Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones

Kenan Buldurun; İsmail Özdemir

doi:10.29130/dubited.473988

TR

Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones

Abstract

In this study,N-substituted 5-nitrobenzimidazole ligands were reacted with [RuCl₂(p-cymene)]₂ and the corresponding complexes were prepared and their structure were elucidated by elemental analysis, IR and NMR spectroscopic techniques. The synthesized Ru(II) complexes were tested as catalysts for the transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence of KOH using 2–propanol as a hydrogen source at 82 ºC. This complexes was found to be an active catalyst in the catalytic transfer hydrogenation of ketones.

Keywords

Benzimidazole,Catalysis,Ru(II) complexes,transfer hydrogenation

References

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Kenan Buldurun ^*
0000-0002-2462-7006
Türkiye

İsmail Özdemir
0000-0001-6325-0216

Publication Date

March 30, 2019

Submission Date

October 24, 2018

Acceptance Date

January 25, 2019

Published in Issue

Year 2019 Volume: 7 Number: 2

DOI

https://doi.org/10.29130/dubited.473988

IZ

https://izlik.org/JA38FU45MP

APA

Buldurun, K., & Özdemir, İ. (2019). Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. Duzce University Journal of Science and Technology, 7(2), 63-72. https://doi.org/10.29130/dubited.473988

AMA

1.Buldurun K, Özdemir İ. Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. DUBİTED. 2019;7(2):63-72. doi:10.29130/dubited.473988

Chicago

Buldurun, Kenan, and İsmail Özdemir. 2019. “Ruthenium(II) Half-Sandwich Complexes Containing N-Substituted 5-Nitrobenzimidazole: Synthesis, Structures and Catalytic Transfer Hydrogenation of Ketones”. Duzce University Journal of Science and Technology 7 (2): 63-72. https://doi.org/10.29130/dubited.473988.

EndNote

Buldurun K, Özdemir İ (March 1, 2019) Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. Duzce University Journal of Science and Technology 7 2 63–72.

IEEE

[1]K. Buldurun and İ. Özdemir, “Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones”, DUBİTED, vol. 7, no. 2, pp. 63–72, Mar. 2019, doi: 10.29130/dubited.473988.

ISNAD

Buldurun, Kenan - Özdemir, İsmail. “Ruthenium(II) Half-Sandwich Complexes Containing N-Substituted 5-Nitrobenzimidazole: Synthesis, Structures and Catalytic Transfer Hydrogenation of Ketones”. Duzce University Journal of Science and Technology 7/2 (March 1, 2019): 63-72. https://doi.org/10.29130/dubited.473988.

JAMA

1.Buldurun K, Özdemir İ. Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. DUBİTED. 2019;7:63–72.

MLA

Buldurun, Kenan, and İsmail Özdemir. “Ruthenium(II) Half-Sandwich Complexes Containing N-Substituted 5-Nitrobenzimidazole: Synthesis, Structures and Catalytic Transfer Hydrogenation of Ketones”. Duzce University Journal of Science and Technology, vol. 7, no. 2, Mar. 2019, pp. 63-72, doi:10.29130/dubited.473988.

Vancouver

1.Kenan Buldurun, İsmail Özdemir. Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. DUBİTED. 2019 Mar. 1;7(2):63-72. doi:10.29130/dubited.473988

Cited By

New Ruthenium-p-Cymene Complexes Containing o-Vanillin and 4-Benzoxybenzaldehyde Schiff Base Ligands; Synthesis, Characterization and Catalytic Activity in the Transfer Hydrogenation of Ketones

Catalysis Letters

https://doi.org/10.1007/s10562-023-04286-2