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The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals

Yıl 2019, Cilt 2 (Ek sayı 1), 97 - 101, 27.12.2019

Öz

Hydrogen gas (H2(g))
production is one of the major topic of the industry and energy production
fields, for the last decades. Especially it is popular with showing high energy
density. Among the other industrial methods electrolysis is the cleanest one
without any by product emissions. It has been very popular to recovery of the
discarded materials (such as batteries) as an environmentally friendly
equipments. Here the coal of a used up battery is utilized as an electrode in
the electrolysis system in order to produce (H2(g)). Then these
electrodes were modified with impregnation of Zr and Ce metals. At first, HNO3
(aq) and
H2SO4
(aq)
solutions were compared as electrolytes with plain electrodes and H2SO4
(aq) is
defined as the optimum electrolyte medium (maximum H2(g) production
densities as 24.10xE-5 mL sec-1 and 87.22xE-5
mL sec-1,charge densities as 1137.40xE-4 C sec-1
and 2976.19xE-4 C sec-1 and current densities as 45.68xE-7
i sec-1 and 165.34xE-7 i sec-1 for 0.10 M HNO3
(aq) and
H2SO4
(aq)
solutions respectively). Then all of these modified electrodes were utilized to
the electrolysis system and compared in the case of H2(g) production
yield, charge and current density values. The best performances were obtained
from Ce modified electrode (maximum H2 (g) production density as
125.00xE-5 mL sec -1, charge density as 4265.24xE-4
C sec-1 and current density as 236.96xE-7 i sec-1  in 0.10 M of H2SO4
(aq)
electrolyte). Hydrogen is one of the most promising, clean and sustainable
energy carrier, that can be produced effectively by the usage of Ce modified
battery coal.

Teşekkür

Prof.Dr. M. Hamdi KARAOGLU is greatly acknowledged for their very valuable scientific mentorship.

Kaynakça

  • Demir E, Akbayrak S, Önal AM, Özkar S 2018. Titania, zirconia and hafnia supported ruthenium(0) nanoparticles: Highly active hydrogen evolution catalysts. J Colloid Interf Sci 531: 570-577.
  • Ghodsi FE, Tepehan FZ, Tepehan GG 2011. Derivation of the optical constants of spin coated CeO2–TiO2–ZrO2 thin films prepared by sol–gel route. J Phys Chem Solids 72: 761–767.
  • Kadier A, Simayi Y, Abdeshahian P, Azman NF, Chandrasekhar K, Kalil S 2016. A comprehensive review of microbial electrolysis cells (MEC) reactor designs and configurations for sustainable hydrogen gas production. Alexandria Eng J 55: 427–443.
  • Kaseem M, Ko YG 2018. A novel composite system composed of zirconia and LDHs film grown on plasma electrolysis coating: Toward a stable smart coating. Ultrason Sonochem 49: 316-324.
  • Kumar SS, Ramakrishna SUB, Reddy DS, Bhagawan D, Himabindu V 2017. Synthesis of Polysulfone and zirconium oxide coated asbestos composite separators for alkaline water electrolysis. Int J Chemical Eng & Process Tech 3: 1035/1-6.
  • Lee B, Chae H, Choi NH, Moon C, Moon S, Lim H 2017. Economic evaluation with sensitivity and profitability analysis for hydrogen production from water electrolysis in Korea. Int J Hydrogen Energy 42: 6462–6471.
  • Lei Q, Wang B, Wang P, Liu S 2019. Hydrogen generation with acid/alkaline amphoteric water electrolysis. J Energy Chem 38: 162-169.
  • Lim H 2015. Hydrogen selectivity and permeance effect on the water gas shift reaction (WGSR) in a membrane reactor. Korean J Chem Eng 32: 1522–1527.
  • Mujeebu MA 2016. Hydrogen and syngas production by superadiabatic combustion-A review. Appl Energy 173: 210-224.
  • Ni M, Leung MKH, Leung DYC 2008. Technological development of hydrogen production by solid oxide electrolyzer cell (SOEC). Int J Hydrogen Energy 33: 2337–2354.
  • Polliotto V, Albanese E, Livraghi S, Agnoli S, Pacchioni G, Giamello E 2018. Structural, electronic and photochemical properties of cerium-doped zirconium titanate. Catal Today (In press, corrected proof, Available online 14 October 2018)
  • Rathinam NK, Sani RK, Salem D, Rewiring Extremophilic Electrocatalytic Processes for Production of Biofuels and Value-Added Compounds from Lignocellulosic Biomass. In: R. Sani, N. Krishnaraj Rathinam (eds), Extremophilic Microbial Processing of Lignocellulosic Feedstocks to Biofuels, Value-Added Products, and Usable Power. Springer, Cham. 2018, pp. 229-245.
  • Sapountzi MF, Gracia MJ, Weststrate CJKJ, Hans OA, Niemantsverdriet, JWH 2017. Electrocatalysts for the generation of hydrogen, oxygen and synthesis gas. Prog Energy Combust Sci 58: 1–35.
  • Seyitoglu SS, Dincer I, Kilicarslan A 2017. Energy and exergy analyses of hydrogen production by coal gasification. Int J Hydrogen Energy 42: 2592–600.Sivagurunathan P, Kumar G, Kim SH, Kobayashi T, Xu KQ, Guo W 2016. Enhancement strategies for hydrogen production from wastewater: a review. Curr Org Chem 20: 2744-2752.
  • Wang J, Wang T, Yu L, Wei T, Hu X, Ye Z, Wang Z, Buckley CE, Yao J, Marnellos GE, Dong D 2019. Catalytic CeO2 washcoat over microchanneled supporting cathodes of solid oxide electrolysis cells for efficient and stable CO2 reduction. J Power Sources 412: 344-349.
  • Zeng K, Zhang D 2010. Recent progress in alkaline water electrolysis for hydrogen production and applications. Prog Energy Combust Sci 36: 307–26.
  • Züttel A 2004. Hydrogen storage methods. Naturwissenschaften 91: 157–172.
Yıl 2019, Cilt 2 (Ek sayı 1), 97 - 101, 27.12.2019

