Research Article
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Endüstriyel Asitleme ile Oluşturulan Yüzey Özelliklerinin Boya Yapışma Direnci ve Korozyon Performansına Etkisi

Year 2026, Volume: 14 Issue: 1, 240 - 249, 21.01.2026
https://doi.org/10.29130/dubited.1792680

Abstract

Bu çalışmada, endüstriyel asitleme işlemleri sırasında oluşan ve asit yanığı ve durdurma izleri olarak adlandırılan yüzey kusurlarının düşük karbonlu çelik bir sacın boya yapışma performansı ve korozyon direnci üzerindeki etkisi araştırılmıştır. Optimum ölçüde asitlenmiş, aşırı asitlenmiş ve durdurma izi oluşturulmuş yüzeylerin bu özellikleri, boyama sonrasında yapışma testi (EN ISO 2409:2020) ve tuz püskürtme (ASTM B117-19) testi ile karşılaştırmalı olarak değerlendirilmiştir. Endüstriyel asitleme sınırları içerisinde yürütülen çalışmalardan elde edilen bulgular, hem optimum ölçüde asitlenmiş hem de aşırı asitlenmiş yüzeyler için tatmin edici boya yapışması (Sınıf 0) ve korozyon direnci (Derece 10) ortaya çıkarmıştır. Durdurma izi oluşturulmuş yüzeyler sorunsuz boya yapışması göstermiş, ancak korozyon direncinde hafif bir düşüş (72 saat sonra Derece 9) tespit edilmiştir. Bu kusurların etkisini daha kesin bir şekilde değerlendirmek için, daha zorlu ve uzun süreli duruş koşulları altında ek testler yapılmalı ve bunlar gelişmiş yüzey analiz teknikleriyle desteklenmelidir.

References

  • Akbar, D. H., Purnami, P. & Budio, S. P. (2020). Influence of Surface Roughness and Paint Coating on Corrosion Rate. International Journal of Mechanical Engineering Technologies and Applications, 1(1), 15-19. https://doi.org/10.21776/mechta.2020.001.01.3
  • Anderez, F. J. A., Alguacil, F. J., & López, F. A. (2022). Review: Acid pickling of carbon steel. Revista de Metalurgia, 58(3), Article e226. https://doi.org/10.3989/revmetalm.226
  • ASTM International. (2008). Standard test method for evaluation of painted or coated specimens subjected to corrosive environments (ASTM D1654-08).
  • ASTM International. (2019). Standard practice for operating salt spray (fog) apparatus (ASTM B117-19).
  • Croll, S. G. (2020). Surface roughness profile and its effect on coating adhesion and corrosion protection: A review. Progress in Organic Coatings, 148, Article 105847. https://doi.org/10.1016/j.porgcoat.2020.105847
  • Feser, R., Friedrich, A., & Scheide, F. (2002). The influence of long term use of inhibitors in hydrochloric acid pickling baths on hydrogen induced stress corrosion cracking. Materials and Corrosion, 53(9), 637–646. https://doi.org/10.1002/1521-4176(200209)53:9<637::AID-MACO637>3.0.CO;2-P
  • International Organization for Standardization (ISO). (2020). Paints and varnishes – Cross-cut test (ISO 2409:2020).
  • Kim, A., Kainuma, S., & Yang, M. (2021). Surface characteristics and corrosion behavior of carbon steel treated by abrasive blasting. Metals, 11(12), Article 2065. https://doi.org/10.3390/met11122065
  • Krishna, D. N. G., & Philip, J. (2022). Review on surface-characterization applications of X-ray photoelectron spectroscopy (XPS): Recent developments and challenges. Applied Surface Science Advances, 12, Article 100332. https://doi.org/10.1016/j.apsadv.2022.100332
  • Kuron, D. (Ed.). (1986). Wasserstoff und Korrosion. Festschrift einer Autorengruppe zum 60. Geburtstag von Prof. Dr. Hubert Grafen. Verlag Irene Kuron.
  • Lee, H. S., & Park, P. (2022). Implementation of control structure for steel pickling process using model predictive controller. IFAC-Papers OnLine, 55(7), 679–684. https://doi.org/10.1016/j.ifacol.2022.07.522
  • Maanonen, M. (2014). Steel pickling in challenging conditions [Bachelor’s thesis, Helsinki Metropolia University of Applied Sciences].
  • Moran Machinery. (n.d.). Continuous pickling line for steel coil. Retrieved September 26, 2025, from https://www.moranmachinery.com/pickling-line/acid-pickling-line.html
  • Özdemir, T., Öztin, C., & Kincal, N. S. (2006). Treatment of waste pickling liquors: Process synthesis and economic analysis. Chemical Engineering Communications, 193(5), 548–563. https://doi.org/10.1080/00986440500192238
  • Paatsch, W. (2011). Hydrogen determination and hydrogen embrittlement – Meaning and advantage. Galvanotechnik, 102(1), 48–55.
  • Poleunis, C., Compere, C., & Bertrand, P. (2002). Time-of-flight secondary ion mass spectrometry: Characterisation of stainless steel surfaces immersed in natural seawater. Journal of Microbiological Methods, 48(2–3), 195–205. https://doi.org/10.1016/s0167-7012(01)00323-2
  • Reidenbach, F. (Ed.). (1994). ASM handbook (Vol. 5, Surface Engineering, 19th ed.). ASM International.
  • Sunny Technologies. (n.d.). Continuous pickling line. Retrieved September 26, 2025, from https://en.sunnychina.com.cn/product/7.html
  • Tang, B., Su, W., Wang, J., Fu, F., Yu, G., & Zhang, J. (2012). Minimizing the creation of spent pickling liquors in a pickling process with high-concentration hydrochloric acid solutions: Mechanism and evaluation method. Journal of Environmental Management, 98(1), 147–154. https://doi.org/10.1016/j.jenvman.2011.12.027
  • TradeIndia. (n.d.). Continuous pickling line. Retrieved September 26, 2025, from https://www.tradeindia.com/products/continuous-pickling-line-1961557.html
  • Treischel, C. (1919). The cause and control of “Blistering” in sheet-steel enameling. Journal of the American Ceramic Society, 2(10), 774–781. https://doi.org/10.1111/j.1151-2916.1919.tb17472.x
  • Staley, H. F. (1926). The theory of pickling of sheet iron and steel for enameling purposes. Journal of the American Ceramic Society, 9(12), 787–796. https://doi.org/10.1111/j.1151-2916.1926.tb17958.x
  • Yang, F., Wu, Y., Fang, X., & Ma, L. (2020). Experimental and theoretical study on the behaviour of a pickling solution: The role of ferrous ions. Journal of Cleaner Production, 243, Article 118631. https://doi.org/10.1016/j.jclepro.2019.118631

