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Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory

Year 2012, Volume: 15 Issue: 3, 127 - 132, 04.06.2012

John Jennings

Abstract

A theory for the surface tension of polymer solutions is used along with classical nucleation theory to predict the temperature rise above the solvent limit of superheat due to addition of polymer.  Polystyrene, of 2000 and 4000 molecular weight, was added to cyclohexane and it produced a linear rise in the superheat to an extent that depends upon both molecular weight and concentration.  The theory is used in the athermal case (dT = 0) to give the additional temperature rise with respect to weight fraction.

Keywords

polymer solutions nucleation surface thermodynamics limit of superheat

Year 2012, Volume: 15 Issue: 3, 127 - 132, 04.06.2012

John Jennings

Abstract

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Details

Primary Language English
Journal Section Regular Original Research Article
Authors

John Jennings

Publication Date June 4, 2012
Published in Issue Year 2012 Volume: 15 Issue: 3

Cite

APA Jennings, J. (2012). Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory. International Journal of Thermodynamics, 15(3), 127-132.
AMA Jennings J. Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory. International Journal of Thermodynamics. June 2012;15(3):127-132.
Chicago Jennings, John. “Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory”. International Journal of Thermodynamics 15, no. 3 (June 2012): 127-32.
EndNote Jennings J (June 1, 2012) Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory. International Journal of Thermodynamics 15 3 127–132.
IEEE J. Jennings, “Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory”, International Journal of Thermodynamics, vol. 15, no. 3, pp. 127–132, 2012.
ISNAD Jennings, John. “Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory”. International Journal of Thermodynamics 15/3 (June 2012), 127-132.
JAMA Jennings J. Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory. International Journal of Thermodynamics. 2012;15:127–132.
MLA Jennings, John. “Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory”. International Journal of Thermodynamics, vol. 15, no. 3, 2012, pp. 127-32.
Vancouver Jennings J. Limit of Superheat of Polystyrene-Cyclohexane Solutions: Theory. International Journal of Thermodynamics. 2012;15(3):127-32.