Optimization of extraction parameters of cationic dye using emulsified liquid membrane process. Application of Box-Behnken design
Year 2022,
Volume: 6 Issue: 1, 1 - 6, 06.07.2022
Salima Bendebane
,
Hawa Bendebane
Farida Bendebane
Fadhel Ismaıl
Abstract
Cationic dye (Methylene blue) was extract from waste water by using emulsified liquid membrane process. The membrane composed of two phases: organic and aqueous. D2EHPA, SPAN 80 and acid are the composition of aqueous phase, however the fuel oil represent the organic phase. The effect of different parameters such as the initial concentration of cationic dye (MB), the addition of salt (KCl/ NaCl/ Na2SO4), acid (HCl/ H2SO4/H3PO4) and the extractant concentration (10, 30 and 50 ppm) was examined using Box-Behnken design.
The optimization of the extraction has been showed that the extraction efficiency reach100% for the following optimum operating conditions: 30 ppm for the initial concentration of [BM]0, 10%w for the extracting (D2EHPA) with the presence of Na2SO4 and H2SO4. It can be said that the ELM method is efficient for the removal of methylene bleu.
Supporting Institution
Ministry of Higher Education and Scientific Research of Algeria
Project Number
A16N01UN230120130063
Thanks
We thank Prof. Abbes Boukhari Director of the LOMOP Research Laboratory and Dr Fethi Saoudi Head of the Process EngineeringDepartment, BadjMokhtar University of Annaba, for providing us with the necessary material resources.
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Year 2022,
Volume: 6 Issue: 1, 1 - 6, 06.07.2022
Salima Bendebane
,
Hawa Bendebane
Farida Bendebane
Fadhel Ismaıl
Project Number
A16N01UN230120130063
References
- R.S. Juang et al., Environ. Technol., 1997, 18, 525 531.
- C Zaharia, D Suteu. Textile organic dyes – characteristics polluting effects and sep-aration/elimination procedures from industrial effluents – a critical overview or-ganic pollutants ten years after the Stockholm convention - environmental and analytical update. In: Puzyn T, editor. Croatia: Tech Europr; 2012.
- M. Djenouhat et al., Royal Society Open Science, 2018, 5: 171220.
- H. Ghodbane et al., Ultrason. Sonochem. 16 (2009) 593–598.
- El-Khamssa. Guechi et al., Desalination and water treatment, 2012, Volume 38, issue 1-3, pp. 401-408.
- L. Bouziane et al., Desalination and water treatment, 2012, Volume 49, issue 1-3,189-199.
- F. Bendebane e al., Poll Res., 2016, 35(4): 23-29, ISSN 0257–8050.
- L. Bahloul et al., Journal of Taiwan Institute of Chemical Engineers, 2016, Volume-59, page 26-32, Issue-7.
- EA. Fouad et al., Journal of Membrane Science, 2008, Vol. 307, p. 156–168.
- J-J. Droesbeke, J. Fine, G. Saporta, Plans d’expériences, applications à l’entreprise, association pour la statistique et ses utilisation.société statistique de France, éditions Techni, pp509, chapitre 2, Paris; 1997.
- P. Dangnelie, Principes d’expérimentation, Gembloux, Presses Agronomiques; 1993.
- P. Dangnelie, Statistique théorique et appliquée, Tome 1 : Les bases théoriques, Gembloux, Presses Agronomiques; 1992.
- J. Mare-Azaïs, Composantes de la variabilité des plans d’expériences. laboratoire de statistique et probabilité-UMR CNRS C55830. Université Paul Sabatier-31062-Toulouse Cedex 4.
- I. Amirat, Elimination du colorant cationique (BM) par les membranes liquides émulsionnée, application des plans d’expériences, mémoire de Master, université Badji Mokhtar –Annaba; 2016.
- J. Goupy, Plans d’expériences, Techniques de l’ingénieur, traité Analyse et Caractérisation, Volume PE 230, 1-28 1998.
- M. Djenouhat et al, Separation and purification Technology, 2008, 63 : 231-238.
- M. Lechheb, extraction du colorant orange II en milieu aqueux par membrane liquide émulsionnée, Université Badji Mokhtar Annaba; 2016.
- A. Kargari et al., Desalination, 2004, 162, 237-247.
- J-Q. Shen et al., Journal of Membrane Science, 1996, 120: 45-53.