One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu

Sema Allı; Pinar Geçit; Murat Gürel; Abdulkadir Allı

doi:10.29130/dubited.434025

EN TR

Synthesis and Characterization of Poly(linoleic acid)-g-poly(Nisopropylacrylamide)-g-poly (D, L-lactide) Graft Copolymers by Onepot Polymerization Method

Abstract

In this study, one-pot three-block graft copolymers were synthesized using a combination of ring opening polymerization and free radical polymerization of Auto-oxidized polymeric linoleic acid peroxide (PLina). Graft copolymers with poly(linoleic acid)-g-poly(N-isopropylacrylamide)-g-poly(D,L-lactide) structure were synthesized the free radical polymerization with N-isopropylacrylamide (NIPAM) in monomer the main chain of PLina and the ring opening polymerization of the D, L-lactide (LA) monomer with carboxylic acid groups of PLina with together. The basic parameters such as polymerization time, initiator concentration and monomer concentration affecting the one-pot polymerization reaction were investigated. Characterization of the obtained graft copolymers were carried out using 1H NMR and GPC techniques.

Keywords

Autooxidation, ε-caprolacton, D,L-lactid, N-isopropilacrylamide, Linoleic acid, Auto-oxidation, One-step (one-pot) polymerization

One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu

Abstract

Bu çalışmada, Otookside polimerik linoleik asit peroksit (PLina)’nın halka açılma polimerizasyonu ve serbest radikal polimerizasyonu bir arada kullanılarak tek adımda (one-pot) üç bloklu graft kopolimerler sentezlendi. Poli(linoleik asit)-g-poli(N-isopropilakrilamit)-g-poli(D,L-laktid) yapısına sahip graft kopolimerler; PLina’nın ana zincirinde bulunan peroksit grupları ile N-isopropilakrilamit (NIPAM) monomeriyle serbest radikal polimerizasyonu ve PLina’nın karboksilik asit grupları ile D,L-laktid (LA) monomeri arasındaki halka açılma polimerizasyonunun bir arada (one-pot) kullanılmasıyla sentezlendiler. One-pot polimerizasyon reaksiyonuna etki eden polimerizasyon süresi, başlatıcı konsantrasyonu ve monomer konsantrasyonu gibi temel parametreler incelendi. Elde edilen graft kopolimerlerin karakterizasyonları ¹H NMR ve GPC teknikleri kullanılarak yapıldı.

Keywords

ε-kaprolakton, N-izopropilakrilamit, D, L-laktid, Linoleik asit, Linolenik asit, Otooksidasyon, Tek adım(one-pot) polimerizasyonu

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Sema Allı ^*
Türkiye

Pinar Geçit This is me
Türkiye

Murat Gürel
Türkiye

Abdulkadir Allı
Türkiye

Publication Date

August 1, 2018

Submission Date

June 14, 2018

Acceptance Date

June 29, 2018

Published in Issue

Year 2018 Volume: 6 Number: 4

DOI

https://doi.org/10.29130/dubited.434025

IZ

https://izlik.org/JA62RY47KZ

APA

Allı, S., Geçit, P., Gürel, M., & Allı, A. (2018). One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology, 6(4), 1321-1334. https://doi.org/10.29130/dubited.434025

AMA

1.Allı S, Geçit P, Gürel M, Allı A. One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu. DUBİTED. 2018;6(4):1321-1334. doi:10.29130/dubited.434025

Chicago

Allı, Sema, Pinar Geçit, Murat Gürel, and Abdulkadir Allı. 2018. “One-Pot PolimerleşmeYöntemiyle Poli(linoleik Asit)-G-Poli(N-Isopropilakrilamit)-G-Poli(D,L-Laktid) Graft Kopolimerlerin Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 6 (4): 1321-34. https://doi.org/10.29130/dubited.434025.

EndNote

Allı S, Geçit P, Gürel M, Allı A (August 1, 2018) One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu. Duzce University Journal of Science and Technology 6 4 1321–1334.

IEEE

[1]S. Allı, P. Geçit, M. Gürel, and A. Allı, “One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu”, DUBİTED, vol. 6, no. 4, pp. 1321–1334, Aug. 2018, doi: 10.29130/dubited.434025.

ISNAD

Allı, Sema - Geçit, Pinar - Gürel, Murat - Allı, Abdulkadir. “One-Pot PolimerleşmeYöntemiyle Poli(linoleik Asit)-G-Poli(N-Isopropilakrilamit)-G-Poli(D,L-Laktid) Graft Kopolimerlerin Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology 6/4 (August 1, 2018): 1321-1334. https://doi.org/10.29130/dubited.434025.

JAMA

1.Allı S, Geçit P, Gürel M, Allı A. One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu. DUBİTED. 2018;6:1321–1334.

MLA

Allı, Sema, et al. “One-Pot PolimerleşmeYöntemiyle Poli(linoleik Asit)-G-Poli(N-Isopropilakrilamit)-G-Poli(D,L-Laktid) Graft Kopolimerlerin Sentezi Ve Karakterizasyonu”. Duzce University Journal of Science and Technology, vol. 6, no. 4, Aug. 2018, pp. 1321-34, doi:10.29130/dubited.434025.

Vancouver

1.Sema Allı, Pinar Geçit, Murat Gürel, Abdulkadir Allı. One-pot PolimerleşmeYöntemiyle Poli(linoleik asit)-g-Poli(N-isopropilakrilamit)-g-Poli(D,L-laktid) Graft Kopolimerlerin Sentezi ve Karakterizasyonu. DUBİTED. 2018 Aug. 1;6(4):1321-34. doi:10.29130/dubited.434025

Cited By

Polimerik Linoleik Asit İçeren Graft Kopolimerlerin Atom Transfer Radikal Polimerizasyonu ve Kondenzasyon Reaksiyonu ile Sentezi ve Karakterizasyonu

Düzce Üniversitesi Bilim ve Teknoloji Dergisi

https://doi.org/10.29130/dubited.927837