Araştırma Makalesi
BibTex RIS Kaynak Göster
Yıl 2020, Cilt: 21 Sayı: 3, 389 - 395, 30.09.2020
https://doi.org/10.18038/estubtda.675206

Öz

Kaynakça

  • [1] Khanjani J, Hanifpour A, Pazokifard S, Zohuriaan-Mehr MJ. Waterborne acrylic-styrene/PDMS coatings formulated by different particle sizes of PDMS emulsions for outdoor applications. Prog Org Coat 2020;105267.
  • [2] Guo S, Wang D, Shi J, Li X, Feng B, Meng L, Cai Z, Qiu H, Wei S. Study on waterborne acrylate coatings modified with biomass silicon. Prog Org Coat 2019; 135: 601-607.
  • [3] Schindler F. Properties distinguishing acrylic polymers as binders for basecoats on leather. J Am Leather Chem Assoc 2003; 98: 97-100.
  • [4] Greif M, Cala JA. Polymer characteristics and composition and leather finish properties. J Am Leather Chem Assoc 1972; 67: 480-487.
  • [5] Krings L, Jimenez M, Oliveras M, Pont Pi JM. Acrylic-urethane hybrid polymers: materials with high potential in leather finishing. J Am Leather Chem Assoc 2010; 105: 388-394.
  • [6] Huang Y, Jones FN. Synthesis of crosslinkable acrylic latexes by emulsion polymerization in the presence of etherified melamine-formaldehyde (MF) resins. Prog Org Coat 1996; 28: 133–141.
  • [7] Hegedus CR, Kloiber KA. Aqueous acrylic-polyurethane hybrid dispersions and their use in industrial coatings. J Coatings Technol 1996; 68: 39–48.
  • [8] Brown W. Aromatic polycarbodiimides - a new class of cross-linkers for water-borne coatings. Surf Coat Int 1995; 78: 238–242.
  • [9] Williams A, Ibrahim IT. Carbodiimide chemistry: Recent advances. Chem Rev 1981; 81: 589–636.
  • [10] Roesler RR, Danielmeier K. Tris-3-(1-aziridino)propionates and their use in formulated products. Prog Org Coat 2004; 50: 1–27.
  • [11] Moore G, Zhu DW. Waterborne cross-linkable fluorochemical coatings, Surf Coat Int 1995; 78: 377.
  • [12] Wu S, Soucek MD. Crosslinking of acrylic latex coatings with cycloaliphatic diepoxide. Polymer (Guildf) 2000; 41: 2017–2028.
  • [13] Polloni AE, Valério A, Oliveira D, Araújo PHH, Sayer C. Ultrasound assisted miniemulsion polymerization to prepare poly(urea-urethane) nanoparticles. Polímeros 2018; 28(2): 155-160.
  • [14] Jansen TGT, Meuldijk J, Lovell PA, van Herk A. On the miniemulsion polymerization of very hydrophobic monomers initiated by a completely water-insoluble initiator: Thermodynamics, kinetics and mechanism. J Polym Sci Pol Chem 2016; 54(17): 2731-2745.
  • [15] Leather - Physical and mechanical tests- Sample preparation and conditioning, ISO 2419:2012 (IULTCS/IUP 1, IULTCS/IUP 3).
  • [16] Leather - Determination of flex resistance - Part 1: Flexometer method, ISO 5402-1:2011 (IULTCS/IUP 20-1).
  • [17] Leather - Tests for colour fastness - Colour fastness to cycles of to-and-fro rubbing, ISO 11640:2012 (IULTCS/IUF 450).

ON THE PREPARATION OF POLYACRYLIC BINDER via MINI-EMULSION POLYMERIZATION FOR LEATHER PERFORMANCE COATINGS

Yıl 2020, Cilt: 21 Sayı: 3, 389 - 395, 30.09.2020
https://doi.org/10.18038/estubtda.675206

Öz

A partially crosslinked polyacrylic copolymer latex composed of butyl acrylate (BA), methyl methacrylate (MMA), methacrylic acid (MAA) and 1,4 butanediol dimethacrylate (BDMA) was synthesized via mini-emulsion polymerization technique. The obtained latex had good electrostatic stability with low average particle size (83 nm) and narrow size distributions (PDI= 0.12). The FTIR and DSC analysis verified the success of the copolymer’s synthesis. The latex was further used as a base coat binder for the coating of shoe upper leathers in a leather finishing application. The performed tests on finished leather showed good dry/wet rubbing performance of the coating as well as excellent flexing endurance. The synthesized latex seemed to be a good candidate as performance binder for leather finishing applications.

