Araştırma Makalesi
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Yıl 2021, Cilt: 8 Sayı: 4, 287 - 297, 31.12.2021
https://doi.org/10.17350/HJSE19030000241

Öz

Kaynakça

  • [1] Zamri MH, Akil HM, MohdIshak ZA. Pultruded Kenaf Fibre Reinforced Composites: Effect of Different Kenaf Fibre Yarn Tex. Procedia Chem. 19 (2016) 577–585.
  • [2] Ilyas RA, Sapuan SM. The Preparation Methods and Processing of Natural Fibre Bio-polymer Composites. Curr. Org. Synth. 16 (2020) 1068–1070.
  • [3] Ilyas RA, Sapuan SM. Biopolymers and Biocomposites: Chemistry and Technology. Curr. Anal. Chem. 16 (2020) 500–503.
  • [4] Abral H, Atmajaya A, Mahardika M, Hafizulhaq F, Handayani DK, Sapuan SM, Ilyas RA. Effect of ultrasonication duration of polyvinyl alcohol (PVA) gel on characterizations of PVA film. J. Mater. Res. Technol. 9 (2020) 2477–2486.
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  • [7] Ilyas RA, Sapuan SM, Ibrahim R, Abral H, Ishak MR, Zainudin ES, Atikah MSN, Mohd Nurazzi N, Atiqah A, Ansari MNM, Syafri E, Asrofi M, Sari NH, Cumaidink R. Effect of sugar palm nanofibrillated cellulose concentrations on morphological, mechanical and physical properties of biodegradable films based on agro-waste sugar palm (Arenga pinnata (Wurmb.) Merr) starch. J. Mater. Res. Technol. 8 (2019) 4819–4830.
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Production and Characterization of Palm Oil Based Epoxy Biocomposite by RSM Design

Yıl 2021, Cilt: 8 Sayı: 4, 287 - 297, 31.12.2021
https://doi.org/10.17350/HJSE19030000241

Öz

In this research, some physical and chemical properties of the biocomposite obtained from synthesized epoxy modified palm oil (MPO) and epoxy resin have been characterized. The experimental study plan is made according to Response Surface Methodology (RSM) and biocomposites with different MPO rates are obtained. The chemical bond structure of MPO and epoxy biocomposite has been evaluated with Fourier Transform Infrared Spektrofotometre (FTIR). The experimental, and RSM model results obtained, the density of the biocomposite rise as the MPO rate increases. It is determined that the Shore D hardness of the biocomposite is inversely proportional to the MPO rate by mass. The thermal conductivity coefficient and thermal stability also rise with the rate of MPO (wt.%) in the biocomposite.
In the thermal degradation experiments of the obtained biocomposite, it is observed that the thermal stability of the composite goes up as the MPO rate rises. Activation energies are calculated using the Flynn Wall Ozawa, Kissinger, and Coats Redfern models. The activation energies calculated for the 9th, 2nd, and 13th experiments according to the Flynn Wall Ozawa method are approximately 139.65, 143.56, and 145.28 kJ/mol, respectively. The function with the highest R2 value has been determined according to the Coats Redfern method, and the deviation in Flynn Wall Ozawa and Kissinger model results was below 7%.

