and methyl methacrylate."Polym. Adv. Technol. 7 pp. 471.
- Patel R. J., Patel Z. H., Patel B. C., Bhavesh P. D. (2013) "Synthesis of acrylic copolymers and their antimicrobial screening" Der Pharma Chemica, 5, pp. 63-72
- Reis A. V., Cavalcanti O.A., Rubira A. F., Muniz E. C., (2003)," Synthesis and characterization of hydrogels formed from a glycidyl methacrylate derivative of galactomannan " Int J Pharm, 267, pp.13-25
- Marton, O. R. Varnishes and Lacquers, European Polymer Journal, 1968
Ayrıntılar
| Bölüm | Derleme |
|---|---|
| Yazarlar | |
| Yayımlanma Tarihi | 13 Mayıs 2015 |
| Yayımlandığı Sayı | Yıl 2015 Cilt: 36 Sayı: 3 |