Interaction of Methyl Red with Cetylpyridinium Chloride in Methanol-Water System

Year 2023, , 120 - 134, 01.03.2023

Neelam Shahi , Sujit Kumar Shah , Amar Prasad Yadav , Ajaya Bhattarai

https://doi.org/10.35378/gujs.978088

Cited By: 3

Abstract

The interaction between methyl red (azo dye) and cetylpyridinium chloride (cationic surfactant) in the methanol-water system were studied using a spectrophotometric technique. Variable parameters like constant dye concentration and its structure, surfactant concentration, pH, absorbance, and solvent composition were studied. Using the UV-Vis technique, critical micelle concentrations (CMCs) of cetylpyridinium chloride were measured with methyl red. The spectral data were analyzed and determined the differential absorbance, binding and partition constants, partition coefficient, the Gibbs free energy of binding and partition in mixed solvent media (0.1, 0.2, 0.3, 0.4 volume fraction (v.f.)s of methanol, respectively).

Keywords

Azo Dye, Cationic surfactant, CMC, Absorbance, Hypochromic shift

References

• [1] Ghoreishi, S.M., Behpour, M., Farsani, A.G., "Study of interaction between a cationic surfactant and two anionic azo dyes by ion-selective electrode technique and spectrophotometry", Dyes and Pigments, 74(3): 585–589, (2007).
• [2] Garcia, M.E.D., Sanz-Medel, A., "Dye-surfactant interactions: a review", Talanta, 33(3): 255–264, (1986).
• [3] Kert, M., Simoncic, B., "Importance of dye-surfactant interactions in dyeing", Tekstilec, 50: 187-207, (2007).
• [4] Bilksi, P., Chignell, C.F., "Properties of differently charged micelles containing rose bengal: application in photosensitization studies", Journal of Photochemistry and Photobiology A: Chemistry, 77: 49–58, (1994).
• [5] Bilski, P., Holt, R.N., Chignell, C.F., "Premicellar aggregates of Rose Bengal with cationic and zwitterionic surfactants", Journal of Photochemistry and Photobiology A: Chemistry, 110: 67–74, (1997).
• [6] Niraula, T.P., Chatterjee, S.K., Bhattarai, A., "Micellization of sodium dodecyl sulphate in presence and absence of alkali metal halides at different temperatures in water and methanol-water mixtures", Journal of Molecular Liquids, 250: 287-294, (2018).
• [7] Biswas, S., Pal, A., "Spectrophotometric determination of cationic surfactants in aqueous media using chrome azurol S as colour forming agent and 1-butanol as extracting solvent", Talanta, 206: 120-238, (2020).
• [8] Ahmadi, F., Daneshmehr, M. A., Rahimi, M., "The effect of anionic and cationic surfactants on indicators and measurement of dissociation constants with two different methods", Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 67(2): 412–419, (2007).
• [9] Sharifi, S., Nazar, M.F., Rakhshanizadeh, F., Sangsefedi, S.A., Azarpour, A., "Impact of amino acids, organic solvents and surfactants on azo-hydrazone tautomerism in methyl red: spectral-luminescent and nonlinear optical properties", Optical and Quantum Electronics, 52(2): 98, (2020).
• [10] Hahn, C., Wokaun, A., "Diffusion in surfactant systems studied by forced Rayleigh scattering", Langmuir, 13(3): 391–397, (1997).
• [11] Chanda, S., Ismail, K., "Surface potential and polarity at the micelle-solution interface in AOT + water system", Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 48(6): 775–780, (2009).
• [12] Terpko, A.T., Serafin, R.J., Bucholtz, M.L., “Conjugate acid-conjugate base equilibrium in reverse micelles”, Journal of Colloid and Interface Science, 84(1): 202-205, (1981).
• [13] Narayan, R.B., Goutham, R., Srikanth, B., Gopinath, K.P., "A novel nano-sized calcium hydroxide catalyst prepared from clam shells for the photodegradation of methyl red dye", Journal of Environmental Chemical Engineering, 6(3): 3640–3647, (2018).
• [14] Zhang, L., Cole, J.M., Waddell, P.G., Low, K.S., Liu, X., “Relating electron donor and carboxylic acid anchoring substitution effects in azo dyes to dye-sensitized solar cell performance”, ACS Sustainable Chemistry and Engineering, 1(11): 1440–1452, (2013).
