Femtosecond Laser Cleaning of Archaeological Cultural Assets
Yıl 2022,
Cilt: 17 Sayı: 2, 75 - 84, 30.06.2022
Gülin Gençoğlu Korkmaz
,
Yasemin Gündoğdu
,
İlker Işık
,
Abuzer Kızıl
,
Serap Yiğit Gezgin
,
Hamdi Şükür Kılıç
Öz
This study presents research on femtosecond laser ablation of corrosion crusts from ancient coin. On the surface of ancient coin sample was irradiated with 800 nm laser wavelength, 90 femtosecond laser pulses in duration, and 1 kHz repetition rate. Femtosecond laser ablation was carried out changing laser intensity using from 1.96 x1013 W/cm2 to 9.82 x 1014 W/cm2 in atmospheric conditions. Scanning electron microscope and optic microscope images were recorded and scanning electron microscope- energy dispersive X-ray spectroscopy graphs and reports were recorded. The used coin belonged to the near Roman Imperial Age where the copper-zinc alloy was used for coins. The amount of copper and zinc ratios before and after application of laser ablation procedure is reported by courtesy of scanning electron microscope-energy dispersive X-ray spectroscopy graphs and reports on surface of coin. Scanning electron microscope and light microscope images show that laser intensities above 9,82 x1014 W/cm2 perform an effective cleaning process.
Teşekkür
Authors kindly would like to thank,
- Selçuk University, High Technology Research and Application Center and
- University of Selçuk, SULTAN Center and Conservation and Restoration of Cultural Assets Department for supplying with infrastructure,
- Republic of Turkey, Ministry of Culture to permission and to supply ancient coin.
Note:
The permission document to allow us to remove of corrosion layer on ancient coin samples have been got from Ministry of Culture of Republic of Turkey and they have been given back to museum after cleaning process.
Kaynakça
- Referans1
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016a). Evaluatıng Laser Cleanıng Of Corroded Archaeologıcal Sılver Coıns. Mediterranean Archaeology & Archaeometry, 16(1).https://doi.org/DOI: 10.5281/zenodo.35527
- Referans2
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016b). Evaluatıng The Use Of Laser In Analysıs And Cleanıng Of The Islamıc Marıne Archaeologıcal Coıns Excavated From The Red Sea. International Journal of Conservation Science, 7(2).
- Referans3
Al-Sadoun, A., & Abdel-Kareem, O. (2019). Authentıcatıon And Conservatıon Of Selected Metal Objects Excavated From Al-Sereın, Near Makkah, Saudı Arabıa. Mediterranean Archaeology and Archaeometry, 19(2), 23-38. https://doi.org/DOI:10.5281/zenodo.306600
- Referans4
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016a). Evaluatıng Laser Cleanıng Of Corroded Archaeologıcal Sılver Coıns. Mediterranean Archaeology & Archaeometry, 16(1). https://doi.org/DOI: 10.5281/zenodo.35527
- Referans5
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016b). Evaluatıng The Use Of Laser In Analysıs And Cleanıng Of The Islamıc Marıne Archaeologıcal Coıns Excavated From The Red Sea. International Journal of Conservation Science, 7(2).
- Referans6
Al-Sadoun, A., & Abdel-Kareem, O. (2019). Authentıcatıon And Conservatıon Of Selected Metal Objects Excavated From Al-Sereın, Near Makkah, Saudı Arabıa. Mediterranean Archaeology and Archaeometry, 19(2), 23-38. https://doi.org/DOI:10.5281/zenodo.306600
- Referans7
Antonopoulou-Athera, N., Kalathakis, C., Chatzitheodoridis, E., & Serafetinides, A. (2019). Theoretical and experimental approach on laser cleaning of coins. SN Applied Sciences, 1(3), 238. https://doi.org/https://doi.org/10.1007/s42452-019-0255-4
- Referans8
Bilmes, G. M., Vallejo, J., Vera, C. C., & Garcia, M. E. (2018). High efficiencies for laser cleaning of glassware irradiated from the back: application to glassware historical objects. Applied Physics A, 124(4), 347. https://doi.org/https://doi.org/10.1007/s00339-018-1761-8
Referans9
Buccolieri, G., Nassisi, V., Torrisi, L., Buccolieri, A., Castellano, A., Di Giulio, M., Giuffreda, E., Delle Side, D., & Velardi, L. (2014). Analysis of selective laser cleaning of patina on bronze coins. Journal of Physics: Conference Series,
- Referans10
Burmester, T., Meier, M., Haferkamp, H., Barcikowski, S., Bunte, J., & Ostendorf, A. (2005). Femtosecond laser cleaning of metallic cultural heritage and antique artworks. In Lasers in the Conservation of Artworks (pp. 61-69). Springer.