The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance

Year 2026, Volume: 14 Issue: 1, 240 - 249, 21.01.2026
https://doi.org/10.29130/dubited.1792680

Abstract

This study investigated the effects of surface defects, known as acid burns and stop marks, formed during industrial pickling processes on the paint adhesion performance and corrosion resistance of a low-carbon steel sheet. These properties of optimally pickled, heavily pickled, and stop mark-formed surfaces were evaluated comparatively using a post-painting adhesion test (EN ISO 2409:2020) and salt spray (ASTM B117-19) tests. Findings from studies conducted within the industrial pickling range revealed satisfactory paint adhesion (Grade 0) and corrosion resistance (Grade 10) for optimally pickled and heavily pickled surfaces. The stop mark-formed surfaces exhibited excellent paint adhesion, but a slight decrease in corrosion resistance (Grade 9 after 72 hours) was observed. To more accurately assess the impact of these defects, additional tests should be conducted under more challenging and prolonged stop conditions, supported by advanced surface analysis techniques.

Ethical Statement

This study does not involve human or animal participants. All procedures followed scientific and ethical principles, and all referenced studies are appropriately cited.

Supporting Institution

This research received no external funding.

Thanks

The author does not wish to acknowledge any individual or institution.

References

  • Akbar, D. H., Purnami, P. & Budio, S. P. (2020). Influence of Surface Roughness and Paint Coating on Corrosion Rate. International Journal of Mechanical Engineering Technologies and Applications, 1(1), 15-19. https://doi.org/10.21776/mechta.2020.001.01.3
  • Anderez, F. J. A., Alguacil, F. J., & López, F. A. (2022). Review: Acid pickling of carbon steel. Revista de Metalurgia, 58(3), Article e226. https://doi.org/10.3989/revmetalm.226
  • ASTM International. (2008). Standard test method for evaluation of painted or coated specimens subjected to corrosive environments (ASTM D1654-08).
  • ASTM International. (2019). Standard practice for operating salt spray (fog) apparatus (ASTM B117-19).
  • Croll, S. G. (2020). Surface roughness profile and its effect on coating adhesion and corrosion protection: A review. Progress in Organic Coatings, 148, Article 105847. https://doi.org/10.1016/j.porgcoat.2020.105847
  • Feser, R., Friedrich, A., & Scheide, F. (2002). The influence of long term use of inhibitors in hydrochloric acid pickling baths on hydrogen induced stress corrosion cracking. Materials and Corrosion, 53(9), 637–646. https://doi.org/10.1002/1521-4176(200209)53:9<637::AID-MACO637>3.0.CO;2-P
  • International Organization for Standardization (ISO). (2020). Paints and varnishes – Cross-cut test (ISO 2409:2020).
  • Kim, A., Kainuma, S., & Yang, M. (2021). Surface characteristics and corrosion behavior of carbon steel treated by abrasive blasting. Metals, 11(12), Article 2065. https://doi.org/10.3390/met11122065
  • Krishna, D. N. G., & Philip, J. (2022). Review on surface-characterization applications of X-ray photoelectron spectroscopy (XPS): Recent developments and challenges. Applied Surface Science Advances, 12, Article 100332. https://doi.org/10.1016/j.apsadv.2022.100332
  • Kuron, D. (Ed.). (1986). Wasserstoff und Korrosion. Festschrift einer Autorengruppe zum 60. Geburtstag von Prof. Dr. Hubert Grafen. Verlag Irene Kuron.
  • Lee, H. S., & Park, P. (2022). Implementation of control structure for steel pickling process using model predictive controller. IFAC-Papers OnLine, 55(7), 679–684. https://doi.org/10.1016/j.ifacol.2022.07.522
  • Maanonen, M. (2014). Steel pickling in challenging conditions [Bachelor’s thesis, Helsinki Metropolia University of Applied Sciences].
  • Moran Machinery. (n.d.). Continuous pickling line for steel coil. Retrieved September 26, 2025, from https://www.moranmachinery.com/pickling-line/acid-pickling-line.html