• [15] Christodoulides, D.N., Khoo, I.C., Salamo, G.J., Stegeman, G.I., Van Stryland, E.W., "Nonlinear refraction and absorption: mechanisms and magnitudes", Advances in Optics and Photonics, 2(1): 60, (2010).
• [16] Plutino, M.R., Guido, E., Colleoni, C., Rosace, G., "Effect of GPTMS functionalization on the improvement of the pH-sensitive methyl red photostability", Sensors and Actuators, B: Chemical, 238: 281–291, (2017).
• [17] Sachin, K.M., Karpe, S.A., Singh, M., Bhattarai, A., "Study on surface properties of sodiumdodecyl sulfate and dodecyltrimethylammonium bromide mixed surfactants and their interaction with dyes", Heliyon, 5(4): e01510, (2019).
• [18] Shahi, N., Shah, S.K., Yadav, A.P., Bhattarai, A., "The spectral study of azo dye and cationic surfactant interaction in ethanol-water mixture”, Journal of the Serbian Chemical Society, 86(5): 483-494, (2021).
• [19] Tajpuriya, G.P., Shah, P., Shahi, N., Bhattarai, A., "UV–Vis studies of methyl red in the presence of sodium dioctylsulfosuccinate/acetone and sodium dioctylsulfosuccinate/acetone/water", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 255: 119646, (2021).
• [20] Hosseinzadeh, R., Maleki, R., Matin, A.A., Nikkhahi, Y., "Spectrophotometric study of anionic azo-dye light yellow (X6G) interaction with surfactants and its micellar solubilization in cationic surfactant micelles", Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 69(4): 1183–1187, (2008).
• [21] Edbey, K., El-Hashani, A., Benhmid, A., Ghwel, K., Benamer, M., "Spectral studies of eriochrome black T in cationic surfactants", Chemical Science International Journal, 24(4): 1–12, (2018).
• [22] Fazeli, S., Sohrabi, B., Tehrani-Bagha, A.R., "The study of sunset yellow anionic dye interaction with gemini and conventional cationic surfactants in aqueous solution", Dyes and Pigments, 95(3): 768–775, (2012).
• [23] Khosa, M.A., "Interaction of azo dye with cationic surfactant under different pH conditions", Journal of Surfactants and Detergents, 13: 529–537, (2010).
• [24] Shah, S.S., Naeem, K., Shah, S.W.H., Laghari, G.M., "Differential absorbance measurements of amphiphilic hemicyanine dyes, solubilization study in anionic surfactant", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 168(1): 77–85, (2000).
• [25] Bhattarai, A., Chatterjee, S.K., Deo, T.K., Niraula, T.P., "Effects of concentration, temperature, and solvent composition on the partial molar volumes of sodium lauryl sulfate in methanol ( 1 ) + water ( 2 ) mixed solvent media", Journal of Chemical & Engineering Data, 56(8): 3400-3405, (2011).
• [26] Karukstis, K.K., Perelman, L.A., Wong, W.K., “Spectroscopic characterization of azo dye aggregation on dendrimer surfaces”, Langmuir, 18: 10363–10371, (2002).
• [27] Hashemi, N., Sun, G., "Intermolecular interactions between surfactants and cationic dyes and effect on antimicrobial properties", Industrial and Engineering Chemistry Research, 49(18): 8347–8352, (2010).
• [28] Yang, J., "Interaction of surfactants and aminoindophenol dye", Journal of Colloid and Interface Science, 274(1): 237–243, (2004).
• [29] Hari, A.C., Paruchuri, R.A., Sabatini, D.A., Kibbey, T.C.G., "Effects of pH and cationic and nonionic surfactants on the adsorption of pharmaceuticals to a natural aquifer material", Environmental Science & Technology, 39(8): 2592–2598, (2005).
• [30] Bhattarai, A., Yadav, A.K., Sah, S.K., Deo, A., "Influence of methanol and dimethyl sulfoxide and temperature on the micellization of cetylpyridinium chloride", Journal of Molecular Liquids, 242: 831–837, (2017).
• [31] Kaur, A., Gupta, U., "The Review on Spectrophotometric Determination of Synthetic Food Dyes and Lakes" Gazi University Journal of Science, 25(3): 579-588, (2012).
• [32] Shah, P., Kumari Jha, S., Bhattarai, A., "Spectrophotometric study of the Sodium dodecyl sulfate in the presence of Methylene blue in the methanol-water mixed solvent system", Journal of Molecular Liquids, 117200, (2021).
• [33] Buwalda, R.T., Jonker, J.M., Engberts, J.B.F.N., "Aggregation of azo dyes with cationic amphiphiles at low concentrations in aqueous solution", Langmuir, 15(4): 1083–1089, (1999).