Öz

Kaynakça

  • Demir E, Akbayrak S, Önal AM, Özkar S 2018. Titania, zirconia and hafnia supported ruthenium(0) nanoparticles: Highly active hydrogen evolution catalysts. J Colloid Interf Sci 531: 570-577.
  • Ghodsi FE, Tepehan FZ, Tepehan GG 2011. Derivation of the optical constants of spin coated CeO2–TiO2–ZrO2 thin films prepared by sol–gel route. J Phys Chem Solids 72: 761–767.
  • Kadier A, Simayi Y, Abdeshahian P, Azman NF, Chandrasekhar K, Kalil S 2016. A comprehensive review of microbial electrolysis cells (MEC) reactor designs and configurations for sustainable hydrogen gas production. Alexandria Eng J 55: 427–443.
  • Kaseem M, Ko YG 2018. A novel composite system composed of zirconia and LDHs film grown on plasma electrolysis coating: Toward a stable smart coating. Ultrason Sonochem 49: 316-324.
  • Kumar SS, Ramakrishna SUB, Reddy DS, Bhagawan D, Himabindu V 2017. Synthesis of Polysulfone and zirconium oxide coated asbestos composite separators for alkaline water electrolysis. Int J Chemical Eng & Process Tech 3: 1035/1-6.
  • Lee B, Chae H, Choi NH, Moon C, Moon S, Lim H 2017. Economic evaluation with sensitivity and profitability analysis for hydrogen production from water electrolysis in Korea. Int J Hydrogen Energy 42: 6462–6471.
  • Lei Q, Wang B, Wang P, Liu S 2019. Hydrogen generation with acid/alkaline amphoteric water electrolysis. J Energy Chem 38: 162-169.
  • Lim H 2015. Hydrogen selectivity and permeance effect on the water gas shift reaction (WGSR) in a membrane reactor. Korean J Chem Eng 32: 1522–1527.
  • Mujeebu MA 2016. Hydrogen and syngas production by superadiabatic combustion-A review. Appl Energy 173: 210-224.
  • Ni M, Leung MKH, Leung DYC 2008. Technological development of hydrogen production by solid oxide electrolyzer cell (SOEC). Int J Hydrogen Energy 33: 2337–2354.
  • Polliotto V, Albanese E, Livraghi S, Agnoli S, Pacchioni G, Giamello E 2018. Structural, electronic and photochemical properties of cerium-doped zirconium titanate. Catal Today (In press, corrected proof, Available online 14 October 2018)
  • Rathinam NK, Sani RK, Salem D, Rewiring Extremophilic Electrocatalytic Processes for Production of Biofuels and Value-Added Compounds from Lignocellulosic Biomass. In: R. Sani, N. Krishnaraj Rathinam (eds), Extremophilic Microbial Processing of Lignocellulosic Feedstocks to Biofuels, Value-Added Products, and Usable Power. Springer, Cham. 2018, pp. 229-245.
  • Sapountzi MF, Gracia MJ, Weststrate CJKJ, Hans OA, Niemantsverdriet, JWH 2017. Electrocatalysts for the generation of hydrogen, oxygen and synthesis gas. Prog Energy Combust Sci 58: 1–35.