Kaynakça

  • [1] Zamri MH, Akil HM, MohdIshak ZA. Pultruded Kenaf Fibre Reinforced Composites: Effect of Different Kenaf Fibre Yarn Tex. Procedia Chem. 19 (2016) 577–585.
  • [2] Ilyas RA, Sapuan SM. The Preparation Methods and Processing of Natural Fibre Bio-polymer Composites. Curr. Org. Synth. 16 (2020) 1068–1070.
  • [3] Ilyas RA, Sapuan SM. Biopolymers and Biocomposites: Chemistry and Technology. Curr. Anal. Chem. 16 (2020) 500–503.
  • [4] Abral H, Atmajaya A, Mahardika M, Hafizulhaq F, Handayani DK, Sapuan SM, Ilyas RA. Effect of ultrasonication duration of polyvinyl alcohol (PVA) gel on characterizations of PVA film. J. Mater. Res. Technol. 9 (2020) 2477–2486.
  • [5] Faruk O, Bledzki AK, Fink HP, Sain M. Biocomposites reinforced with natural fibers: 2000–2010. Prog. Polym. Sci. 37 (2012) 1552–1596.
  • [6] Ilyas RA, Sapuan SM, Atikah, MSN, Asyraf MRM, Rafiqah SA, Aisyah HA, Nurazzi NM, Norrrahim MNF. Effect of hydrolysis time on the morphological, physical, chemical and thermal behavior of sugar palm nanocrystalline cellulose (Arenga pinnata (Wurmb.) Merr). Text. Res. J. 91(2021) 152–167.
  • [7] Ilyas RA, Sapuan SM, Ibrahim R, Abral H, Ishak MR, Zainudin ES, Atikah MSN, Mohd Nurazzi N, Atiqah A, Ansari MNM, Syafri E, Asrofi M, Sari NH, Cumaidink R. Effect of sugar palm nanofibrillated cellulose concentrations on morphological, mechanical and physical properties of biodegradable films based on agro-waste sugar palm (Arenga pinnata (Wurmb.) Merr) starch. J. Mater. Res. Technol. 8 (2019) 4819–4830.
  • [8] Ilyas RA, Sapuan SM, Ibrahim R, Abral H, Ishak MR, Zainudin ES, Asrofi M, Atikah MSN, Huzaifah MMR, Radzi AM, Azammi AMN, Shaharuzaman MA, Nurazzi NM, Syafri E, Sari NH, Norrrahim MRF, Jumaidinp R. Sugar palm (Arenga pinnata (Wurmb.) Merr) cellulosic fibre hierarchy: A comprehensive approach from macro to nanoscale. J. Mater. Res. Technol. 8 (2019) 2753–2766.
  • [9] Aisyah HA, Paridah MT, Sapuan SM, Khalina A, Berkalp OB, Lee SH, Lee CH, Nurazzi NM, Ramli N, Wahab MS, Ilyas RA. Thermal Properties of Woven Kenaf/Carbon Fibre-Reinforced Epoxy Hybrid Composite Panels. Int. J. Polym. Sci. (2019) 1–8.
  • [10] Jumaidin R, Saidi ZAS, Ilyas RA, Ahmad MN, Wahid MK, Yaakob MY, Maidin NA, Rahman MHA, Osman MH. Characteristics of Cogon Grass Fibre Reinforced Thermoplastic Cassava Starch Biocomposite: Water Absorption and Physical Properties. J. Adv. Res. Fluid Mech. Therm. Sci. 62 (2019) 43–52.
  • [11] Alsubari S, Zuhri MYM, Sapuan SM, Ishak M.R, Ilyas R.A, Asyraf M.R.M. Potential of Natural Fiber Reinforced Polymer Composites in Sandwich Structures: A Review on Its Mechanical Properties. Polymers 13 (2021) 423.
  • [12] Omran AAB, Mohammed AABA, Sapuan SM, Ilyas RA, Asyraf MRM, Koloor SSR, Petru M. Micro- and Nanocellulose in Polymer Composite Materials: A Review. Polymers. 13 (2021) 231.
  • [13] Nurazzi MN, Asyraf MRM, Khalina A, Abdullah N, Sabaruddin FA, Kamarudin SH, Ahmad S, Mahat AM, Lee C.L, Aisyah H.A, Norrahim MNF, İlyas RA, Harussani MM, Ishak B, Sapuanca SM. Fabrication, Functionalization, and Application of Carbon Nanotube-Reinforced Polymer Composite: An Overview. Polymers. 13 (2021) 1047.
  • [14] Aisyah HA, Paridah MT, Sapuan SM, Ilyas RA, Khalina A, Nurazzi NM, Lee SH, Lee CH. A Comprehensive Review on Advanced Sustainable Woven Natural Fibre Polymer Composites. Polymers. 13 (2021) 471.
  • [15] Jumaidin R, Khiruddin MAA, Saidi ASZ, Salit MS, Ilyas RA. Effect of cogon grass fibre on the thermal, mechanical and biodegradation properties of thermoplastic cassava starch biocomposite. Int. J. Biol. Macromol. 146 (2020) 746–755.
  • [16] Sanjay MR, Arpitha GR, Naik LL, Gopalakrishna K, Yogesha B. Applications of Natural Fibers and Its Composites: An Overview. Nat. Resour. 7 (2016)108–114.
  • [17] Asyraf MRM, Ishak MR, Sapuan SM, Yidris N, Ilyas RA. Woods and composites cantilever beam: A comprehensive review of experimental and numerical creep methodologies. J. Mater. Res. Technol. 9 (2020) 6759–6776.
  • [18] Ayu RS, Khalina A, Harmaen A.S, Zaman K, Isma T, Liu Q, Ilyas RA, Lee CH. Characterization Study of Empty Fruit Bunch (EFB) Fibers Reinforcement in Poly (Butylene) Succinate (PBS)/Starch/Glycerol Composite Sheet. Polymers. 12 (2020) 1571.
  • [19] Holbery J, Houston D. Natural-fiber-reinforced polymer composites in automotive applications. JOM. 58 (2006) 80–86.
  • [20] Kim YK, Chalivendra V. Natural fibre composites (NFCs) for construction and automotive industries. In Handbook of Natural Fibres; Elsevier: Amsterdam, The Netherlands, 469–498, 2020.
