Determination of Hydrogen Peroxide in Foods Using Enzyme-likeBehaviors of Nano Iron-Oxide

Abstract

Hydrogen peroxide (H2O2) is a chemical compound that is introduced into food for the food production, processing, packaging and preservation. In many countries it is known that par-ticipation in gardens is prohibited and causes food production costs to be lowered even though it is restricted, so it can be informally involved in food and it is known that microor-ganisms breeding in food and causing deterioration cause increase in H2O2in food. It has been reported that a considerable decrease in the quality of H2O2food, which is present in high quantities in potatoes, leads to loss of vitamins and especially poisoning and cancer. For this reason, it is very important to determine the peroxide level in ppm scale in foods at the residual level. In this study; we aimed to determine hydrogen peroxide using nano-iron-oxide (Fe3O4) synthesized by green synthesis method. For this purpose, we determined that hydro-gen peroxide determination at 0.15-12.5 m level can be done linearly by using the reaction that nano-iron-oxide(Fe3O4) shows peroxidase enzyme like properties.

Keywords

• Hydrogen peroxide (H2O2),Green synthesis,Nano-iron-oxide (Fe3O4)

References

1. [1] Silva RAB, Montes RHO, Richter EM, Munoz RAA. Rapid and se-lective determination of hydrogen peroxide residues in milk by batch injection analysis with amperometric detection. Food Chemistry(2012) 133:200–4. doi:10.1016/j.foodchem.2012.01.003.
2. [2] Tanaka A, Iijima M, Kikuchi Y. Determination of hydrogen perox-ide in fish products and noodles (Japanese) by gas-liquid chromatography with electron-capture detection. Journal of Agricultural and Food Chemistry(1990) 38:2154–9. doi:10.1021/jf00102a011.
3. [3] Güngör AA, Gündüz S, Nadaroğlu H, Altundaş A, editors. Glukoz Tayini İçin Enzim Benzeri Metal Nanopartiküllerin Kullanımının Araştırılması [Investigation of the Use of Enzyme-Like Metal Nano-particles for Glucose Detection] (2017).
4. [4] Karaduman I, Güngör AA, Nadaroğlu H, Altundaş A, Acar S. Green synthesis of γ-Fe2O3nanoparticles for methane gas sensing. Journal of Materials Science: Materials in Electronics(2017) 28:16094–105. doi:10.1007/s10854-017-7510-5.
5. [5] Güngör AA. Use of Different Plant Derived Peroxidases for the Removal of Phenol from Water. Asian Journal of Chemistry (ISI),(2011) 23:3710-3712.
6. [6] Gao Y, Wang G, Huang H, Hu J, Shah SM, Su X. Fluorometric method for the determination of hydrogen peroxide and glucose with Fe3O4 as catalyst. Talanta(2011) 85:1075–80. doi:10.1016/j.ta-lanta.2011.05.021.
7. [7] Liu J, Lu L, Li A, Tang J, Wang S, Xu S, et al. Simultaneous detection of hydrogen peroxide and glucose in human serum with upcon-version luminescence. Biosensors & Bioelectronics(2015) 68:204–9. doi:10.1016/j.bios.2014.12.053.
8. [8] Song S, Liu Y, Song A, Zhao Z., Lu H, Hao J. Peroxidase mimetic activity of Fe3O4 nanoparticle prepared based on magnetic hydro-gels for hydrogen peroxide and glucose detection. Journal of Colloid and Interface Science(2017) 506:46–57

9. [9] Zhao, Y., Huo D., Bao J., Yang M., Chen M., Hou J., Fa H. and Hou C. Biosensor based on 3D graphene-supported Fe3O4quantum dots as biomimetic enzyme for in situ detection of H2O2released from living cells. Sensors and Actuators B: Chemical(2017) 244:1037–44.
10. [10] Bağcı U, Temiz A. Taze Sıkılmış Meyve Sularının Mikrobiyolojik Kalitesi [Microbiological Quality of Fresh Fruit Juices]. Orlab Online Mikrobiyoloji Dergisi [Orlab Online Journal of Microbiol-ogy] (2006) 4:1–20.
11. [11] White JW, Subers MH, Schepartz AI. The identification of inhibine the antibacterial factor in honey, as hydrogen peroxide and its origin in a honey glucose-oxidase system. Biochimica et Biophysica Acta (BBA)(1963):57–70.
12. [12] Weston R. Identification and quantitative levels of antibacterial components of some New Zealand honeys. Food Chemistry(2000) 70:427–35. doi:10.1016/S0308-8146(00)00127-8.