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Thermodynamic Analysis of Isobutane Dehydrogenation Reaction

Year 2015, Volume: 18 Issue: 4, 213 - 223, 18.01.2015
https://doi.org/10.5541/ijot.5000087441

Abstract

The thermodynamic of isobutane dehydrogenation reaction was deeply investigated using most reliable literature data. Conversion and reaction mixture distribution at equilibrium was computed for various process conditions.
Reaction enthalpy, ∆_R H_T^o , ranges between 122±1.1 and 123±1.2 kJ.mol-1 over the temperature (773.15 to 923.15) K where the equilibrium constant K_T value varies between 0.12±0.03 and 2.6±0.7. The reaction becomes thermodynamically favorable at temperatures higher than 873.15 K.

References

  • D. Sanfilippo, I. Miracca, F. Trifirò, Dehydrogenation Processes, In Encyclopedia of Hydrocarbons, Grafiche, M. Ed. Roma-Italy: S.P.A., 2005.
  • D. E. Resasco, Dehydrogenation by Heterogeneous Catalysts, In Encyclopedia of Catalysis, Horvath, I.T.N.Y., Ed. New York: Wiley, 2003.
  • B. M. Weckhuysen, R. A. Schoonheydt, “Alkane dehydrogenation over supported chromium oxide catalysts,” Catalysis Today, 51, 223-232, 1999.
  • J. Gregor, D. Wei, UOP Oleflex Process for light olefin production, In Handbook of Petrochemicals Production Processes, Meyers, R. A., Ed. New York: McGraw-Hill, 2005.
  • H. Liu, Z. Yu, A. Ma, Y. Sun, Z. Wang, ”Thermodynamic analysis on dehydrogenation of isobutane to isobutene,” Acta Petrolei Sinica, 27, 419- 423, 2011. (Chinese)
  • L. Constantinou, and R. Gani. “New group contribution method for estimating properties of pure compounds,” AIChE J, 40, 1697–1710, 1994.
  • E. S. Domalski, E. D. Hearing, “Estimation of the thermodynamic properties of hydrocarbons at 298.15K,” J. Phys. Chem. Ref. Data, 17, 1637-1678, 1988.
  • R. A. Alberty, C. A. Gehrig, “Standard chemical thermodynamic properties of alkene isomer groups,” J. Phys. Chem. Ref. data, 14, 803-820, 1985.
  • Joback, K. G. (1984). A Unified Approach to Physical Property Estimation Using Multivariate Statistical Techniques (MS. Thesis), Massachusetts Institute of Technology, Cambridge, MA.
  • J. Happel, R. Mezaki, “Thermodynamic equilibrium constant of isobutane-isobutene-hydrogen system,” J. Chem. Eng. Data, 18, 2, 152-154, 1973.
  • J. E. Germain, Catalytic Conversion of Hydrocarbons, London: Academic Press, 1969.
  • S. W. Benson, F. R. Cruickshank, D. M. Golden, G. R. Haugen, H. E. O’Neal, A. S. Rodgers, R. Shaw, R. Walsh, “Additivity rules for the estimation of thermochemical properties,” Chem. Rev., 69, 279-324, 1969.
  • B. E. Poling, J. M. Prausnitz, J. P. O’ Connell, The Properties of Gases and Liquids, 5th Ed. New York: McGraw-Hill, 2001
  • N. Cohen, S. W. Benson, Alkanes and Cycloalkanes, West Sussex, England: John Wiley and Sons Ltd., doi: 10.1002/0470034378. ch6. 1992. Published Online: 8 AUG 2006
  • J. E. Kilpatrick, K. S. Pitzer, “Heat Content, Free- energy Function, Entropy, and Heat Capacity of Ethylene, Propylene, and the Four Butenes to 1,500K,” Journal of Research, U. S. Department of Commerce National Bureau of Standards, Research Paper RP 1738, Vol. 37, 163-171, September 1946
  • JCGM 100:2008, Evaluation of measurement data - Guide to the expression of uncertainty in measurement, Document produced by Working Group (JCGM/WG 1) 2008, Corrected version 2010.
  • S. W. Benson, Thermochemical Kinetics, 2nd Ed. New York: Wiley, 1976.
  • R. C. Reid, J. M. Prausnitz, B. E. Poling, The Properties of Gases and Liquids, 4th Ed. New York: McGraw-Hill, 1987.
  • R. L. Rowley, W. V. Wilding, J. L. Oscarson, Y. Yang, N. A. Zundel, T. E. Daubert, R. P. Danner. “DIPPR®. Data Compilation of Pure Chemical Properties, Design Institute for Physical Properties,” AIChE, New York, 2007
  • G. Kyle, Chemical and Process Thermodynamics, Engelwood Cliffs, NJ: Prentice-Hall, 1984.
  • M. W. Chase, “Jr., NIST-JANAF Thermo-chemical Tables, 4th,“ Journal of Physical Chemical Reference Data, Monograph 9, 1-1951, 1998.
  • F. A. Aly, L.L. Lee, “Self-consistent equations for calculating the ideal-gas heat capacity, enthalpy and entropy,” Fluid Phase Equilibria, 6, 69-79, 1981.
  • S. S. Chen, “Ideal gas thermodynamic properties and isomerization of n-butane and isobutane,” J. Phys. Chem. Ref. Data, 4, 859-869, 1975.
  • K. Wark, Thermodynamics, 4th Ed. New York: Mc Graw-Hill, 1983.
  • E. J. Prosen, E. W. Maron, F. Rossini, “Heats of combustion, formation, and isomerization of ten c4 hydrocarbons”, J. Res. Natl. Bur. Stand. (U.S.), 46, 106, 1951.
  • D. W. Scott, “The chemical thermodynamic properties of hydrocarbons and related substances,” Washington U.S. Bureau of Mines, Bull. 666, p187, 1974.
  • J. B. Pedley, R. D. Naylor, S. P. Kirby, Thermochemical
  • Data of Organic Compounds, 2nd Ed. London and New
  • York: Chapman and Hall, 1986.
  • B. J. Zwolinski, et al., “Selected values of properties of
  • hydrocarbons and related compounds,” American
  • Petroleum Institute Research Project 44, Thermodynamic
  • Research Center, Texas A&M University, 1977.
Year 2015, Volume: 18 Issue: 4, 213 - 223, 18.01.2015
https://doi.org/10.5541/ijot.5000087441

