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Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol

Yıl 2019, Cilt 22, Sayı 3, 128 - 136, 01.09.2019
https://doi.org/10.5541/ijot.532108

Öz

The present study aimed to determine the refractive indices at 293.15 K and density data at T= (283.15, 293.15, 303.15 and 313.15) K of the binary mixtures of 1-ethyl-3-methylimidazolium ethylphosphonate + methanol or 2-propanol under the atmospheric pressure. The excess molar volume, the apparent molar volume, the partial molar and excess partial molar volumes of the components at infinite dilution were calculated from the experimental values. The results of excess molar volumes were fitted to a Redlich– Kister equation, leading thus to obtain the coefficients and to estimate the standard deviations between the experimental and the calculated quantities. Also, the results of excess molar volumes of the two investigated binary mixtures showed negative deviations from ideal behavior of the investigated binary systems which can be then discussed in terms of ion-dipole interactions, formation of hydrogen bonds and structural factors. Additionally, the refractive indices measurements and the deviations of refractive index were determined.

Kaynakça

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Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol

Yıl 2019, Cilt 22, Sayı 3, 128 - 136, 01.09.2019
https://doi.org/10.5541/ijot.532108

Öz

La présente étude visait à déterminer les indices de réfraction à 293,15 K et les données de densité à T = (283,15, 293,15, 303,15 et 313,15) K des mélanges binaires de 1- éthyl - 3 - méthylimidazoliuméthylphosphonate + méthanol ou 2-propanol sous la pression atmosphérique. Le volume molaire en excès, le volume molaire apparent, les volumes molaires partiels et les volumes molaires partiels en excès des composants à dilution infinie ont été calculés à partir des valeurs expérimentales. Les résultats des volumes molaires en excès ont été ajustés à une équation de Redlich-Kister, conduisant ainsi à obtenir les coefficients et à estimer les écarts-types entre les quantités expérimentale et calculée. En outre, les résultats des volumes molaires en excès des deux mélanges binaires étudiés ont montré des écarts négatifs par rapport au comportement idéal des systèmes binaires étudiés, qui peuvent ensuite être discutés en termes d’interactions ion-dipôle, de formation de liaisons hydrogène et de facteurs structurels. . Additionally, the refractive indices measurements and the deviations of refractive index were determined.

 

Kaynakça

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  • [27] U. Domanska, A. Marciniak.; “Measurements of activity coefficients at infinite dilution of aromatic and aliphatic hydrocarbons, alcohols and water in new ionic liquid [EMIM][SCN] using GLC ». J. Chem. Thermodyn, 40, 860–866, 2008.
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Ayrıntılar

Birincil Dil İngilizce
Konular Termodinamik
Bölüm Regular Original Research Article
Yazarlar

Farida ALLAL> (Sorumlu Yazar)
Amar Telidji University
Algeria


Abdellah DAHMANİ Bu kişi benim


Boubaker SAİDAT Bu kişi benim

Yayımlanma Tarihi 1 Eylül 2019
Yayınlandığı Sayı Yıl 2019, Cilt 22, Sayı 3

Kaynak Göster

Bibtex @araştırma makalesi { ijot532108, journal = {International Journal of Thermodynamics}, issn = {1301-9724}, eissn = {2146-1511}, address = {}, publisher = {Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi}, year = {2019}, volume = {22}, number = {3}, pages = {128 - 136}, doi = {10.5541/ijot.532108}, title = {Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol}, key = {cite}, author = {Allal, Farida and Dahmani, Abdellah and Saidat, Boubaker} }
APA Allal, F. , Dahmani, A. & Saidat, B. (2019). Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol . International Journal of Thermodynamics , 22 (3) , 128-136 . DOI: 10.5541/ijot.532108
MLA Allal, F. , Dahmani, A. , Saidat, B. "Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol" . International Journal of Thermodynamics 22 (2019 ): 128-136 <https://dergipark.org.tr/tr/pub/ijot/issue/48498/532108>
Chicago Allal, F. , Dahmani, A. , Saidat, B. "Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol". International Journal of Thermodynamics 22 (2019 ): 128-136
RIS TY - JOUR T1 - Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol AU - FaridaAllal, AbdellahDahmani, BoubakerSaidat Y1 - 2019 PY - 2019 N1 - doi: 10.5541/ijot.532108 DO - 10.5541/ijot.532108 T2 - International Journal of Thermodynamics JF - Journal JO - JOR SP - 128 EP - 136 VL - 22 IS - 3 SN - 1301-9724-2146-1511 M3 - doi: 10.5541/ijot.532108 UR - https://doi.org/10.5541/ijot.532108 Y2 - 2019 ER -
EndNote %0 International Journal of Thermodynamics Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol %A Farida Allal , Abdellah Dahmani , Boubaker Saidat %T Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol %D 2019 %J International Journal of Thermodynamics %P 1301-9724-2146-1511 %V 22 %N 3 %R doi: 10.5541/ijot.532108 %U 10.5541/ijot.532108
ISNAD Allal, Farida , Dahmani, Abdellah , Saidat, Boubaker . "Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol". International Journal of Thermodynamics 22 / 3 (Eylül 2019): 128-136 . https://doi.org/10.5541/ijot.532108
AMA Allal F. , Dahmani A. , Saidat B. Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol. International Journal of Thermodynamics. 2019; 22(3): 128-136.
Vancouver Allal F. , Dahmani A. , Saidat B. Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol. International Journal of Thermodynamics. 2019; 22(3): 128-136.
IEEE F. Allal , A. Dahmani ve B. Saidat , "Volumetric properties of binary mixtures of 1-ethyl-3-methylimidazolium ethyl phosphonate + methanol or 2-propanol", International Journal of Thermodynamics, c. 22, sayı. 3, ss. 128-136, Eyl. 2019, doi:10.5541/ijot.532108