Thermal and Chemical Aspect in Equation of State and Relation with Generalized Thermodynamic Entropy

Year 2018, Volume: 21 Issue: 1, 55 - 60, 01.03.2018

Pierfrancesco Palazzo

https://doi.org/10.5541/ijot.383353

Cited By: 3

Abstract

The present
research is aimed at using the definition of generalized thermodynamic entropy,
as a state and additive property, to extend the canonical Equation of State in
the perspective of thermal or chemical aspect of microscopic configurations
related to inter-particle kinetic energy and inter-particle potential energy
determining macroscopic parameters. As a consequence, a generalized state
equation is formulated accounting for thermal, chemical and mechanical
thermodynamic potentials characterizing any system, large or small, in any
state, equilibrium or non-equilibrium.

Keywords

Many-particle system, few-particle system, first law, second law, generalized thermodynamic entropy, generalized exergy, generalized state equation

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