Research Article

1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials

Volume: 2026 Number: 2 August 11, 2026

1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials

Abstract

This study presents the first systematic evaluation of 1-aryl-2-nitroethenes as antimicrobial additives in M-11 lubricating oils. A series of nine substituted derivatives (R = H, p-CH₃, p-OCH₃, o/p-F, o/p-Cl, o/p-OH) were synthesized via Henry condensation and characterized by FT-IR, ¹H NMR, and melting point analysis. Antimicrobial efficacy was assessed against Pseudomonas aeruginosa ATCC 27853, Bacillus subtilis ATCC 6633, Aspergillus niger ATCC 16404, and Penicillium chrysogenum ATCC 10106 using GOST 9.052-75 and GOST 9.082-77 protocols (n = 3, ANOVA, p < 0.05). Halogen-substituted derivatives (p-F, o-Cl) demonstrated superior activity (MIC 0.01–0.05% for bacteria; 0.01–0.025% for fungi), outperforming the commercial biocide 1,3-bis(2-hydroxyethyl)-1,3-diazacyclobutane (MIC 0.25–0.5%). Notably, 0.05% additive concentrations preserved the physicochemical properties of M-11 oil over 450 days, whereas untreated oil exhibited significant degradation. These results establish 1-aryl-2-nitroethenes as promising, cost-effective antimicrobial additives for industrial lubricants.

Keywords

References

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Details

Primary Language

English

Subjects

Physical Organic Chemistry

Journal Section

Research Article

Publication Date

August 11, 2026

Submission Date

May 15, 2026

Acceptance Date

July 5, 2026

Published in Issue

Year 2026 Volume: 2026 Number: 2

APA
Yusifova, A., Huseynova, M., Dadashova, T., Yusifzadeh, G., Ismayilov, R., Ismayilova, S., Mammadli, C., Abbasova, M., Akkurt, B., & Yalcin, B. (2026). 1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials. Journal of the Turkish Chemical Society Section A: Chemistry, 2026(2), 1-6. https://doi.org/10.18596/jotcsa.1952124
AMA
1.Yusifova A, Huseynova M, Dadashova T, et al. 1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials. JOTCSA. 2026;2026(2):1-6. doi:10.18596/jotcsa.1952124
Chicago
Yusifova, Aida, Mansura Huseynova, Tarana Dadashova, et al. 2026. “1-Aryl-2-Nitroethenes As Antimicrobial Additives for Lubricating Materials”. Journal of the Turkish Chemical Society Section A: Chemistry 2026 (2): 1-6. https://doi.org/10.18596/jotcsa.1952124.
EndNote
Yusifova A, Huseynova M, Dadashova T, Yusifzadeh G, Ismayilov R, Ismayilova S, Mammadli C, Abbasova M, Akkurt B, Yalcin B (August 1, 2026) 1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials. Journal of the Turkish Chemical Society Section A: Chemistry 2026 2 1–6.
IEEE
[1]A. Yusifova et al., “1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials”, JOTCSA, vol. 2026, no. 2, pp. 1–6, Aug. 2026, doi: 10.18596/jotcsa.1952124.
ISNAD
Yusifova, Aida - Huseynova, Mansura - Dadashova, Tarana - Yusifzadeh, Gulshan - Ismayilov, Rayyat - Ismayilova, Sabina - Mammadli, Chinara - Abbasova, Malakhat - Akkurt, Barbaros - Yalcin, Bahattin. “1-Aryl-2-Nitroethenes As Antimicrobial Additives for Lubricating Materials”. Journal of the Turkish Chemical Society Section A: Chemistry 2026/2 (August 1, 2026): 1-6. https://doi.org/10.18596/jotcsa.1952124.
JAMA
1.Yusifova A, Huseynova M, Dadashova T, Yusifzadeh G, Ismayilov R, Ismayilova S, Mammadli C, Abbasova M, Akkurt B, Yalcin B. 1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials. JOTCSA. 2026;2026:1–6.
MLA
Yusifova, Aida, et al. “1-Aryl-2-Nitroethenes As Antimicrobial Additives for Lubricating Materials”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 2026, no. 2, Aug. 2026, pp. 1-6, doi:10.18596/jotcsa.1952124.
Vancouver
1.Aida Yusifova, Mansura Huseynova, Tarana Dadashova, Gulshan Yusifzadeh, Rayyat Ismayilov, Sabina Ismayilova, Chinara Mammadli, Malakhat Abbasova, Barbaros Akkurt, Bahattin Yalcin. 1-Aryl-2-Nitroethenes as Antimicrobial Additives for Lubricating Materials. JOTCSA. 2026 Aug. 1;2026(2):1-6. doi:10.18596/jotcsa.1952124