Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri

Gökhan Uzun

doi:10.29130/dubited.682151

Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri

Abstract

Hekzagonal bor nitrür (hBN) numuneleri, 1373 K'de farklı metal karboniller, M (CO)6, (M = Mo, Cr, W) ile modifiye edilmiş O’Connor yöntemi kullanılarak hazırlandı. Numuneler FTIR, XRD ve SEM teknikleri ile karakterize edildi. XRD sonuçları, katmanlar arası aralıkta bir artış olduğunu gösterdi ve 1373 K'de nano ölçekli ürünlerin oluşumu gözlendi. Hesaplanan kafes değerleri hBN için bildirilen değere çok yakındı ve Debye-Scherrer denklemine göre ürünlerin tane büyüklüğünün nano ölçekte olduğu bulundu.

Keywords

Hekzagonal bor nitrür, Nanokristaller, O’Connor metot, Metal karboniller

References

[1] Arya S.P.S, D'Amico A, Preparation, Properties and Applications of Boron-Nitride Thin-Films, Thin Solid Films, vol. 157, no. 2, pp. 267-288, 1988.
[2] Economy J, Anderson R, A New Route to Boron Nitride, Inorg. Chem., vol. 5 no. 6, pp. 989-992, 1966.
[3] K. A. Schwetz, Boron Carbide, Boron Nitride, and Metal Borides, Ullmann’s Encyclopedia of Industrial Chemistry Book, 15-Jun-2000.
[4] ¬ Hagio T, Nonaka K , Sato T., Microstructural Development with Crystallization of Hexagonal Boron Nitride, J. Mater. Sci. Lett., vol. 16, no. 10, pp. 795- 798, 1997.
[5] O’Connor T.E, Synthesis of Boron Nitride, J. Am. Chem. Soc., vol. 84, no. 9, pp. 1753- 1754 1962.
[6] Budak E, Bozkurt Ç, The Effect of Transition Metals on the Structure of h-BN Intercalation Compounds, J.Solid State Chem., vol. 177, no. 4-5, pp. 1768-1770, 2004.
[7] Budak, E, Bozkurt Ç, Synthesis of Hexagonal Boron Nitride with the Presence of Representative Metals, Physica B, vol. 405, no. 22, pp. 4702-4705, 2010.
[8] Aydoğdu A, Sevinç N, Carbothermic Formation of Boron Nitride, J. Eur Ceram Soc., vol. 23, no. 16, pp. 3153-3161, 2003.
[9] Hubacek M, Sato T, Ishii T, A Coexistence of Boron Nitride and Boric Oxide, J Solid State Chem., vol. 109, no. 2, pp. 384-390, 1994.
[10] J. Q. Hu et al., Synthesis and Characterization of Nanocrystalline Boron Nitride, J. Solid State Chem., vol. 148, no. 2, 325-328, 1999.

