Color and COD Removal from Real Textile Wastewater using Nanoscale Zero-Value Iron (nZVI)
Year 2021,
Volume: 34 Issue: 4, 973 - 985, 01.12.2021
Özlem Tepe
,
Müslün Sara Tunç
,
Özge Hanay
Abstract
Nanoscale zero-value iron (nZVI) has a high specific surface area and significant abilities to reduce contaminants. In this study, the removal of color and COD from real textile wastewater was studied by nZVI particles. A series of experiments were conducted to evaluate the effect of operational parameters such as solution pH, nZVI dosage and temperature on color and COD removal. The results showed that the color and COD removals mainly depend on solution pH. The color removal efficiencies were 96.3% at 436 nm, 97.8% at 525 nm and 98.0% at 620 nm, respectively at nZVI dosage of 0.3 g/L and initial pH of 3 after 180 minutes of reaction time at 25 ○C. Moreover, the maximum COD removal efficiency obtained under these conditions was 86%.
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Year 2021,
Volume: 34 Issue: 4, 973 - 985, 01.12.2021
Özlem Tepe
,
Müslün Sara Tunç
,
Özge Hanay
References
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- [2] Bulca, Ö., Palas, B., Atalay, S., Ersöz, G. “Performance investigation of the hybrid methods of adsorption or catalytic wet air oxidation subsequent to electrocoagulation in treatment of real textile wastewater and kinetic modelling”, J. Water Process Eng., in press.
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- [17] Nakhate, P.H., Gadipelly, C.R., Joshi, N.T., Marathe, K.V., “Engineering aspects of catalytic ozonation for purification of real textile industry wastewater at the pilot scale”, J. Ind. Eng. Chem., 69: 77–89, (2019).
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- [19] Asgari, G., Shabanloo, A., Salarib, M., Eslami, F., “Sonophotocatalytic treatment of AB113 dye and real textile wastewater using ZnO/persulfate: Modeling by response surface methodology and artificial neural network”, Environ. Res., 184: 109367, (2020).
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- [21] Song, H., Carrway, E.R., “Reduction of chlorinated ethanes by nanosized zero-valent iron: kinetics, pathways, and effects of reaction condition”, Environ. Sci. Technol., 39, 6237–6245, (2005).
- [22] Üzüm, C., Shahwan, T., Eroğlu, A.E., Lieberwirth, I., Scott, T.B., Hallam, K.R., “Application of zero-valent iron nanoparticles for the removal of aqueous Co2+ ions under various experimental conditions”, Chem. Eng. J., 144: 213-220, (2008).
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- [27] Sohrabi, M.R., Amiri, S., Masoumi, H.R.F., Moghri, M., “Optimization of Direct Yellow 12 dye removal by nanoscale zero-valent iron using response surface methodology”, J. Ind. Eng. Chem., 20: 2535–2542, (2014).
- [28] Sohrabi, M.R., Moghri, M., Masoumi, H.R.F., Amiri, S., Moosavi, N., “Optimization of Reactive Blue 21 removal by nanoscale zero-valent iron using response surface methodology”, Arab. J. Chem., 9: 518–525, (2016).
- [29] Ling, X.F., Li, J.S., Zhu, W., Zhu, Y.Y., Sun, X.Y., Shen, J.Y., Han, W.Q., Wang, L.J., “Synthesis of nanoscale zero-valent iron/ordered mesoporous carbon for adsorption and synergistic reduction of nitrobenzene”, Chemosphere, 87: 655–660, (2012).
- [30] Zhang, X., Lin, Y.M., Shan, X.Q., Chen, Z.L., “Degradation of 2,4,6-trinitrotoluene(TNT) from explosive wastewater using nanoscale zero-valent iron”, Chem. Eng. J., 158, 566–570, (2010).
- [31]Hwang, Y.H., Kim, D.G., Shin, H.S., “Mechanism study of nitrate reduction by nano zero valent iron”, J. Hazard. Mater., 185: 1513–1521, (2011).
- [32] Eljamal, O., Mokete, R., Matsunaga, N., Sugihara, Y., “Chemical pathways of nanoscale zero-valent ıron (NZVI) during its transformation in aqueous solutions”, J. Environ. Chem. Eng., 6: 6207–6220, (2018).
- [33] Shoukat, R., Khan, S.J., Jamal, Y., “Hybrid anaerobic-aerobic biological treatment for real textile wastewater”, J. Water Process Eng., 29: 100804, (2019).
- [34] Hanay, O., Turk, H., “Comprehensive evaluation of adsorption and degradation of tetracycline and oxytetracycline by nanoscale zero-valent iron”, Desalin. Water Treat., 53(7): 1986-1994, (2015).
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- [36] Tunç, M.S., Tepe, O., “Removal of phenol from aqueous solution using persulfate activated with nanoscale zero-valent iron”, Desalin. Water Treat., 74: 269–277, (2017).
- [37] Sawafta, R., Shahwan, T., “A comparative study of the removal of methylene blue by iron nanoparticles from water and water-ethanol solutions”, J. Mol. Liq., 273: 274–281, (2019).
- [38] Fang, Z., Chen, J., Qiu, X., Qiu, X., Cheng, W., Zhu, L., “Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles”, Desalination, 268: 60–67, (2011).
- [39] Chen, Y., Lin, Z., Hao, R., Xu, H., Huang, C., “Rapid adsorption and reductive degradation of Naphthol Green B from aqueous solution by Polypyrrole/Attapulgite composites supported nanoscale zero-valent iron”, J. Hazard. Mater., 371: 8–17, (2019).
- [40] Dutta, S., Saha, R., Kalita, H., Bezbaruah, A.N., “Rapid reductive degradation of azo and anthraquinone dyes by nanoscale zero-valent iron”, Environ. Technol. Innov., 5: 176–187, (2016).
- [41] Weng, X., Cai, W., Lin, S., Chen, Z., “Degradation mechanism of amoxicillin using clay supported nanoscale zerovalent iron”, Appl. Clay Sci., 147: 137–142, (2017).
- [42] Zhang, B., Wang, D., “Preparation of biomass activated carbon supported nanoscale zero-valent iron (nZVI) and its application in decolorization of methyl orange from aqueous solution”, Water, 11: 1671, (2019).
- [43] Satapanajaru, T., Chompuchan, C., Suntornchot, P., Pengthamkeerati, P., “Enhancing decolorization of Reactive Black 5 and Reactive Red 198 during nano zerovalent iron treatment”, Desalination, 266: 218–230, (2011).
- [44] Xia, S., Gu, Z., Zhang, Z., Zhang, J., Hermanowicz, S.W., “Removal of chloramphenicol from aqueous solution by nanoscale zero-valent iron particles”, Chem. Eng. J., 257: 98–104, (2014).
- [45] Chen, Z.-X., Jin, X.-Y., Chen, Z., Megharaj, M., Naidu, R., “Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron”, J. Colloid Interf. Sci., 363: 601–607, (2011).