- Referans11
Chichkov, B. N., Momma, C., Nolte, S., Von Alvensleben, F., & Tünnermann, A. (1996). Femtosecond, picosecond and nanosecond laser ablation of solids. Applied Physics A, 63(2), 109-115. https://doi.org/https://doi.org/10.1007/BF01567637
- Referans12
Chillè, C., Papadakis, V. M., & Theodorakopoulos, C. (2020). An analytical evaluation of Er: YAG laser cleaning tests on a nineteenth century varnished painting. Microchemical Journal, 105086. https://doi.org/https://doi.org/10.1016/j.microc.2020.105086
- Referans13
Craddock, P. (2009). Scientific investigation of copies, fakes, and forgeries. Routledge. https://doi.org/10.4324/9780080939001
- Referans14
Dajnowski, B. A. (2013). Laser ablation cleaning of an underwater archaeological bronze spectacle plate from the HMS DeBraak shipwreck. Optics for Arts, Architecture, and Archaeology IV,
- Referans15
Di Francia, E., Lahoz, R., Neff, D., Angelini, E., & Grassini, S. (2018). Laser cleaning of Cu-based artefacts: laser/corrosion products interaction. ACTA IMEKO, 7(3), 104-110. https://doi.org/DOI: 10.21014/acta_imeko.v7i3.610
- Referans16
Di Turo, F. (2019). Limits and perspectives of archaeometric analysis of archaeological metals: A focus on the electrochemistry for studying ancient bronze coins. Journal of cultural heritage. https://doi.org/https://doi.org/10.1016/j.culher.2019.10.006
- Referans17
Drakaki, E., Karydas, A., Klinkenberg, B., Kokkoris, M., Serafetinides, A., Stavrou, E., Vlastou, R., & Zarkadas, C. (2004). Laser cleaning on Roman coins. Applied Physics A, 79(4-6), 1111-1115. https://doi.org/DOI: 10.1007/s00339-004-2657-3
- Referans18
Ersoy, T., Tunay, T., Uğuryol, M., Mavili, G., & Akturk, S. (2014). Femtosecond laser cleaning of historical paper with sizing. Journal of cultural heritage, 15(3), 258-265. https://doi.org/https://doi.org/10.1016/j.culher.2013.07.002
- Referans19
Gamaly, E. G., Rode, A. V., Luther-Davies, B., & Tikhonchuk, V. T. (2002). Ablation of solids by femtosecond lasers: Ablation mechanism and ablation thresholds for metals and dielectrics. Physics of plasmas, 9(3), 949-957. https://doi.org/https://doi.org/10.1063/1.1447555
- Referans20
Georgiou, S., Anglos, D., & Fotakis, C. (2008). Photons in the service of our past: lasers in the preservation of cultural heritage. Contemporary Physics, 49(1), 1-27. https://doi.org/https://doi.org/10.1080/00107510802038398
- Referans21
Gondal, M. A., Nasr, M. M., Ahmed, Z., & Yamani, Z. H. (2009). Determination of trace elements in volcanic rock samples collected from Cenozoic lava eruption sites using LIBS. Journal of Environmental Science and Health Part A, 44(5), 528-535.https://doi.org/10.1080/10934520902720116
- Referans22
Harmon, R. S., Remus, J., McMillan, N. J., McManus, C., Collins, L., Gottfried, J. L., DeLucia, F. C., & Miziolek, A. W. (2009). LIBS analysis of geomaterials: Geochemical fingerprinting for the rapid analysis and discrimination of minerals. Applied Geochemistry, 24(6), 1125-1141. https://doi.org/https://doi.org/10.1016/j.apgeochem.2009.02.009
- Referans23
Harmon, R. S., Russo, R. E., & Hark, R. R. (2013). Applications of laser-induced breakdown spectroscopy for geochemical and environmental analysis: A comprehensive review. Spectrochimica Acta Part B: Atomic Spectroscopy, 87, 11-26.https://doi.org/10.1016/j.sab.2013.05.017