  • Seyitoglu SS, Dincer I, Kilicarslan A 2017. Energy and exergy analyses of hydrogen production by coal gasification. Int J Hydrogen Energy 42: 2592–600.Sivagurunathan P, Kumar G, Kim SH, Kobayashi T, Xu KQ, Guo W 2016. Enhancement strategies for hydrogen production from wastewater: a review. Curr Org Chem 20: 2744-2752.
  • Wang J, Wang T, Yu L, Wei T, Hu X, Ye Z, Wang Z, Buckley CE, Yao J, Marnellos GE, Dong D 2019. Catalytic CeO2 washcoat over microchanneled supporting cathodes of solid oxide electrolysis cells for efficient and stable CO2 reduction. J Power Sources 412: 344-349.
  • Zeng K, Zhang D 2010. Recent progress in alkaline water electrolysis for hydrogen production and applications. Prog Energy Combust Sci 36: 307–26.
  • Züttel A 2004. Hydrogen storage methods. Naturwissenschaften 91: 157–172.
Toplam 17 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Sema Aslan 0000-0001-9796-7311

Yayımlanma Tarihi 27 Aralık 2019
Kabul Tarihi 18 Kasım 2019
Yayımlandığı Sayı Yıl 2019 Cilt 2 (Ek sayı 1)

Kaynak Göster

APA Aslan, S. (2019). The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals. Eurasian Journal of Biological and Chemical Sciences, 2, 97-101.
AMA Aslan S. The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals. Eurasian J. Bio. Chem. Sci. Aralık 2019;2:97-101.
Chicago Aslan, Sema. “The Usage of Discarded Battery Coals As Electrodes and Improving Their Hydrogen Gas Production Performances by Impregnation With Zr and Ce Metals”. Eurasian Journal of Biological and Chemical Sciences 2, Aralık (Aralık 2019): 97-101.
EndNote Aslan S (01 Aralık 2019) The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals. Eurasian Journal of Biological and Chemical Sciences 2 97–101.
IEEE S. Aslan, “The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals”, Eurasian J. Bio. Chem. Sci., c. 2, ss. 97–101, 2019.
ISNAD Aslan, Sema. “The Usage of Discarded Battery Coals As Electrodes and Improving Their Hydrogen Gas Production Performances by Impregnation With Zr and Ce Metals”. Eurasian Journal of Biological and Chemical Sciences 2 (Aralık 2019), 97-101.
JAMA Aslan S. The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals. Eurasian J. Bio. Chem. Sci. 2019;2:97–101.
MLA Aslan, Sema. “The Usage of Discarded Battery Coals As Electrodes and Improving Their Hydrogen Gas Production Performances by Impregnation With Zr and Ce Metals”. Eurasian Journal of Biological and Chemical Sciences, c. 2, 2019, ss. 97-101.
Vancouver Aslan S. The usage of discarded battery coals as electrodes and improving their hydrogen gas production performances by impregnation with Zr and Ce metals. Eurasian J. Bio. Chem. Sci. 2019;2:97-101.