Enhancing Fire Resistance of Scots Pine and Turkish Fir Woods: A Comparative Study of Firetex and Boric Acid Treatments
Year 2025,
Volume: 1 Issue: 1, 10 - 17, 31.07.2025
Osman Emre Özkan
,
Haci İsmail Kesik
,
Hakan Aydoğan
,
Elif Maraz
Abstract
Wood material is disadvantageous due to its flammable properties. Various fire-retardant chemical substances are used to eliminate this disadvantage. In this study, Scots pine (Pinus sylvestris L.) and Turkish fir (Abies nordmanniana subsp. bornmuelleriana) woods were impregnated with fire-retardant chemicals firetex and boric acid, and combustion experiments were carried out according to ASTM-E 69-02 standard. As a result, both mass loss and carbon monoxide (CO) emissions were significantly reduced in fire-retardant treated samples compared to untreated control samples. Among the treatments, Firetex showed the highest performance in increasing fire resistance by minimizing combustion-induced mass loss and toxic gas emission. The combination of Firetex with boric acid also showed effective results closely following Firetex alone, whereas boric acid alone provided moderate protection. In contrast, untreated control samples showed the most severe mass loss and highest gas emissions during combustion. These findings demonstrated that fire-retardant impregnation plays a significant role in improving the fire performance of wood materials in both tree species. Therefore, it is recommended to apply fire-retardant impregnation in wooden structures.
References
-
Abdul Rashid, A., Murphy, R., 1992: Pyrolysis and heat release of inorganic flame-retardants. Journal of Tropical Forest Science, 5(3), 322-336.
-
ASTM E 69-02, 2007: Standard Test Method for Combustible Properties of Treated Wood by the Fire-Tube Apparatus, ASTM International, West Conshohocken, PA.
-
Can, A., Özlüsoylu, A., Grzeskowıak, W., Sözen, E., 2017: Improvement of fire performance of impregnated wood with copper based chemicals. 28th International Conference on Wood Science and Technology.
-
Can, A., Özlüsoylu, A., Sözen, E., 2018: Investigation of Water Absorption, Decay Resistance and Bending Strength Properties of Firetex Added Cua and ACQ. 4th International Congress on Multidisciplinary Studies.
-
Grexa, O., Horváthová, E., Besinova, O. G., Lehocký, P., 1999: Flame retardant treated plywood. Polymer degradation and stability, 64(3), 529-533.
-
Holmes, C. A. Effect of fire-retardant treatments on performance properties of wood. ACS Symp. Ser, Washington, D.C., 82-106.
-
Kesik, H. İ., Aydoğan, H., Çağatay, K., Özkan, O. E., Maraz, E. 2015: Fire Properties of Scots Pine Impregnated with Firetex. ICOEST International Conference on Environmental Science and Technology, Sarajevo, BH.
-
Kesik, H. I., Aydoğan, H., Özkan, O. E., Maraz, E., 2016: Combustion properties of Turkish fir impregnated with Firetex. 2nd International Furniture Congress.
-
Kurt, Ş., Uysal, B., 2009: Combustion Properties of Oak (Quercus robur L.) Laminated Veneer Lumbers Bonded with PVAc, PF Adhesives and Impregnated with Some Fire-Retardants. Composite Interfaces, 16(2-3), 175-190.
-
Kurt, Ş., Uysal, B., 2010: Combustion properties of laminated veneer lumbers bonded with PVAc, PF adhesives and impregnated with some fire retardants. Fire and Materials, 34(3), 147-161.
-
LeVan, S. L., Winandy, J. E., 1990: Effects of fire retardant treatments on wood strength: a review. Wood and Fiber Science, 22(1), 113-131.
-
Özkan, O. E., Temiz, A., Tor, Ö., Vurdu, H., 2022: Effect of post-heat treatment on fire retardant treated wood properties. Holzforschung, 76(7), 645-657.
-
Özcan, C., Esen, R., Lıkos, E., Kurt, Ş., Yapıcı, F., 2012: The Effects of Fire Retardants Paint on Combustion Properties of Fir Wood. Kastamonu University Journal of Forestry Faculty, 12(3), 124-126.
-
Prockop, L. D., Chichkova, R. I., 2007: Carbon monoxide intoxication: an updated review. Journal of the neurological sciences, 262(1), 122-130.
-
Raub, J. A., Mathieu-Nolf, M., Hampson, N. B., Thom, S. R., 2000: Carbon monoxide poisoning—a public health perspective. Toxicology, 145(1), 1-14.
-
Sözen, E., Gündüz, G., Aydemir, D., Can, A., 2021: Surface Modification of Bacterial Cellulose Sheets with Various Fire Retardants. Journal of Thermal Science and Engineering Applications, 13(2), 021003.
-
Temiz, A., Gezer, E. D., Yildiz, U. C., Yildiz, S., 2008: Combustion properties of alder (Alnus glutinosa L.) and southern pine (Pinus sylvestris L.) wood treated with boron compounds. Construction and Building Materials, 22(11), 2165-2169.
-
Terzi, E., 2008: Fire properties of wood materials treated with amonia compounds, Master Thesis, Institue of Science, Istanbul University.
-
Tomak, E. D., and Cavdar, A. D. (2013). Limited oxygen index levels of impregnated Scots pine wood. Thermochimica Acta, 573, 181-185.
-
TS ISO 3129, 2021: Wood - Sampling Methods and General Requirements for Physical and Mechanical Tests, Turkish Standards Institution, Ankara.
-
Yapıcı, F., Uysal, B., Kurt, Ş., Esen, R., Özcan, C., 2011: Impacts of impregnation chemicals on finishing process and combustion properties of oriental beech (Fagus orientalis L.) wood. BioResources, 6(4).
-
White, R. H., Dietenberger, M. A., 2010: Fire safety of wood construction. General Technical Report, FPL-GTR-190, 18, 3.