- Referans24
Kalam, S. A., Rao, S. B. M., Jayananda, M., & Rao, S. V. (2020). Standoff femtosecond filament-induced breakdown spectroscopy for classification of geological materials. Journal of Analytical Atomic Spectrometry, 35(12), 3007-3020.DOI https://doi.org/10.1039/D0JA00355G
- Referans25
Koh, Y., & Sárady, I. (2003). Cleaning of corroded iron artefacts using pulsed TEA CO2-and Nd: YAG-lasers. Journal of cultural heritage, 4, 129-133. https://doi.org/https://doi.org/10.1016/S1296-2074(02)01140-8
- Referans26
Korenberg, C., & Baldwin, A. (2006). Laser cleaning tests on archaeological copper alloys using an ND: YAG Laser. Laser Chemistry, 2006. https://doi.org/DOI: 10.1155/2006/75831
- Referans27
Korte, F., Serbin, J., Koch, J., Egbert, A., Fallnich, C., Ostendorf, A., & Chichkov, B. (2003). Towards nanostructuring with femtosecond laser pulses. Applied Physics A, 77(2), 229-235. https://doi.org/https://doi.org/10.1007/s00339-003-2110-z
- Referans28
Lasheras, R., Bello-Gálvez, C., & Anzano, J. (2010). Identification of polymers by libs using methods of correlation and normalized coordinates. Polymer testing, 29(8), 1057-1064.https://doi.org/10.1016/j.polymertesting.2010.07.011
- Referans29
Liu, X., Du, D., & Mourou, G. (1997). Laser ablation and micromachining with ultrashort laser pulses. IEEE journal of quantum electronics, 33(10), 1706-1716. https://doi.org/DOI: 10.1109/3.631270
- Referans30
Maharjan, N., Zhou, W., Zhou, Y., & Guan, Y. (2017). Femtosecond laser cleaning for aerospace manufacturing and remanufacturing. Lasers and Electro-Optics Pacific Rim (CLEO-PR), 2017 Conference on,
- Referans31
Muhammed Shameem, K. M., Dhanada, V. S., Harikrishnan, S., George, S. D., Kartha, V. B., Santhosh, C., & Unnikrishnan, V. K. (2020). Echelle LIBS-Raman system: A versatile tool for mineralogical and archaeological applications. Talanta, 208, 120482. https://doi.org/https://doi.org/10.1016/j.talanta.2019.120482
- Referans32
Nevin, A., Pouli, P., Georgiou, S., & Fotakis, C. (2007). Laser conservation of art. Nature Materials, 6(5), 320. https://doi.org/https://doi.org/10.1038/nmat1895
- Referans33
Palomar, T., Oujja, M., Llorente, I., Barat, B. R., Cañamares, M., Cano, E., & Castillejo, M. (2016). Evaluation of laser cleaning for the restoration of tarnished silver artifacts. Applied Surface Science, 387, 118-127. https://doi.org/https://doi.org/10.1016/j.apsusc.2016.06.017
- Referans34
Petiti, C., Toniolo, L., Gulotta, D., Mariani, B., & Goidanich, S. (2020). Effects of cleaning procedures on the long-term corrosion behavior of bronze artifacts of the cultural heritage in outdoor environment. Environmental Science and Pollution Research, 1-14. https://doi.org/https://doi.org/10.1007/s11356-020-07814-4
- Referans35
Pini, R., Siano, S., Salimbeni, R., Pasquinucci, M., & Miccio, M. (2000). Tests of laser cleaning on archeological metal artefacts. Journal of cultural heritage, 1, S129-S137. https://doi.org/https://doi.org/10.1016/S1296-2074(00)00139-4
- Referans36
Pouli, P., Oujja, M., & Castillejo, M. (2012). Practical issues in laser cleaning of stone and painted artefacts: optimisation procedures and side effects. Applied Physics A, 106(2), 447-464. https://doi.org/https://doi.org/10.1007/s00339-011-6696-2
