Öz
Polylactic acid (PLA) is used as a potential polymer for consumer products and biomedical applications. With the increasing environmental and sustainability concerns associated with traditional petrochemical-based polymers, PLA applications continue to increase every day. Activated carbon (A.C.) is a substance obtained by carbonization of softwood parts such as linden and willow and is used as an antidote in industrial applications because it absorbs the toxin and prevents the absorption of toxins from the small intestine into the blood. It is a toxin absorber due to its adhesion to surfaces. A.C. the biggest problem with the fact that over time, the gaseous pollutants A.C. is a gradual filling of adsorption surfaces. In this study, PLA nanofibers reinforced with biyokompozit elektrospinning technique has been secured for the production and structural (FTIR, Fourier-Transform İnfrared Spectroscopy), morphological (FEGSEM, Field Emission Gun Scanning Electron Microscope), mechanical (Tensile Test) and biological (Cell Culture) by providing a characterization of the material properties were determined. With the obtained biocomposites, it will be able to be the ideal filtration material with a longer life and a large surface area that can be used in health sector applications.
Anahtar Kelimeler
Polylactic Acid Activated Charcoal Electrospinning Clean Air Filtration
Teşekkür
The author also would like to thank to Polymer Technologies and Composite Application and Research Center (ArelPOTKAM) for their help in material characterization.
Kaynakça
- J. M. Anderson & M. S. Shive, “Biodegradation and biocompatibility of PLA and PLGA microspheres. Advanced drug delivery reviews,” 28(1), 5-24, 1997.
- S. S. Ray & M. Bousmina, “Poly (butylene sucinate-co-adipate)/montmorillonite nanocomposites: effect of organic modifier miscibility on structure, properties, and viscoelasticity,” Polymer, 46(26), 12430-12439, 2005.
- A. R. Kakroodi, Y. Kazemi, M., Nofar & C. B. Park, “Tailoring poly (lactic acid) for packaging applications via the production of fully bio-based in situ microfibrillar composite films,” Chemical Engineering Journal, 308, 772-782, 2017.
- Y. K. Dasan, A. H. Bhat & F. Ahmad, “Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging material,” Carbohydrate polymers, 157, 1323-1332, 2017.
- https://muhendistan.com/aktif-karbon-filtreler
- C. J. Kensler & S. Battista, “Components of cigarette smoke with ciliary-depressant activity: Their selective removal by filters containing activated charcoal granules,” New England Journal of Medicine, 269(22), 1161-1166, 1963.
- Y. Zhao, L. Zhou & Z. Wang, “Direct melting polycondensation and characterization of poly (ɛ-caprolactone-co-lactic acid),” Frontiers of Chemistry in China, 2(2), 178-182, 2007.
- F. Aynali, H. Balci, E. Doganci & E. Bulus, “Production and characterization of non-leaching antimicrobial and hydrophilic polycaprolactone based nanofiber mats,” European Polymer Journal, 149, 110368, 2021.
- E. Buluş, G. S. Buluş & M. Akkaş, “Investigation of the Effects of Working Parameters in Electrospinning Technology on Morphology of Polymeric Nanofiber Membranes Using Reference Polymers,” JOURNAL OF MATERIALS AND ELECTRONIC DEVICES, 2(1), 6-11, 2021.
- C. M. Vaz, S. Van Tuijl, C. V. C. Bouten & F. P. T. Baaijens, “Design of scaffolds for blood vessel tissue engineering using a multi-layering electrospinning technique,” Acta biomaterialia, 1(5), 575-582, 2005.
