Optimization of pH in Heavy Metal Adsorption Using Natural and Activated Bentonite for Multi-Component Aqueous Solutions Containing Cu²⁺, Fe³⁺, and Pb²⁺
Abstract
Heavy metal pollution, including Cu²⁺, Fe³⁺, and Pb²⁺ is a significant environmental concern due to their toxic nature, posing a risk to living organisms and the environment. Adsorption using bentonite as an adsorbent is an efficient approach for removing heavy metal pollutants from water. This study employs three forms of bentonite: natural bentonite, acid-activated bentonite, and acid-thermal activated bentonite. The activation process aims to enhance surface area, porosity, and the number of active sites while removing impurities from the bentonite surface. This research focuses on identifying the optimal pH for heavy metal adsorption using bentonite, and on comparing surface property changes between natural and activated bentonite using SEM-EDX. Adsorption was conducted using a multi-component aqueous solution containing Cu²⁺, Fe³⁺, and Pb²⁺ ions at pH levels of 3, 4, 5, 6, and 7. The findings revealed that acid-activated and acid-thermal activated bentonite exhibited more open and porous surface structures, as well as a greater number of active sites, compared to natural bentonite. Acid-thermal activated bentonite was the most effective adsorbent for removing heavy metals at pH 7 for Cu²⁺ and Pb²⁺. At pH 7, acid-activated bentonite was shown to be the most effective adsorbent for removing Fe³⁺ heavy metal ion.
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References
- 1. Hussain S, Ali S. Removal of heavy metal by ion exchange using bentonite clay. J Ecol Eng. 2021 Jan 1;22(1):104–11. Available from:
. - 2. Rockson-Itiveh DE, Keke M, Fabian O, Tunde A. Bentonite clay as an alternative adsorbent for removal of heavy metals in wastewater. FUOYE J Eng Technol. 2023 Oct 2;8(3):360–4. Available from:
. - 3. Khan S, Ajmal S, Hussain T, Rahman MU. Clay-based materials for enhanced water treatment: Adsorption mechanisms, challenges, and future directions. J Umm Al-Qura Univ Appl Sci. 2025 Jun 16;11(2):219–34. Available from:
. - 4. Kandil AT, Ali MM, Mohamed HH, El Saadi AMK, Othman SA. Study of the adsorption of Pb(II), Cu(II), Fe(II) and Cd(II) by using modified natural clay. Nat Sci. 2017;15(4):78–83. Available from:
. - 5. Hodzic N, Dozic A, Sestan I, Alihodzic H. Examination of adsorption abilities of natural and acid activated bentonite for heavy metals removal from aqueous solutions. Int J Res Appl Sci Biotechnol. 2020 Jan 10;07(01):1–6. Available from:
. - 6. Bennour HAM. Effect of acid activation on adsorption of iron and manganese using Libyan bentonite clay. Chem Sci Trans. 2017 Apr 30;6(2):209–18. Available from:
. - 7. Berhe MT, Berhe GG, Cheru MS, Weldehans MG. Characterization of acid activation of bentonite clay of Hadar, Afar, Ethiopia. Bhoi NK, editor. Adv Mater Sci Eng. 2024 Jan 7;2024(1):6413786. Available from:
. - 8. Yıldız M. Activation conditions of Kutahya-Unye bentonite for removal of nickel from waste water. Eur J Sci Technol. 2019 Aug 31;16:229–34. Available from:
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Details
Primary Language
English
Subjects
Chemical Engineering (Other)
Journal Section
Research Article
Authors
Jilan Nafisah Koenang
0009-0003-2923-5516
Indonesia
Tuty Emilia Agustina
*
0000-0002-7289-7318
Indonesia
Tine Aprianti
0000-0003-0183-2557
Indonesia
Susila Arita
0000-0002-4286-9877
Indonesia
Novia Novia
0000-0002-0046-6076
Indonesia
Muhrinsyah Fatimura
0000-0003-1078-2803
Indonesia
Publication Date
August 11, 2026
Submission Date
February 11, 2026
Acceptance Date
June 24, 2026
Published in Issue
Year 2026 Volume: 2026 Number: 2
