Research Article

An autonomous hydrogen production system design based on the solid chemical hydride

Volume: 6 Number: 4 December 20, 2022
EN

An autonomous hydrogen production system design based on the solid chemical hydride

Abstract

This paper develops a hydrogen generator prototype that is for fuel cell systems used in portable applications. This generator is designed based on the use of solid-state hydrides with high hydrogen storage capacity in the catalytic hydrolysis reaction. Some using problems such as unstable hydrogen production, one-off service life, heavy or large-volume storage system, and short duty time can be avoided in moveable applications when the use of the produced prototype. In addition, A simulation model and an autonomous control algorithm, which evaluates the hydrogen generation and temperature responses of the prototype, are developed. The results confirm that the performance of a portable and autonomous prototype with 4 parts and 1-hour hydrogen production capacity is enough for small fuel cell applications.

Keywords

References

  1. [1] Hansu, T.A., Caglar, A., Sahin, O., Kivrak, H., (2020). Hydrolysis and electrooxidation of sodium borohydride on novel CNT supported CoBi fuel cell catalyst. Materials Chemistry and Physics. doi: 10.1016/j.matchemphys.2019.122031.
  2. [2] Barbir, F., Gorgun, H., & Wang, X. (2005). Relationship between pressure drop and cell resistance as a diagnostic tool for PEM fuel cells. Journal of Power Sources, 141(1), 96-101.
  3. [3] Sahiner, N., Demirci, S., (2017). Very fast H2 production from the methanolysis of NaBH4 by metal-free poly(ethylene imine) microgel catalysts. International Journal of Energy Research. doi: 10.1002/er.3679.
  4. [4] Abdalla, A.M., Hossain, S., Nisfindy, O.B., Azad, A.T., Dawood, M., Azad, A.K., (2018). Hydrogen production, storage, transportation and key challenges with applications: A review. Energy Conversion and Management. doi: 10.1016/j.enconman.2018.03.088.
  5. [5] Rivarolo, M., Improta, O., Magistri, L., Panizza, M., Barbucci, A., (2018). Thermo-economic analysis of a hydrogen production system by sodium borohydride (NaBH4). International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2017.11.079.
  6. [6] Balbay, A., Saka, C., (2018). Effect of phosphoric acid addition on the hydrogen production from hydrolysis of NaBH4 with Cu based catalyst. Energy Sources, Part A: Recovery, Utilization and Environmental Effects. doi: 10.1080/15567036.2018.1463311.
  7. [7] Schlesinger, H.I., Brown, H.C., Finholt, A.E., Gilbreath, J.R., Hoekstra, H.R., Hyde, E.K., (1953). Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen. Journal of the American Chemical Society. doi: 10.1021/ja01097a057.
  8. [8] Zhang, J., Zheng, Y., Gore, J.P., Fisher, T.S., (2007). 1 kWe sodium borohydride hydrogen generation system. Part I: Experimental study. Journal of Power Sources. doi: 10.1016/j.jpowsour.2006.12.055.

Details

Primary Language

English

Subjects

Mechanical Engineering

Journal Section

Research Article

Publication Date

December 20, 2022

Submission Date

January 12, 2022

Acceptance Date

March 4, 2022

Published in Issue

Year 2022 Volume: 6 Number: 4

APA
İskenderoğlu, F. C., Baltacıoğlu, K., Conker, Ç., & Bilgiç, H. H. (2022). An autonomous hydrogen production system design based on the solid chemical hydride. European Mechanical Science, 6(4), 213-220. https://doi.org/10.26701/ems.1056942

Cited By


Dergi TR Dizin'de Taranmaktadır.

Flag Counter