Research Article

Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺

Volume: 2026 Number: 2 August 11, 2026

Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺

Abstract

Heavy metal pollution, including Cu²⁺, Fe³⁺, and Pb²⁺ is a significant environmental concern due to their toxic nature, posing a risk to living organisms and the environment. Adsorption using bentonite as an adsorbent is an efficient approach for removing heavy metal pollutants from water. This study employs three forms of bentonite: natural bentonite, acid-activated bentonite, and acid-thermal activated bentonite. The activation process aims to enhance surface area, porosity, and the number of active sites while removing impurities from the bentonite surface. This research focuses on identifying the optimal pH for heavy metal adsorption using bentonite, and on comparing surface property changes between natural and activated bentonite using SEM-EDX. Adsorption was conducted using a multi-component aqueous solution containing Cu²⁺, Fe³⁺, and Pb²⁺ ions at pH levels of 3, 4, 5, 6, and 7. The findings revealed that acid-activated and acid-thermal activated bentonite exhibited more open and porous surface structures, as well as a greater number of active sites, compared to natural bentonite. Acid-thermal activated bentonite was the most effective adsorbent for removing heavy metals at pH 7 for Cu²⁺ and Pb²⁺. At pH 7, acid-activated bentonite was shown to be the most effective adsorbent for removing Fe³⁺ heavy metal ion.

Keywords

Supporting Institution

Sriwijaya University

Ethical Statement

The author declares that this article is original and has not been published before. All citations and references have been properly cited in accordance with academic ethics, and no plagiarism has been committed.

Thanks

The authors gratefully acknowledge the financial support for this research/publication provided by Universitas Sriwijaya. The funding was granted under the Rector's Decree Number: 029/UN9/LPPM.PT/2025, dated September 17, 2025.

References

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Details

Primary Language

English

Subjects

Chemical Engineering (Other)

Journal Section

Research Article

Publication Date

August 11, 2026

Submission Date

February 11, 2026

Acceptance Date

June 24, 2026

Published in Issue

Year 2026 Volume: 2026 Number: 2

APA
Nafisah Koenang, J., Agustina, T. E., Aprianti, T., Arita, S., Novia, N., & Fatimura, M. (2026). Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺. Journal of the Turkish Chemical Society Section A: Chemistry, 2026(2), 1-10. https://doi.org/10.18596/jotcsa.1884931
AMA
1.Nafisah Koenang J, Agustina TE, Aprianti T, Arita S, Novia N, Fatimura M. Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺. JOTCSA. 2026;2026(2):1-10. doi:10.18596/jotcsa.1884931
Chicago
Nafisah Koenang, Jilan, Tuty Emilia Agustina, Tine Aprianti, Susila Arita, Novia Novia, and Muhrinsyah Fatimura. 2026. “Optimization of PH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺”. Journal of the Turkish Chemical Society Section A: Chemistry 2026 (2): 1-10. https://doi.org/10.18596/jotcsa.1884931.
EndNote
Nafisah Koenang J, Agustina TE, Aprianti T, Arita S, Novia N, Fatimura M (August 1, 2026) Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺. Journal of the Turkish Chemical Society Section A: Chemistry 2026 2 1–10.
IEEE
[1]J. Nafisah Koenang, T. E. Agustina, T. Aprianti, S. Arita, N. Novia, and M. Fatimura, “Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺”, JOTCSA, vol. 2026, no. 2, pp. 1–10, Aug. 2026, doi: 10.18596/jotcsa.1884931.
ISNAD
Nafisah Koenang, Jilan - Agustina, Tuty Emilia - Aprianti, Tine - Arita, Susila - Novia, Novia - Fatimura, Muhrinsyah. “Optimization of PH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺”. Journal of the Turkish Chemical Society Section A: Chemistry 2026/2 (August 1, 2026): 1-10. https://doi.org/10.18596/jotcsa.1884931.
JAMA
1.Nafisah Koenang J, Agustina TE, Aprianti T, Arita S, Novia N, Fatimura M. Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺. JOTCSA. 2026;2026:1–10.
MLA
Nafisah Koenang, Jilan, et al. “Optimization of PH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 2026, no. 2, Aug. 2026, pp. 1-10, doi:10.18596/jotcsa.1884931.
Vancouver
1.Jilan Nafisah Koenang, Tuty Emilia Agustina, Tine Aprianti, Susila Arita, Novia Novia, Muhrinsyah Fatimura. Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺. JOTCSA. 2026 Aug. 1;2026(2):1-10. doi:10.18596/jotcsa.1884931