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Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide

Year 2011, Volume: 14 Issue: 1, 37 - 42, 01.02.2011

Aimen Issaoui Ali Ben Moussa Hatem Hatem Ksibi

Abstract

This contribution is focused on supercritical solutions of many polar solutes in carbon dioxide (nonpolar solvent) when the molar polarization of the solute at infinite dilution is accurately known. A database containing experimental solubility measurements for many solutes is used in this study where isotherms are known between 308 and 343 K. A mathematical model is developed to compute the solubility of solids in supercritical fluids, particularly in carbon dioxide. As a result, a new correlation of the binary interaction (kij) is proposed. This new relationship considers the kij term as a function of the dipole moment and the solute carbon number.

Keywords

Solubility; supercritical fluid; binary interaction; optimization; dipole moment

References

  • Ambrose, D. Walton, J. (1989). Vapour pressures up to their critical temperatures of normal alkanes and 1- alkanols. J. Pure & Appl. Chem. 61, 1395-1403.
  • Bartle, K.D. Clifford, A.A. , Shilstane, G.F. (1992). Estimation of solubilities in supercritical carbon dioxide: A correlation for the peng-robinson interaction parameters. J. of supercritical fluids, 5(3), 220-225.
  • Chrastil, J. (1982) Solubility of solids and liquids in supercritical gases. J. Phys. Chem. 86 (15), 3016-3021.
  • Erkey C., Madras G., Orejuela M., Akgerman A. (1993). Supercritical carbon dioxide extraction of organics from soil. Environmental Science & Technology, 27(6), 1225-1231.
  • Kraska T., Leonhard K. O., Tuma D., Schneider G. M., (2002). Correlation of the solubility of low-volatile organic compounds in near- and supercritical fluids. Part I: applications to adamantane and β-carotene. J. of Supercritical Fluids 23 (3), 209–224.
  • Ksibi, H. (1999). Modélisation de la solubilité d’un produit organique dans une solution supercritique, Revue Entropie, 222, 34-39.
  • Ksibi H., (2004). The solvent - solute interaction in supercritical solution at equilibrium: Modelling and related industrial applications. Int. J. of Thermodynamics, 7(3), 131-140.
  • Ksibi H., Ben Moussa A. (2007). Prediction of critical parameters of cholesterol and its binary interaction coefficient in the supercritical carbon dioxide. Int. J. of Thermodynamics. 10 (1), 47-52.
  • McHugh, M. A., Krukonis, V. J. (1994). Supercritical Fluid Extraction: Principles and Practice, ed. Butterworths
  • Mohamed, R. S.; Saldana, M. D. A.; Socantaype, F. H.; Kieckbusch, T. G. (2000). Reduction in the cholesterol content of butter oil using supercritical ethane extraction and adsorption on alumina. J. of Supercritical Fluids 16(3), 225-233.
  • Paunovic, R.; Jovanovic, S.; Mihajlov, A. (1981). Rapid computation of binary interaction coefficients of an equation of state for vapor-liquid equilibrium calculations: application to the Redlich-Kwong-Soave equation of state. Fluid Phase Equilibria, 6, 141-148.
  • Ravi R., Prakash M. and Bhat K. (2007). Aroma characterization of coriander ( Coriandrum sativum L.) oil samples, Eur Food Res Technol 225, 367–374.
  • Rogalski, M., Carrier, B., Solimando, R., Peneloux, A., (1990). Ccorrelation and prediction of physical properties of hydrocarbons with the modified Peng- Robinson equation of state. 2. Representation of the vapor pressures and of the molar volumes, Ind. Eng. Chem. Res., 29(4), 659-666.
  • Kenneth S. Pitzer, Donald R. Schreiber (1988).Improving equation-of-state accuracy in the critical region; equations for carbon dioxide and neopentane as examples. Fluid Phase Equilibria. 41(1-2),1-17.
  • Stamataki S., Tassios D. (1998). Performance of cubic EOS at high pressures, Oil & Gas Science and Technology -53(3), 367- 377.
  • UenoH., TanakaM., MachmudahS., Sasaki M. and Goto Extraction of Valuable Compounds from Citrus junos Seed, Food and Bioprocess Technology, 1(4), 357-363.
  • Valderrama, J. O. (2003). The state of the cubic equations of state, Ind. Eng. Chem. Res. 42, 1603-1618.