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Remus, J., Gottfried, J., Harmon, R., Draucker, A., Baron, D., & Yohe, R. (2010). Archaeological Applications of Laser-induced Breakdown Spectroscopy: An Example from the Coso Volcanic Field, California, Using Advanced Statistical Signal Processing Analysis. Applied Optics - APPL OPT, 49. https://doi.org/10.1364/AO.49.00C120
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Yıl 2022,
Cilt: 17 Sayı: 2, 75 - 84, 30.06.2022
Gülin Gençoğlu Korkmaz
,
Yasemin Gündoğdu
,
İlker Işık
,
Abuzer Kızıl
,
Serap Yiğit Gezgin
,
Hamdi Şükür Kılıç
Kaynakça
- Referans1
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016a). Evaluatıng Laser Cleanıng Of Corroded Archaeologıcal Sılver Coıns. Mediterranean Archaeology & Archaeometry, 16(1).https://doi.org/DOI: 10.5281/zenodo.35527
- Referans2
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016b). Evaluatıng The Use Of Laser In Analysıs And Cleanıng Of The Islamıc Marıne Archaeologıcal Coıns Excavated From The Red Sea. International Journal of Conservation Science, 7(2).
- Referans3
Al-Sadoun, A., & Abdel-Kareem, O. (2019). Authentıcatıon And Conservatıon Of Selected Metal Objects Excavated From Al-Sereın, Near Makkah, Saudı Arabıa. Mediterranean Archaeology and Archaeometry, 19(2), 23-38. https://doi.org/DOI:10.5281/zenodo.306600
- Referans4
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016a). Evaluatıng Laser Cleanıng Of Corroded Archaeologıcal Sılver Coıns. Mediterranean Archaeology & Archaeometry, 16(1). https://doi.org/DOI: 10.5281/zenodo.35527
- Referans5
Abdel-Kareem, O., Al-Zahrani, A., Khedr, A., & Harith, M. A. (2016b). Evaluatıng The Use Of Laser In Analysıs And Cleanıng Of The Islamıc Marıne Archaeologıcal Coıns Excavated From The Red Sea. International Journal of Conservation Science, 7(2).
- Referans6
Al-Sadoun, A., & Abdel-Kareem, O. (2019). Authentıcatıon And Conservatıon Of Selected Metal Objects Excavated From Al-Sereın, Near Makkah, Saudı Arabıa. Mediterranean Archaeology and Archaeometry, 19(2), 23-38. https://doi.org/DOI:10.5281/zenodo.306600
- Referans7
Antonopoulou-Athera, N., Kalathakis, C., Chatzitheodoridis, E., & Serafetinides, A. (2019). Theoretical and experimental approach on laser cleaning of coins. SN Applied Sciences, 1(3), 238. https://doi.org/https://doi.org/10.1007/s42452-019-0255-4
- Referans8
Bilmes, G. M., Vallejo, J., Vera, C. C., & Garcia, M. E. (2018). High efficiencies for laser cleaning of glassware irradiated from the back: application to glassware historical objects. Applied Physics A, 124(4), 347. https://doi.org/https://doi.org/10.1007/s00339-018-1761-8
Referans9
Buccolieri, G., Nassisi, V., Torrisi, L., Buccolieri, A., Castellano, A., Di Giulio, M., Giuffreda, E., Delle Side, D., & Velardi, L. (2014). Analysis of selective laser cleaning of patina on bronze coins. Journal of Physics: Conference Series,
- Referans10
Burmester, T., Meier, M., Haferkamp, H., Barcikowski, S., Bunte, J., & Ostendorf, A. (2005). Femtosecond laser cleaning of metallic cultural heritage and antique artworks. In Lasers in the Conservation of Artworks (pp. 61-69). Springer.
