BAZI HOFMANN-Td-TİPİ KLATRATLARIN TİTREŞİM SPEKTROSKOPİSİ İLE İNCELENMESİ: Ni(1,9-DİAMİNONONAN)M(CN)4.2G (M = Cd VEYA Hg, G = 1,3-DİKLOROBENZEN)

Yıl 2009, Sayı: 020, 1 - 6, 15.12.2009

Cemal Parlak

Öz

Ni(1,9-diaminononan)M(CN)₄.2G
(M = Cd veya Hg, 1,9-diaminononan = danon, G = 1,3-diklorobenzen) genel
formülüne sahip Hofmann-T_d-tipi klatratlar toz halde hazırlanmakta
ve bunların infrared ve Raman spektrumları sırasıyla (4000–200) cm^-1
ve (2850–1650) cm^-1 aralıklarında incelenmektedir. Spektrum
sonuçları bu bileşiklerin yapısal olarak Hofmann-T_d-tipi klatratlara
benzediğini ortaya koymaktadır.

Anahtar Kelimeler

Hofmann-Td-tipi klatrat; Titreşim spektrumu; 1, 9-diaminononan, 3-diklorobenzen

VIBRATIONAL SPECTROSCOPIC INVESTIGATION ON SOME HOFMANN-TdTYPE CLATHRATES: Ni(1,9-DIAMINONONANE)M(CN)4.2G (M = Cd OR Hg, G = 1,3-DICHLOROBENZENE)

Öz

New Hofmann-T_d-type
clathrates in the general form of Ni(1,9-diaminononane)M(CN)₄.2G
(M = Cd or Hg,                1,9-diaminononane
= danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR
and Raman spectra have been reported in the range of (4000–200) cm^-1 and (2850–1650)
cm^-1, respectively. The spectral results suggest that these
compounds are similar in structure to the Hofmann-T_d-type
clathrates.

New Hofmann-T_d-type
clathrates in the general form of Ni(1,9-diaminononane)M(CN)₄.2G
(M = Cd or Hg,                1,9-diaminononane
= danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR
and Raman spectra have been reported in the range of (4000–200) cm^-1 and (2850–1650)
cm^-1, respectively. The spectral results suggest that these
compounds are similar in structure to the Hofmann-T_d-type
clathrates.

Anahtar Kelimeler

Hofmann-Td-type clathrate, Vibrational spectrum, 1, 9-diaminononane, 3-dichlorobenzene

Kaynakça

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