Adsorption of Basic Blue 41 using Juniperus excelsa: Isotherm, kinetics and thermodynamics studies

Year 2019, Volume: 2 Issue: 3, 112 - 121, 30.09.2019

Ali Rıza Kul , Adnan Aldemir , Salih Alkan Hasan Elik , Meliha Çalışkan

https://doi.org/10.35208/ert.568992

Cited By: 12

https://izlik.org/JA77HR66UJ

Abstract

In this study Juniperus excelsa shavings powder (JESP)
was utilized as an adsorbent for the removal of Basic Blue 41 (BB 41) which is
one of the common basic dyes, from aqueous solution. The adsorption experiments
were carried out in a batch system and effects of initial concentration of dye,
interaction time and temperature were investigated. Langmuir, Freundlich and
Temkin adsorption isotherms were used to model equilibrium data. According to
the results, Freundlich isotherm model becomes more convenient option compared
with Langmuir and Temkin models. Freundlich model coefficients are raise as the
temperature rises, showing that the adsorption process becomes favorable higher
temperature. The kinetic parameters were determined by pseudo first order
(PFO), pseudo second order (PSO) and intra-particle diffusion (IPD) models.
Results indicated that experimental and calculated qe values are matched to
each other. Thus the process fits PSO kinetic model with higher R²
values than other two models. Kinetic constants become closer to both temperatures
and initial concentrations and qe values are increases with increasing
concentration of BB 41. Initial dye concentration elevates from 25 to 100 mg L^-1,
dye adsorption capacity onto JESP from 3.06 to 16.53 mg g^-1,
respectively. Thermodynamic parameters for instance free energy (ΔG), enthalpy (ΔH) and entropy (ΔS) were
assessed. Enthalpy and entropy of this separation process are determined from
3081.91 J mol^-1 and 12.33 kJ mol^-1, respectively. The
negative values of ΔG° showed that
this separation process was endothermic and natural. The research results
demonstrate that JESP may be a substitute than pricey adsorbents for dye
removal.

Keywords

Basic Blue 41 , dye adsorption , Juniperus excelsa , isotherm models , kinetic and thermodynamic parameters

References

• 1. Ciesielczyk, F., et al., Active MgO-SiO2 hybrid material for organic dye removal: A mechanism and interaction study of the adsorption of C.I. Acid Blue 29 and C.I. Basic Blue 9. J Environ Manage, 2017. 204(Pt 1): p. 123-135.
• 2. Mehrizi, M.Z. and A. Badiei, Highly efficient removal of basic blue 41 with nanoporous silica. Water Resources and Industry, 2014. 5: p. 49-57.
• 3. Humelnicua, I., et al., The removal of Basic Blue 41 textile dye from aqueous solution by adsorption onto natural zeolitic tuff: Kinetics and thermodynamics. Process Safety and Environmental Protection, 2017. 105: p. 274-287.
• 4. Wawrzkiewicz, M., Removal of C.I. Basic Blue 3 dye by sorption onto cation exchange resin functionalized and non-functionalized polymeric sorbents from aqueous solutions and wastewaters. Chemical Engineering Journal, 2013. 217: p. 414-425.
• 5. Laysandra, L., et al., Adsorption and photocatalytic performance of bentonite-titanium dioxide composites for methylene blue and rhodamine B decoloration. Heliyon, 2017. 3(12): p. e00488.
• 6. Regti, A., et al., Removal of Basic Blue 41 dyes using Persea americana-activated carbon prepared by phosphoric acid action. Int J Ind Chem, 2017. 8: p. 187-195.
• 7. Luo, H., et al., Adsorption behavior and mechanism of acidic blue 25 dye onto cucurbit[8]uril: A spectral and DFT study. Spectrochim Acta A Mol Biomol Spectrosc, 2018. 193: p. 125-132.
• 8. Jin, Y., et al., Efficient adsorption of methylene blue and lead ions in aqueous solutions by 5-sulfosalicylic acid modified lignin. Int J Biol Macromol, 2018. 123: p. 50-58.
• 9. Hasan, R., et al., Process optimization of methylene blue adsorption onto eggshell–treated palm oil fuel ash. Environmental Technology & Innovation, 2019. 13: p. 62-73.
• 10. Ali, I. and V.K. Gupta, Advances in water treatment by adsorption technology. Nat. Protoc, 2006. 1: p. 2661-2667.
• 11. Daneshvar, E., et al., Shrimp shell as an efficient bioadsorbent for Acid Blue 25 dye removal from aqueous solution. Journal of the Taiwan Institute of Chemical Engineers, 2014. 45: p. 2926-2934.
• 12. Sankhadeep Basu, Gourab Ghosh, and S. Saha, Adsorption characteristics of phosphoric acid induced activation of bio-carbon: Equilibrium, kinetics, thermodynamics and batch adsorber design. Process Safety and Environmental Protection, 2018. 117: p. 125-142.
• 13. Basas-Jaumandreu, J., et al., Labdane-type diterpenoids from Juniperus communis needles. Industrial Crops and Products, 2015. 76: p. 333-345.
• 14. Yaglioglu, A.S. and F. Eser, Screening of some Juniperus extracts for the phenolic compounds and their antiproliferative activities. South African Journal of Botany, 2017. 113: p. 29-33.
• 15. Laura Bulgariu, et al., The utilization of leaf-based adsorbents for dyes removal: A review. Journal of Molecular Liquids, 2019. 276: p. 728-747.
• 16. Y.Jiang, et al., Equilibrium and kinetic studies of C.I. Basic Blue 41 adsorption onto N, F-codoped flower-like TiO2 microspheres. Applied Surface Science, 2013. 273(273): p. 448-456.
• 17. Yagub, M.T., et al., Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interface Sci, 2014. 209: p. 172-84.
• 18. Afshin, S., et al., Data of adsorption of Basic Blue 41 dye from aqueous solutions by activated carbon prepared from filamentous algae. Data Brief, 2018. 21: p. 1008-1013.
• 19. Sumanjit, S. Rani, and R.K. Mahajan, Equilibrium, kinetics and thermodynamic parameters for adsorptive removal of dye Basic Blue 9 by ground nut shells and Eichhornia. Arabian Journal of Chemistry, 2016. 9: p. 1464-1477.
• 20. Crini, G., et al., The removal of Basic Blue 3 from aqueous solutions by chitosan-based adsorbent: batch studies. J Hazard Mater, 2008. 153(1-2): p. 96-106.
• 21. Tahir, S.S. and N. Rauf, Removal of a cationic dye from aqueous solutions by adsorption onto bentonite clay. Chemosphere, 2006. 63(11): p. 1842-8.
• 22. Siew-Ling Chan, et al., Equilibrium, kinetic and thermodynamic studies of a new potential biosorbent for the removal of Basic Blue 3 and Congo Red dyes: Pineapple ( Ananas comosus ) plant stem. Journal of the Taiwan Institute of Chemical Engineers, 2016. 61: p. 306-315.