Öz
Polilaktik asit (PLA), tüketici ürünleri ve biyomedikal uygulamalar için potansiyel bir polimer olarak kullanılmaktadır. Geleneksel petrokimya bazlı polimerlerle ilişkili artan çevresel ve sürdürülebilirlik endişeleri ile PLA uygulamaları her geçen gün artmaya devam etmektedir. Aktif karbon (A.K.), ıhlamur ve söğüt gibi yumuşak ağaç kısımlarının karbonizasyonu ile elde edilen bir maddedir ve toksini emdiği ve toksinlerin ince bağırsaktan kana emilimini engellediği için endüstriyel uygulamalarda panzehir olarak kullanılmaktadır. Yüzeylere yapışması nedeniyle toksin emicidir. A.K. ile ilgili en büyük problem, zamanla gaz halindeki kirleticilerin A.K.'nin adsorpsiyon yüzeylerini yavaş yavaş doldurmasıdır. Yapılan bu çalışmada, elektroeğirme tekniği ile güçlendirilmiş PLA nanofiber biyokompozit üretimi sağlanmış olup, yapısal (FTIR, Fourier Dönüşümlü Kızılötesi Spektroskopi), morfolojik (FEGSEM, Alan Emisyon Tabancası Taramalı Elektron Mikroskobu), mekanik (Çekme Testi) ve biyolojik (Hücre Kültürü) karakterizasyonu sağlanarak malzeme özellikleri belirlenmiştir. Elde edilen biyokompozitler ile sağlık sektörü uygulamalarında kullanılabilecek daha uzun ömürlü ve geniş yüzey alanına sahip ideal filtrasyon materyali olabilecektir.
Anahtar Kelimeler
Polilaktik Asit Aktif Kömür Elektrospinning Temiz Hava Filtrasyonu
Kaynakça
- J. M. Anderson & M. S. Shive, “Biodegradation and biocompatibility of PLA and PLGA microspheres. Advanced drug delivery reviews,” 28(1), 5-24, 1997.
- S. S. Ray & M. Bousmina, “Poly (butylene sucinate-co-adipate)/montmorillonite nanocomposites: effect of organic modifier miscibility on structure, properties, and viscoelasticity,” Polymer, 46(26), 12430-12439, 2005.
- A. R. Kakroodi, Y. Kazemi, M., Nofar & C. B. Park, “Tailoring poly (lactic acid) for packaging applications via the production of fully bio-based in situ microfibrillar composite films,” Chemical Engineering Journal, 308, 772-782, 2017.
- Y. K. Dasan, A. H. Bhat & F. Ahmad, “Polymer blend of PLA/PHBV based bionanocomposites reinforced with nanocrystalline cellulose for potential application as packaging material,” Carbohydrate polymers, 157, 1323-1332, 2017.
- https://muhendistan.com/aktif-karbon-filtreler
- C. J. Kensler & S. Battista, “Components of cigarette smoke with ciliary-depressant activity: Their selective removal by filters containing activated charcoal granules,” New England Journal of Medicine, 269(22), 1161-1166, 1963.
- Y. Zhao, L. Zhou & Z. Wang, “Direct melting polycondensation and characterization of poly (ɛ-caprolactone-co-lactic acid),” Frontiers of Chemistry in China, 2(2), 178-182, 2007.
- F. Aynali, H. Balci, E. Doganci & E. Bulus, “Production and characterization of non-leaching antimicrobial and hydrophilic polycaprolactone based nanofiber mats,” European Polymer Journal, 149, 110368, 2021.
- E. Buluş, G. S. Buluş & M. Akkaş, “Investigation of the Effects of Working Parameters in Electrospinning Technology on Morphology of Polymeric Nanofiber Membranes Using Reference Polymers,” JOURNAL OF MATERIALS AND ELECTRONIC DEVICES, 2(1), 6-11, 2021.
- C. M. Vaz, S. Van Tuijl, C. V. C. Bouten & F. P. T. Baaijens, “Design of scaffolds for blood vessel tissue engineering using a multi-layering electrospinning technique,” Acta biomaterialia, 1(5), 575-582, 2005.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 31 Temmuz 2023 |
| Yayımlandığı Sayı | Yıl 2023 |