Year 2011, Volume: 14 Issue: 1, 37 - 42, 01.02.2011

Aimen Issaoui Ali Ben Moussa Hatem Hatem Ksibi

Abstract

References

  • Ambrose, D. Walton, J. (1989). Vapour pressures up to their critical temperatures of normal alkanes and 1- alkanols. J. Pure & Appl. Chem. 61, 1395-1403.
  • Bartle, K.D. Clifford, A.A. , Shilstane, G.F. (1992). Estimation of solubilities in supercritical carbon dioxide: A correlation for the peng-robinson interaction parameters. J. of supercritical fluids, 5(3), 220-225.
  • Chrastil, J. (1982) Solubility of solids and liquids in supercritical gases. J. Phys. Chem. 86 (15), 3016-3021.
  • Erkey C., Madras G., Orejuela M., Akgerman A. (1993). Supercritical carbon dioxide extraction of organics from soil. Environmental Science & Technology, 27(6), 1225-1231.
  • Kraska T., Leonhard K. O., Tuma D., Schneider G. M., (2002). Correlation of the solubility of low-volatile organic compounds in near- and supercritical fluids. Part I: applications to adamantane and β-carotene. J. of Supercritical Fluids 23 (3), 209–224.
  • Ksibi, H. (1999). Modélisation de la solubilité d’un produit organique dans une solution supercritique, Revue Entropie, 222, 34-39.
  • Ksibi H., (2004). The solvent - solute interaction in supercritical solution at equilibrium: Modelling and related industrial applications. Int. J. of Thermodynamics, 7(3), 131-140.
  • Ksibi H., Ben Moussa A. (2007). Prediction of critical parameters of cholesterol and its binary interaction coefficient in the supercritical carbon dioxide. Int. J. of Thermodynamics. 10 (1), 47-52.
  • McHugh, M. A., Krukonis, V. J. (1994). Supercritical Fluid Extraction: Principles and Practice, ed. Butterworths
  • Mohamed, R. S.; Saldana, M. D. A.; Socantaype, F. H.; Kieckbusch, T. G. (2000). Reduction in the cholesterol content of butter oil using supercritical ethane extraction and adsorption on alumina. J. of Supercritical Fluids 16(3), 225-233.
  • Paunovic, R.; Jovanovic, S.; Mihajlov, A. (1981). Rapid computation of binary interaction coefficients of an equation of state for vapor-liquid equilibrium calculations: application to the Redlich-Kwong-Soave equation of state. Fluid Phase Equilibria, 6, 141-148.
  • Ravi R., Prakash M. and Bhat K. (2007). Aroma characterization of coriander ( Coriandrum sativum L.) oil samples, Eur Food Res Technol 225, 367–374.
  • Rogalski, M., Carrier, B., Solimando, R., Peneloux, A., (1990). Ccorrelation and prediction of physical properties of hydrocarbons with the modified Peng- Robinson equation of state. 2. Representation of the vapor pressures and of the molar volumes, Ind. Eng. Chem. Res., 29(4), 659-666.
  • Kenneth S. Pitzer, Donald R. Schreiber (1988).Improving equation-of-state accuracy in the critical region; equations for carbon dioxide and neopentane as examples. Fluid Phase Equilibria. 41(1-2),1-17.
  • Stamataki S., Tassios D. (1998). Performance of cubic EOS at high pressures, Oil & Gas Science and Technology -53(3), 367- 377.
  • UenoH., TanakaM., MachmudahS., Sasaki M. and Goto Extraction of Valuable Compounds from Citrus junos Seed, Food and Bioprocess Technology, 1(4), 357-363.
  • Valderrama, J. O. (2003). The state of the cubic equations of state, Ind. Eng. Chem. Res. 42, 1603-1618.
There are 17 citations in total.

Details

Primary Language English
Journal Section Regular Original Research Article
Authors

Aimen Issaoui This is me

Ali Ben Moussa This is me

Hatem Hatem Ksibi

Publication Date February 1, 2011
Published in Issue Year 2011 Volume: 14 Issue: 1

Cite

APA Issaoui, A., Moussa, A. B., & Hatem Ksibi, H. (2011). Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide. International Journal of Thermodynamics, 14(1), 37-42.
AMA Issaoui A, Moussa AB, Hatem Ksibi H. Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide. International Journal of Thermodynamics. February 2011;14(1):37-42.
Chicago Issaoui, Aimen, Ali Ben Moussa, and Hatem Hatem Ksibi. “Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide”. International Journal of Thermodynamics 14, no. 1 (February 2011): 37-42.
EndNote Issaoui A, Moussa AB, Hatem Ksibi H (February 1, 2011) Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide. International Journal of Thermodynamics 14 1 37–42.
IEEE A. Issaoui, A. B. Moussa, and H. Hatem Ksibi, “Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide”, International Journal of Thermodynamics, vol. 14, no. 1, pp. 37–42, 2011.
ISNAD Issaoui, Aimen et al. “Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide”. International Journal of Thermodynamics 14/1 (February 2011), 37-42.
JAMA Issaoui A, Moussa AB, Hatem Ksibi H. Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide. International Journal of Thermodynamics. 2011;14:37–42.
MLA Issaoui, Aimen et al. “Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide”. International Journal of Thermodynamics, vol. 14, no. 1, 2011, pp. 37-42.
Vancouver Issaoui A, Moussa AB, Hatem Ksibi H. Correlation of the Binary Interaction Factor for Polar Solutes Dissolved in Supercritical Carbon Dioxide. International Journal of Thermodynamics. 2011;14(1):37-42.