Abstract

References

  • D. Sanfilippo, I. Miracca, F. Trifirò, Dehydrogenation Processes, In Encyclopedia of Hydrocarbons, Grafiche, M. Ed. Roma-Italy: S.P.A., 2005.
  • D. E. Resasco, Dehydrogenation by Heterogeneous Catalysts, In Encyclopedia of Catalysis, Horvath, I.T.N.Y., Ed. New York: Wiley, 2003.
  • B. M. Weckhuysen, R. A. Schoonheydt, “Alkane dehydrogenation over supported chromium oxide catalysts,” Catalysis Today, 51, 223-232, 1999.
  • J. Gregor, D. Wei, UOP Oleflex Process for light olefin production, In Handbook of Petrochemicals Production Processes, Meyers, R. A., Ed. New York: McGraw-Hill, 2005.
  • H. Liu, Z. Yu, A. Ma, Y. Sun, Z. Wang, ”Thermodynamic analysis on dehydrogenation of isobutane to isobutene,” Acta Petrolei Sinica, 27, 419- 423, 2011. (Chinese)
  • L. Constantinou, and R. Gani. “New group contribution method for estimating properties of pure compounds,” AIChE J, 40, 1697–1710, 1994.
  • E. S. Domalski, E. D. Hearing, “Estimation of the thermodynamic properties of hydrocarbons at 298.15K,” J. Phys. Chem. Ref. Data, 17, 1637-1678, 1988.
  • R. A. Alberty, C. A. Gehrig, “Standard chemical thermodynamic properties of alkene isomer groups,” J. Phys. Chem. Ref. data, 14, 803-820, 1985.
  • Joback, K. G. (1984). A Unified Approach to Physical Property Estimation Using Multivariate Statistical Techniques (MS. Thesis), Massachusetts Institute of Technology, Cambridge, MA.
  • J. Happel, R. Mezaki, “Thermodynamic equilibrium constant of isobutane-isobutene-hydrogen system,” J. Chem. Eng. Data, 18, 2, 152-154, 1973.
  • J. E. Germain, Catalytic Conversion of Hydrocarbons, London: Academic Press, 1969.
  • S. W. Benson, F. R. Cruickshank, D. M. Golden, G. R. Haugen, H. E. O’Neal, A. S. Rodgers, R. Shaw, R. Walsh, “Additivity rules for the estimation of thermochemical properties,” Chem. Rev., 69, 279-324, 1969.
  • B. E. Poling, J. M. Prausnitz, J. P. O’ Connell, The Properties of Gases and Liquids, 5th Ed. New York: McGraw-Hill, 2001
  • N. Cohen, S. W. Benson, Alkanes and Cycloalkanes, West Sussex, England: John Wiley and Sons Ltd., doi: 10.1002/0470034378. ch6. 1992. Published Online: 8 AUG 2006
  • J. E. Kilpatrick, K. S. Pitzer, “Heat Content, Free- energy Function, Entropy, and Heat Capacity of Ethylene, Propylene, and the Four Butenes to 1,500K,” Journal of Research, U. S. Department of Commerce National Bureau of Standards, Research Paper RP 1738, Vol. 37, 163-171, September 1946
  • JCGM 100:2008, Evaluation of measurement data - Guide to the expression of uncertainty in measurement, Document produced by Working Group (JCGM/WG 1) 2008, Corrected version 2010.
  • S. W. Benson, Thermochemical Kinetics, 2nd Ed. New York: Wiley, 1976.
  • R. C. Reid, J. M. Prausnitz, B. E. Poling, The Properties of Gases and Liquids, 4th Ed. New York: McGraw-Hill, 1987.
  • R. L. Rowley, W. V. Wilding, J. L. Oscarson, Y. Yang, N. A. Zundel, T. E. Daubert, R. P. Danner. “DIPPR®. Data Compilation of Pure Chemical Properties, Design Institute for Physical Properties,” AIChE, New York, 2007
  • G. Kyle, Chemical and Process Thermodynamics, Engelwood Cliffs, NJ: Prentice-Hall, 1984.
  • M. W. Chase, “Jr., NIST-JANAF Thermo-chemical Tables, 4th,“ Journal of Physical Chemical Reference Data, Monograph 9, 1-1951, 1998.
  • F. A. Aly, L.L. Lee, “Self-consistent equations for calculating the ideal-gas heat capacity, enthalpy and entropy,” Fluid Phase Equilibria, 6, 69-79, 1981.
  • S. S. Chen, “Ideal gas thermodynamic properties and isomerization of n-butane and isobutane,” J. Phys. Chem. Ref. Data, 4, 859-869, 1975.
  • K. Wark, Thermodynamics, 4th Ed. New York: Mc Graw-Hill, 1983.
  • E. J. Prosen, E. W. Maron, F. Rossini, “Heats of combustion, formation, and isomerization of ten c4 hydrocarbons”, J. Res. Natl. Bur. Stand. (U.S.), 46, 106, 1951.
  • D. W. Scott, “The chemical thermodynamic properties of hydrocarbons and related substances,” Washington U.S. Bureau of Mines, Bull. 666, p187, 1974.
  • J. B. Pedley, R. D. Naylor, S. P. Kirby, Thermochemical
  • Data of Organic Compounds, 2nd Ed. London and New
  • York: Chapman and Hall, 1986.
  • B. J. Zwolinski, et al., “Selected values of properties of
  • hydrocarbons and related compounds,” American
  • Petroleum Institute Research Project 44, Thermodynamic
  • Research Center, Texas A&M University, 1977.
There are 33 citations in total.