  • Özdemir, T., Öztin, C., & Kincal, N. S. (2006). Treatment of waste pickling liquors: Process synthesis and economic analysis. Chemical Engineering Communications, 193(5), 548–563. https://doi.org/10.1080/00986440500192238
  • Paatsch, W. (2011). Hydrogen determination and hydrogen embrittlement – Meaning and advantage. Galvanotechnik, 102(1), 48–55.
  • Poleunis, C., Compere, C., & Bertrand, P. (2002). Time-of-flight secondary ion mass spectrometry: Characterisation of stainless steel surfaces immersed in natural seawater. Journal of Microbiological Methods, 48(2–3), 195–205. https://doi.org/10.1016/s0167-7012(01)00323-2
  • Reidenbach, F. (Ed.). (1994). ASM handbook (Vol. 5, Surface Engineering, 19th ed.). ASM International.
  • Sunny Technologies. (n.d.). Continuous pickling line. Retrieved September 26, 2025, from https://en.sunnychina.com.cn/product/7.html
  • Tang, B., Su, W., Wang, J., Fu, F., Yu, G., & Zhang, J. (2012). Minimizing the creation of spent pickling liquors in a pickling process with high-concentration hydrochloric acid solutions: Mechanism and evaluation method. Journal of Environmental Management, 98(1), 147–154. https://doi.org/10.1016/j.jenvman.2011.12.027
  • TradeIndia. (n.d.). Continuous pickling line. Retrieved September 26, 2025, from https://www.tradeindia.com/products/continuous-pickling-line-1961557.html
  • Treischel, C. (1919). The cause and control of “Blistering” in sheet-steel enameling. Journal of the American Ceramic Society, 2(10), 774–781. https://doi.org/10.1111/j.1151-2916.1919.tb17472.x
  • Staley, H. F. (1926). The theory of pickling of sheet iron and steel for enameling purposes. Journal of the American Ceramic Society, 9(12), 787–796. https://doi.org/10.1111/j.1151-2916.1926.tb17958.x
  • Yang, F., Wu, Y., Fang, X., & Ma, L. (2020). Experimental and theoretical study on the behaviour of a pickling solution: The role of ferrous ions. Journal of Cleaner Production, 243, Article 118631. https://doi.org/10.1016/j.jclepro.2019.118631
There are 23 citations in total.

Details

Primary Language English
Subjects Material Design and Behaviors
Journal Section Research Article
Authors

Candan Sen Elkoca 0000-0002-6123-835X

Submission Date September 28, 2025
Acceptance Date December 15, 2025
Publication Date January 21, 2026
Published in Issue Year 2026 Volume: 14 Issue: 1

Cite

APA Sen Elkoca, C. (2026). The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance. Duzce University Journal of Science and Technology, 14(1), 240-249. https://doi.org/10.29130/dubited.1792680
AMA Sen Elkoca C. The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance. DUBİTED. January 2026;14(1):240-249. doi:10.29130/dubited.1792680
Chicago Sen Elkoca, Candan. “The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance”. Duzce University Journal of Science and Technology 14, no. 1 (January 2026): 240-49. https://doi.org/10.29130/dubited.1792680.
EndNote Sen Elkoca C (January 1, 2026) The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance. Duzce University Journal of Science and Technology 14 1 240–249.
IEEE C. Sen Elkoca, “The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance”, DUBİTED, vol. 14, no. 1, pp. 240–249, 2026, doi: 10.29130/dubited.1792680.
ISNAD Sen Elkoca, Candan. “The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance”. Duzce University Journal of Science and Technology 14/1 (January2026), 240-249. https://doi.org/10.29130/dubited.1792680.
JAMA Sen Elkoca C. The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance. DUBİTED. 2026;14:240–249.
MLA Sen Elkoca, Candan. “The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance”. Duzce University Journal of Science and Technology, vol. 14, no. 1, 2026, pp. 240-9, doi:10.29130/dubited.1792680.
Vancouver Sen Elkoca C. The Effect of Surface Properties Created by Industrial Pickling on Paint Adhesion Resistance and Corrosion Performance. DUBİTED. 2026;14(1):240-9.