Decolorization of Reactive Black 5 Using N-Doped TiO2
Year 2022,
, 360 - 370, 01.06.2022
Aslı Berktaş
,
Özlem Esen Kartal
Abstract
Decolorization of Reactive Black 5 (RB5) was investigated by heterogeneous photocatalysis using N-doped TiO2. N-doped TiO2 photocatalysts were synthesized by means of a sol-gel process. X-ray diffraction performed the characterization of synthesized samples, scanning electron microscopy and X-ray photoelectron spectroscopy measurements. Photocatalytic activity of N-doped TiO2 samples was assessed by following decolorization and degradation efficiency of RB5. N-TiO2(3) sample yielded the highest decolorization efficiency. The apparent first-order rate constants for decolorization of RB5 with N-TiO2(X) samples followed the order of N-TiO2(3) > N-TiO2(2) > N-TiO2(4) > N-TiO2(1). Improvement of decolorization efficiency of TiO2 was observed doping with nitrogen. The effect of actual sunlight on decolorization efficiency was also investigated. 96% and 49% of decolorization efficiency levels were attained within 60 minutes of reaction time with outdoor sunlight and fluorescent daylight lamps, respectively.
Supporting Institution
Scientific and Technological Research Council of Turkey
References
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Year 2022,
, 360 - 370, 01.06.2022
Aslı Berktaş
,
Özlem Esen Kartal
References
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- [2] Rodriguez-Narvaez, O.M., Peralta-Hernandez, J.M., Goonetilleke, A., Bandala, E.R., “Treatment technologies for emerging contaminants in water: A review”, Chemical Engineering Journal, 323: 361-380, (2017).
[3] Shahidi, D., Roy, R., Azzouz, A., “Advances in catalytic oxidation of organic pollutants – Prospects for thorough mineralization by natural clay catalysts”, Applied Catalysis B-Environmental, 174-175: 277-292, (2015).
- [4] Al-Mamun, M.R., Kader, S., Islam, M.S., Khan, M.Z.H., “Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: A review”, Journal of Environmental Chemical Engineering, 7: 103248, (2019).
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[8] Asahi, R., Morikawa, T., Ohwaki, T., Aoki, K., Taga, Y., “Visible-light photocatalysis in nitrogen-doped titanium oxides”, Science, 293: 269-271, (2001).
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[11] Ansari, S.A., Khan, M.M., Ansari, M. O., Cho, M.H., “Nitrogen-doped titanium dioxide (N-doped TiO2) for visible light photocatalysis”, New Journal of Chemistry, 40: 3000-3009, (2016).
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[15] Sullivan, J.J.A., Neville, E.M., Herron, R., Thampi, K. R., Mac Elroy, J.M.D., “Routes to visible light active C-doped TiO2 photocatalysts using carbon atoms from the Ti precursors”, Journal of Photochemistry and Photobiology A: Chemistry, 289: 60-65, (2014).
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[18] Bilinska, L., Gmurek, M., Ledakowicz, S., “Comparison between industrial and simulated textile wastewater treatment by AOPs – Biodegradability, toxicity and cost assessment”, Chemical Engineering Journal, 306: 550-559, (2016).
- [19] Ambigadevi, J., Kumar, S.P., Vo, D.V. N., Haran, S.H., Raghavan, T.N.S., “Recent developments in photocatalytic remediation of textile effluent using semiconductor based nanostructured catalyst: A review”, Journal of Environmental Chemical Engineering, 9:104881, (2021).
- [20] Selvaraj, V., Karthikaa, T.S., Mansiya, C., Alagar, M., “An over review on recently developed techniques, mechanisms and intermediate involved in the advanced azo dye degradation for industrial applications”, Journal of Molecular Structure, 1224: 129195, (2021).
- [21] Rochkind, M., Pasternak, S., Paz, Y., “Using dyes for evaluating photocatalytic properties: A critical review”, Molecules, 20: 88-110, (2015).
[22] Akpan, U.G., Hameed, B.H., “Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: A review”, Journal of Hazardous Materials, 170: 520-529, (2009).
[23] Collazzo, G.C., Foletto, E.L., Jahn, S.L., Villetti, M.A., “Degradation of Direct Black 38 dye under visible light and sunlight irradiation by N-doped anatase TiO2 as photocatalyst”, Journal of Environmental Management, 98: 107-111, (2012).
[24] Yeber, M.C., Zamora, T., Álvarez, R., Medina, P., “N-doped titanium dioxide nanoparticles activated under visible light achieve the photocatalytic degradation of textile azo dye remazol brilliant blue R”, Desalination and Water Treatment, 151: 161–166, (2019).
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- [27] Lin, Y. H., Chiu, T. C., Hsueh, H. T., Chu, H., “N-doped TiO2 photo-catalyst for the degradation of 1, 2-dichloroethane under fluorescent light”, Applied Surface Science, 258: 1581-1586, (2011).
- [28] Huang, W.C., Ting, J.M., “Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response”, Ceramics International, 43(13): 9992-9997, (2017).
- [29] Kalantari, K., Kalbasi, M., Sonrabi, M., Royaee, S.J., “Synthesis and characterization of N-doped TiO2 nanoparticles and their application in photocatalytic oxidation of dibenzothiophene under visible light”, Ceramics International, 42(13): 14834-14842, (2016).
- [30] Lee, S., Chou, I.S., Lee, D.K., Kim, D.W., Noh, T.H., Kwak, C.H., Park, S., Hong, K.S., Lee, J.-K., Jung, H.S., “Influence of nitrogen chemical states on photocatalytic activities of nitrogen-doped TiO2 nanoparticles under visible light”, Journal of Photochemistry and Photobiology A: Chemistry, 213: 129-135, (2010).
- [31] Ma, Y., Zhang, J., Tian, B., Chen, F., Wang, L., “Synthesis and characterization of thermally stable Sm, N co-doped TiO2 with highly visible light activity”, Journal of Hazardous Materials, 182: 386-393, (2010).
- [32] Gai, L., Mei, Q., Duan, X., Jiang, H., Zhou, G., Tian, Y., Lu, X., “Controlled synthesis of nitrogen-doped binary and ternary TiO2 nanostructures with enhanced visible-light catalytic activity”, Journal of Solid State Chemistry, 199: 271-279, (2013).
- [33] Senthilnathan, J., Philip, L., “Photocatalytic degradation of lindane under UV and visible light using N-doped TiO2”, Chemical Engineering Journal, 161: 83-92, (2010).
- [34] Din, M.İ., Khalid, R., Najeeb, J., Hussain, Z., “Fundamentals and photocatalysis of methylene blue dye using various nanocatalytic assemblies- a critical review”, Journal of Cleaner Production, 298: 126567, (2021).
- [35] Damodar, R.A., You, S. J., “Performance of an integrated membrane photocatalytic reactor for the removal of Reactive Black 5”, Separation and Purification Technology, 71: 44-49, (2010).
- [36] Turkish State Meteorological Service https://www.mgm.gov.tr/kurumici/radyasyon_iller.aspx?il=malatya Access date: 06.05.2021