- Referans11
Chichkov, B. N., Momma, C., Nolte, S., Von Alvensleben, F., & Tünnermann, A. (1996). Femtosecond, picosecond and nanosecond laser ablation of solids. Applied Physics A, 63(2), 109-115. https://doi.org/https://doi.org/10.1007/BF01567637
- Referans12
Chillè, C., Papadakis, V. M., & Theodorakopoulos, C. (2020). An analytical evaluation of Er: YAG laser cleaning tests on a nineteenth century varnished painting. Microchemical Journal, 105086. https://doi.org/https://doi.org/10.1016/j.microc.2020.105086
- Referans13
Craddock, P. (2009). Scientific investigation of copies, fakes, and forgeries. Routledge. https://doi.org/10.4324/9780080939001
- Referans14
Dajnowski, B. A. (2013). Laser ablation cleaning of an underwater archaeological bronze spectacle plate from the HMS DeBraak shipwreck. Optics for Arts, Architecture, and Archaeology IV,
- Referans15
Di Francia, E., Lahoz, R., Neff, D., Angelini, E., & Grassini, S. (2018). Laser cleaning of Cu-based artefacts: laser/corrosion products interaction. ACTA IMEKO, 7(3), 104-110. https://doi.org/DOI: 10.21014/acta_imeko.v7i3.610
- Referans16
Di Turo, F. (2019). Limits and perspectives of archaeometric analysis of archaeological metals: A focus on the electrochemistry for studying ancient bronze coins. Journal of cultural heritage. https://doi.org/https://doi.org/10.1016/j.culher.2019.10.006
- Referans17
Drakaki, E., Karydas, A., Klinkenberg, B., Kokkoris, M., Serafetinides, A., Stavrou, E., Vlastou, R., & Zarkadas, C. (2004). Laser cleaning on Roman coins. Applied Physics A, 79(4-6), 1111-1115. https://doi.org/DOI: 10.1007/s00339-004-2657-3
- Referans18
Ersoy, T., Tunay, T., Uğuryol, M., Mavili, G., & Akturk, S. (2014). Femtosecond laser cleaning of historical paper with sizing. Journal of cultural heritage, 15(3), 258-265. https://doi.org/https://doi.org/10.1016/j.culher.2013.07.002
- Referans19
Gamaly, E. G., Rode, A. V., Luther-Davies, B., & Tikhonchuk, V. T. (2002). Ablation of solids by femtosecond lasers: Ablation mechanism and ablation thresholds for metals and dielectrics. Physics of plasmas, 9(3), 949-957. https://doi.org/https://doi.org/10.1063/1.1447555
- Referans20
Georgiou, S., Anglos, D., & Fotakis, C. (2008). Photons in the service of our past: lasers in the preservation of cultural heritage. Contemporary Physics, 49(1), 1-27. https://doi.org/https://doi.org/10.1080/00107510802038398
- Referans21
Gondal, M. A., Nasr, M. M., Ahmed, Z., & Yamani, Z. H. (2009). Determination of trace elements in volcanic rock samples collected from Cenozoic lava eruption sites using LIBS. Journal of Environmental Science and Health Part A, 44(5), 528-535.https://doi.org/10.1080/10934520902720116
- Referans22
Harmon, R. S., Remus, J., McMillan, N. J., McManus, C., Collins, L., Gottfried, J. L., DeLucia, F. C., & Miziolek, A. W. (2009). LIBS analysis of geomaterials: Geochemical fingerprinting for the rapid analysis and discrimination of minerals. Applied Geochemistry, 24(6), 1125-1141. https://doi.org/https://doi.org/10.1016/j.apgeochem.2009.02.009
- Referans23
Harmon, R. S., Russo, R. E., & Hark, R. R. (2013). Applications of laser-induced breakdown spectroscopy for geochemical and environmental analysis: A comprehensive review. Spectrochimica Acta Part B: Atomic Spectroscopy, 87, 11-26.https://doi.org/10.1016/j.sab.2013.05.017
- Referans24
Kalam, S. A., Rao, S. B. M., Jayananda, M., & Rao, S. V. (2020). Standoff femtosecond filament-induced breakdown spectroscopy for classification of geological materials. Journal of Analytical Atomic Spectrometry, 35(12), 3007-3020.DOI https://doi.org/10.1039/D0JA00355G
