Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination

Ahmad Badreddin Musatat; Alparslan Atahan; Mecit Aksu; Mustafa Zengin

doi:10.29130/dubited.1148897

TR EN

Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination

Abstract

This study reports the evaluation of 2-acetylpyridine based chalcone structure as a useful sensing material for Hg2+ ion detection by the means of UV-visible spectroscopy. In this context, firstly, the most common twenty metal ions were treated by the chalcone structure which was synthesized from 2-acetylpyridine and 4-diphenylaminobenzaldehyde according to the known procedures. As result, the studied chalcone compound exhibited good sensing activity towards Hg2+ ion in acetonitrile/water medium with significant red-shift phenomenon. In addition, some photophysical/electronic parameters of the chalcone and its Hg2+ complex were determined experimentally and theoretically. B3LYP, PBE0 methods and SVP, TVZP, and TVZPP basis sets were used for theoretical calculations in acetonitrile media. Finally, experimental results were explained and the proposed sensing mechanism was supported via density functional theory (DFT) outputs.

Keywords

Chalcone, Sensors, UV/Vis Spectroscopy, Density functional theory

Thanks

The authors are thankful to Department of Chemistry of Düzce University and Department of Chemistry of Sakarya University for the laboratory facilities.

References

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Ahmad Badreddin Musatat
0000-0002-4137-4901
Türkiye

Alparslan Atahan ^*
0000-0001-8904-9377
Türkiye

Mecit Aksu
0000-0002-9405-1217
Türkiye

Mustafa Zengin
0000-0002-0243-1432
Türkiye

Publication Date

October 25, 2022

Submission Date

July 26, 2022

Acceptance Date

September 8, 2022

Published in Issue

Year 2022 Volume: 10 Number: 4

DOI

https://doi.org/10.29130/dubited.1148897

IZ

https://izlik.org/JA24RF34EB

APA

Musatat, A. B., Atahan, A., Aksu, M., & Zengin, M. (2022). Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination. Duzce University Journal of Science and Technology, 10(4), 2133-2143. https://doi.org/10.29130/dubited.1148897

AMA

1.Musatat AB, Atahan A, Aksu M, Zengin M. Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination. DUBİTED. 2022;10(4):2133-2143. doi:10.29130/dubited.1148897

Chicago

Musatat, Ahmad Badreddin, Alparslan Atahan, Mecit Aksu, and Mustafa Zengin. 2022. “Employing of 2-Acetylpyridine Based Chalcone As Hg2+ Sensing Material: Experimental and Theoretical Examination”. Duzce University Journal of Science and Technology 10 (4): 2133-43. https://doi.org/10.29130/dubited.1148897.

EndNote

Musatat AB, Atahan A, Aksu M, Zengin M (October 1, 2022) Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination. Duzce University Journal of Science and Technology 10 4 2133–2143.

IEEE

[1]A. B. Musatat, A. Atahan, M. Aksu, and M. Zengin, “Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination”, DUBİTED, vol. 10, no. 4, pp. 2133–2143, Oct. 2022, doi: 10.29130/dubited.1148897.

ISNAD

Musatat, Ahmad Badreddin - Atahan, Alparslan - Aksu, Mecit - Zengin, Mustafa. “Employing of 2-Acetylpyridine Based Chalcone As Hg2+ Sensing Material: Experimental and Theoretical Examination”. Duzce University Journal of Science and Technology 10/4 (October 1, 2022): 2133-2143. https://doi.org/10.29130/dubited.1148897.

JAMA

1.Musatat AB, Atahan A, Aksu M, Zengin M. Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination. DUBİTED. 2022;10:2133–2143.

MLA

Musatat, Ahmad Badreddin, et al. “Employing of 2-Acetylpyridine Based Chalcone As Hg2+ Sensing Material: Experimental and Theoretical Examination”. Duzce University Journal of Science and Technology, vol. 10, no. 4, Oct. 2022, pp. 2133-4, doi:10.29130/dubited.1148897.

Vancouver

1.Ahmad Badreddin Musatat, Alparslan Atahan, Mecit Aksu, Mustafa Zengin. Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination. DUBİTED. 2022 Oct. 1;10(4):2133-4. doi:10.29130/dubited.1148897

Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination

2-Asetilpiridin Bazlı Kalkonun Hg2+ Sensör Malzemesi Olarak Kullanılması: Deneysel ve Teorik İnceleme

Abstract

Keywords

Employing of 2-Acetylpyridine Based Chalcone as Hg2+ Sensing Material: Experimental and Theoretical Examination

Abstract

Keywords

Thanks

References

Details

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Subjects

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Acceptance Date

Published in Issue

DOI

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