Kaynakça

  • [1] Khanjani J, Hanifpour A, Pazokifard S, Zohuriaan-Mehr MJ. Waterborne acrylic-styrene/PDMS coatings formulated by different particle sizes of PDMS emulsions for outdoor applications. Prog Org Coat 2020;105267.
  • [2] Guo S, Wang D, Shi J, Li X, Feng B, Meng L, Cai Z, Qiu H, Wei S. Study on waterborne acrylate coatings modified with biomass silicon. Prog Org Coat 2019; 135: 601-607.
  • [3] Schindler F. Properties distinguishing acrylic polymers as binders for basecoats on leather. J Am Leather Chem Assoc 2003; 98: 97-100.
  • [4] Greif M, Cala JA. Polymer characteristics and composition and leather finish properties. J Am Leather Chem Assoc 1972; 67: 480-487.
  • [5] Krings L, Jimenez M, Oliveras M, Pont Pi JM. Acrylic-urethane hybrid polymers: materials with high potential in leather finishing. J Am Leather Chem Assoc 2010; 105: 388-394.
  • [6] Huang Y, Jones FN. Synthesis of crosslinkable acrylic latexes by emulsion polymerization in the presence of etherified melamine-formaldehyde (MF) resins. Prog Org Coat 1996; 28: 133–141.
  • [7] Hegedus CR, Kloiber KA. Aqueous acrylic-polyurethane hybrid dispersions and their use in industrial coatings. J Coatings Technol 1996; 68: 39–48.
  • [8] Brown W. Aromatic polycarbodiimides - a new class of cross-linkers for water-borne coatings. Surf Coat Int 1995; 78: 238–242.
  • [9] Williams A, Ibrahim IT. Carbodiimide chemistry: Recent advances. Chem Rev 1981; 81: 589–636.
  • [10] Roesler RR, Danielmeier K. Tris-3-(1-aziridino)propionates and their use in formulated products. Prog Org Coat 2004; 50: 1–27.
  • [11] Moore G, Zhu DW. Waterborne cross-linkable fluorochemical coatings, Surf Coat Int 1995; 78: 377.
  • [12] Wu S, Soucek MD. Crosslinking of acrylic latex coatings with cycloaliphatic diepoxide. Polymer (Guildf) 2000; 41: 2017–2028.
  • [13] Polloni AE, Valério A, Oliveira D, Araújo PHH, Sayer C. Ultrasound assisted miniemulsion polymerization to prepare poly(urea-urethane) nanoparticles. Polímeros 2018; 28(2): 155-160.
  • [14] Jansen TGT, Meuldijk J, Lovell PA, van Herk A. On the miniemulsion polymerization of very hydrophobic monomers initiated by a completely water-insoluble initiator: Thermodynamics, kinetics and mechanism. J Polym Sci Pol Chem 2016; 54(17): 2731-2745.
  • [15] Leather - Physical and mechanical tests- Sample preparation and conditioning, ISO 2419:2012 (IULTCS/IUP 1, IULTCS/IUP 3).
  • [16] Leather - Determination of flex resistance - Part 1: Flexometer method, ISO 5402-1:2011 (IULTCS/IUP 20-1).
  • [17] Leather - Tests for colour fastness - Colour fastness to cycles of to-and-fro rubbing, ISO 11640:2012 (IULTCS/IUF 450).
Toplam 17 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Catalina Cheaburu 0000-0001-5229-8986

Onur Yilmaz 0000-0002-0992-5937

Yayımlanma Tarihi 30 Eylül 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 21 Sayı: 3

Kaynak Göster

AMA Cheaburu C, Yilmaz O. ON THE PREPARATION OF POLYACRYLIC BINDER via MINI-EMULSION POLYMERIZATION FOR LEATHER PERFORMANCE COATINGS. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering. Eylül 2020;21(3):389-395. doi:10.18038/estubtda.675206