- Referans25
Koh, Y., & Sárady, I. (2003). Cleaning of corroded iron artefacts using pulsed TEA CO2-and Nd: YAG-lasers. Journal of cultural heritage, 4, 129-133. https://doi.org/https://doi.org/10.1016/S1296-2074(02)01140-8
- Referans26
Korenberg, C., & Baldwin, A. (2006). Laser cleaning tests on archaeological copper alloys using an ND: YAG Laser. Laser Chemistry, 2006. https://doi.org/DOI: 10.1155/2006/75831
- Referans27
Korte, F., Serbin, J., Koch, J., Egbert, A., Fallnich, C., Ostendorf, A., & Chichkov, B. (2003). Towards nanostructuring with femtosecond laser pulses. Applied Physics A, 77(2), 229-235. https://doi.org/https://doi.org/10.1007/s00339-003-2110-z
- Referans28
Lasheras, R., Bello-Gálvez, C., & Anzano, J. (2010). Identification of polymers by libs using methods of correlation and normalized coordinates. Polymer testing, 29(8), 1057-1064.https://doi.org/10.1016/j.polymertesting.2010.07.011
- Referans29
Liu, X., Du, D., & Mourou, G. (1997). Laser ablation and micromachining with ultrashort laser pulses. IEEE journal of quantum electronics, 33(10), 1706-1716. https://doi.org/DOI: 10.1109/3.631270
- Referans30
Maharjan, N., Zhou, W., Zhou, Y., & Guan, Y. (2017). Femtosecond laser cleaning for aerospace manufacturing and remanufacturing. Lasers and Electro-Optics Pacific Rim (CLEO-PR), 2017 Conference on,
- Referans31
Muhammed Shameem, K. M., Dhanada, V. S., Harikrishnan, S., George, S. D., Kartha, V. B., Santhosh, C., & Unnikrishnan, V. K. (2020). Echelle LIBS-Raman system: A versatile tool for mineralogical and archaeological applications. Talanta, 208, 120482. https://doi.org/https://doi.org/10.1016/j.talanta.2019.120482
- Referans32
Nevin, A., Pouli, P., Georgiou, S., & Fotakis, C. (2007). Laser conservation of art. Nature Materials, 6(5), 320. https://doi.org/https://doi.org/10.1038/nmat1895
- Referans33
Palomar, T., Oujja, M., Llorente, I., Barat, B. R., Cañamares, M., Cano, E., & Castillejo, M. (2016). Evaluation of laser cleaning for the restoration of tarnished silver artifacts. Applied Surface Science, 387, 118-127. https://doi.org/https://doi.org/10.1016/j.apsusc.2016.06.017
- Referans34
Petiti, C., Toniolo, L., Gulotta, D., Mariani, B., & Goidanich, S. (2020). Effects of cleaning procedures on the long-term corrosion behavior of bronze artifacts of the cultural heritage in outdoor environment. Environmental Science and Pollution Research, 1-14. https://doi.org/https://doi.org/10.1007/s11356-020-07814-4
- Referans35
Pini, R., Siano, S., Salimbeni, R., Pasquinucci, M., & Miccio, M. (2000). Tests of laser cleaning on archeological metal artefacts. Journal of cultural heritage, 1, S129-S137. https://doi.org/https://doi.org/10.1016/S1296-2074(00)00139-4
- Referans36
Pouli, P., Oujja, M., & Castillejo, M. (2012). Practical issues in laser cleaning of stone and painted artefacts: optimisation procedures and side effects. Applied Physics A, 106(2), 447-464. https://doi.org/https://doi.org/10.1007/s00339-011-6696-2
- Referans37
Remus, J., Gottfried, J., Harmon, R., Draucker, A., Baron, D., & Yohe, R. (2010). Archaeological Applications of Laser-induced Breakdown Spectroscopy: An Example from the Coso Volcanic Field, California, Using Advanced Statistical Signal Processing Analysis. Applied Optics - APPL OPT, 49. https://doi.org/10.1364/AO.49.00C120
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