Details

Primary Language English
Journal Section Regular Original Research Article
Authors

Mazhar Abdulwahed

Publication Date January 18, 2015
Published in Issue Year 2015 Volume: 18 Issue: 4

Cite

APA Abdulwahed, M. (2015). Thermodynamic Analysis of Isobutane Dehydrogenation Reaction. International Journal of Thermodynamics, 18(4), 213-223. https://doi.org/10.5541/ijot.5000087441
AMA Abdulwahed M. Thermodynamic Analysis of Isobutane Dehydrogenation Reaction. International Journal of Thermodynamics. December 2015;18(4):213-223. doi:10.5541/ijot.5000087441
Chicago Abdulwahed, Mazhar. “Thermodynamic Analysis of Isobutane Dehydrogenation Reaction”. International Journal of Thermodynamics 18, no. 4 (December 2015): 213-23. https://doi.org/10.5541/ijot.5000087441.
EndNote Abdulwahed M (December 1, 2015) Thermodynamic Analysis of Isobutane Dehydrogenation Reaction. International Journal of Thermodynamics 18 4 213–223.
IEEE M. Abdulwahed, “Thermodynamic Analysis of Isobutane Dehydrogenation Reaction”, International Journal of Thermodynamics, vol. 18, no. 4, pp. 213–223, 2015, doi: 10.5541/ijot.5000087441.
ISNAD Abdulwahed, Mazhar. “Thermodynamic Analysis of Isobutane Dehydrogenation Reaction”. International Journal of Thermodynamics 18/4 (December 2015), 213-223. https://doi.org/10.5541/ijot.5000087441.
JAMA Abdulwahed M. Thermodynamic Analysis of Isobutane Dehydrogenation Reaction. International Journal of Thermodynamics. 2015;18:213–223.
MLA Abdulwahed, Mazhar. “Thermodynamic Analysis of Isobutane Dehydrogenation Reaction”. International Journal of Thermodynamics, vol. 18, no. 4, 2015, pp. 213-2, doi:10.5541/ijot.5000087441.
Vancouver Abdulwahed M. Thermodynamic Analysis of Isobutane Dehydrogenation Reaction. International Journal of Thermodynamics. 2015;18(4):213-2.