  • [21] Fragassa C. Marine applications of natural fibre-reinforced composites: A manufacturing case study. In Advances in Applications of Industrial Biomaterials; Springer: Berlin/Heidelberg, Germany, 21–47, 2017.
  • [22] Jaafar ACN, Zainol I, Ishak NS, Ilyas RA, Sapuan SM. Effects of the Liquid Natural Rubber (LNR) on Mechanical Properties and Microstructure of Epoxy/Silica/Kenaf Hybrid Composite for Potential Automotive Applications. J. Mater. Res. Technol. 12 (2021) 1026–1038.
  • [23] Rezaifard AH, Hodd KA, Tod DA, Barton JM. Toughening epoxy resins with poly (methyl methacrylate)-grafter-natural rubber and its use in adhesive formulations. Int. J. Adhes. Adhes. 14 (1994) 153–159.
  • [24] Technotes BE. Composite Recycling, and Disposal An Environmental R&D Issue. Boeing Environ. Technotes. 8 (2003) 1–4.
  • [25] Bandyopadhyay S. Source composite curve for waste reduction. Chem. Eng. J. 125 (2006) 99–110.
  • [26] Sanjay MR, Madhu P, Jawaid M, Senthamaraikannan P, Senthil S, Pradeep S. Characterization and properties of natural fiber polymer composites: A comprehensive review. J. Clean. Prod. 172 (2018) 566–581.
  • [27] Vinod A, Sanjay MR, Suchart S, Jyotishkumar P. Renewable and sustainable biobased materials: An assessment on biofibers, biofilms, biopolymers, and biocomposites. J. Clean. Prod. 258 (2020) 120978.
  • [28] Ramnath VB, Kokan JS, Raja NR, Sathyanarayanan R, Elanchezhian C, Prasad RA, Manickavasagam V.M. Evaluation of mechanical properties of abaca-jute-glass fibre reinforced epoxy composite. Mater. Des. 51 (2013) 357–366.
  • [29] Szolnoki B, Bocz K, Sóti PL, Bodzay B, Zimonyi E, Toldy A, Morlin B, Bujnowicz K, Wladyka-Przybylak M, Marosi G. Development of natural fibre reinforced flame retarded epoxy resin composites. Polym. Degrad. Stab. 119 (2015) 68–76.
  • [30] Pickering KL, Le TM. High performance aligned short natural fibre—Epoxy composites. Compos. Part B Eng. 85 (2016) 123–129.
  • [31] Mittal V, Saini R, Sinha S. Natural fiber-mediated epoxy composites—A review. Compos. Part B 99 (2016) 425–435.
  • [32] Abu Bakar MA, Ahmad S, Kuntjoro W. Effect of epoxidized natural rubber on mechanical properties of epoxy reinforced kenaf fibre composites. Pertanika J. Sci. Technol. 20 (2012) 129–137.
  • [33] Hassan F, Zulkifli R, Ghazali MJ, Azhari CH. Kenaf Fiber Composite in Automotive Industry: An Overview. Int. J. Adv. Sci. Eng. Inf. Technol. 7 (2017) 315.
  • [34] Nurazzi NM, Khalina A, Sapuan SM, Ilyas, R.A. Mechanical properties of sugar palm yarn/woven glass fiber reinforced unsaturated polyester composites: Effect of fiber loadings and alkaline treatment. Polimery. 64 (2019) 12–22.
  • [35] Rihayat T, Suryani S, Fauzi T, Agusnar H, Wirjosentono B, Syafruddin, Helmi, Zulkifli, Alam PN, Sami M. . Mechanical properties evaluation of single and hybrid composites epoxy reinforced bamboo, PALF and coir fiber. IOP Conf Ser Mater Sci Eng. 334 (2018) 012081. doi:10.1088/1757-899X/334/1/012081 [36] Wang F, Shao Z. Study on the variation law of bamboo fibers’ tensile properties and the organization structure on the radial direction of bamboo stem. Ind Cros Products. 152 (2020) 112521.
  • [37] Mahmoud MA. Oil spill cleanup by raw flax fiber: modification effect, sorption isotherm, kinetics, and thermodynamics. Arabian J Chem. 13 (2020) 5553– 5563.
  • [38] Kang JT, Kim SH. Improvement in the mechanical properties of polylactide and bamboo fiber biocomposites by fiber surface modification. Macromol Res. 19 (2011)789–796.
  • [39] Lee SH, Wang S. Biodegradable polymers/bamboo fiber biocomposite with bio-based coupling agent. Compos Appl Sci Manuf. 37 (2006) 80–91.
  • [40] Fan M. Chemical compositions of natural fibres. In: S. R. Reid, G. Zhou, editors. Advanced high strength natural fibre composites in construction. London: Woodhead Publishing, 35–41, 2016.
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Toplam 62 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Hakan Şahal 0000-0001-8714-1735

Ercan Aydoğmuş 0000-0002-1643-2487

Yayımlanma Tarihi 31 Aralık 2021
Gönderilme Tarihi 24 Haziran 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 8 Sayı: 4

Kaynak Göster

Vancouver Şahal H, Aydoğmuş E. Production and Characterization of Palm Oil Based Epoxy Biocomposite by RSM Design. Hittite J Sci Eng. 2021;8(4):287-9.

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