[11] Chen LY, Gu YL, Li ZF, Qian YT, Yang ZH, Ma JH, Low-Temperature Synthesis and Benzene-Thermal Growth of Nanocrystalline Boron Nitride, J. Cryst. Growth, vol. 273, no. 3, pp. 646-650 2005.
[12] Chen L.Y, Huang M.X, Luo T, Gu Y.L, Shi L, Yang Z.H, Qian Y.T, A Low-Temperature Route to Nanocrystalline Boron Nitride Whiskers and Flakes, Mater Lett., vol. 58, no. 27-28, pp. 3634-3636, 2004.
[13] Hubacek M, Ueki M, Chemical Reactions in Hexagonal Boron Nitride System. J Solid State Chem, vol. 123, no. 2, pp. 215-222, 1996.
[14] Yuan S.D, Zhu L.H, Fan M.X, Wang X.B, Wan D.J, Peng S.X, Tang H.Q: Fluffy-Like Boron Nitride Spheres Synthesized by Epitaxial Growth. Mater. Chem. Phys vol. 112, no. 3 pp. 912-915, 2008.
[15] Zheng M.T, Gu Y.L, Xu Z.L, Liu Y.L, Synthesis and Characterization of Boron Nitride Nanoropes, Mater Lett, 61, no. 8-9, pp. 1943-1945, 2007.
[16] Dibandjo P, Bois L, Chassagneux F, Miele P, Thermal Stability of Mesoporous Boron Nitride Templated with a Cationic Surfactant, J. Eur. Ceram. Soc., vol. 27, no. 1, pp. 313-317, 2007.
[17] Choi J.Y, Kang S.J.L, Fukunaga O, Park J.K, Eun K.Y, Effect of B2O3 and HBN Crystallinity on CBN Synthesis, J Am Ceram Soc., vol. 76, no. 10, pp. 2525-2528, 1993.
[18] Shi L, Gu Y.L, Chen L.Y, Qian Y.T, Yang Z.H, Ma J.H, Synthesis and Morphology Control of Nanocrystalline Boron Nitride, J Solid State Chemistry, vol. 177, no.3 pp. 721-724, 2004.
[19] Shi L, Gu Y.L, Chen L.Y, Yang Z.H, Ma J.H, Qian Y.T, Formation of Nanocrystalline BN With a Simple Chemical Route, Materials Letter, vol. 58, no.26, pp. 3301-3303, 2004.
[20] Zhou G.W, Zhang Z, Bai Z.G, Yu D.P, Catalyst Effects on Formation of Boron Nitride Nano-Tubules Synthesized by Laser Ablation, Solid State Community, vol. 109, no. 8, pp. 555-559 1999.
[21] Warner T.E, Fray D.J, Nitriding of Iron Boride to Hexagonal Boron Nitride. J. Mater. Science, vol. 35, no. 21, pp. 5341-5345 2000.
[22] Kurooka S, Ikeda T, Kohama K, Tanaka T, Tanaka A, Formation and Characterization of BN Films with Ti Added, Surface and Coating Technolology, vol. 166, no 2-3, pp. 111-116, 2003.
[23] Hao X, Yu M, Cui D, Xu X, Wang Q, Jiang M, The Effect of Temperature on the Synthesis of BN Nanocrystals, J. Crystal Growth, vol. 241, no. 1, pp. 124-128, 2002.
[24] Shuvaev A.T, Helmer B.Y, Kraizman V.L, Lyubesnova T.A, Mirmilstein A.S, Kvacheva L.D, Novikov Y.N, Volpin M.E, Graphite Intercalation Compounds with 3D-Transition Metals, Graphite-Metal Interaction, Physica B, vol. 158, no. 1-3, pp. 539-542, 1989.

Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Gökhan Uzun ^*
0000-0001-9425-0446
Türkiye

Publication Date

April 25, 2021

Submission Date

January 30, 2020

Acceptance Date

December 29, 2020

Published in Issue

Year 2021 Volume: 9 Number: 2

DOI

https://doi.org/10.29130/dubited.682151

IZ

https://izlik.org/JA72HL65NA

APA

Uzun, G. (2021). Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri. Duzce University Journal of Science and Technology, 9(2), 672-678. https://doi.org/10.29130/dubited.682151

AMA

1.Uzun G. Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri. DUBİTED. 2021;9(2):672-678. doi:10.29130/dubited.682151

Chicago

Uzun, Gökhan. 2021. “Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri”. Duzce University Journal of Science and Technology 9 (2): 672-78. https://doi.org/10.29130/dubited.682151.

EndNote

Uzun G (April 1, 2021) Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri. Duzce University Journal of Science and Technology 9 2 672–678.

IEEE

[1]G. Uzun, “Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri”, DUBİTED, vol. 9, no. 2, pp. 672–678, Apr. 2021, doi: 10.29130/dubited.682151.

ISNAD

Uzun, Gökhan. “Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri”. Duzce University Journal of Science and Technology 9/2 (April 1, 2021): 672-678. https://doi.org/10.29130/dubited.682151.

JAMA

1.Uzun G. Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri. DUBİTED. 2021;9:672–678.

MLA

Uzun, Gökhan. “Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri”. Duzce University Journal of Science and Technology, vol. 9, no. 2, Apr. 2021, pp. 672-8, doi:10.29130/dubited.682151.

Vancouver

1.Gökhan Uzun. Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri. DUBİTED. 2021 Apr. 1;9(2):672-8. doi:10.29130/dubited.682151

Metal Karbonillerin Hekzagonal Bor Nitrür Sentezi Üzerindeki Etkileri

Abstract

Keywords

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

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