Quinaldinium Chlorochromate(VI), (QnCC) Catalyzed Oxidation of Alcohols with Periodic Acid Under Solvent-Free Conditions and Microwave Irradition

Abstract

The economic synthesis of quinaldinium chlorochromate(VI), C₁₀H₉NH[CrO₃Cl], (QnCC) was performed by using a 1:1:1 stoichiometric amounts of CrO₃, HCl (aq) and quinaldine. QnCC was isolated in 99% yield as an orange crystalline solid and characterized with FT-IR, ¹H-NMR, and ¹³C-NMR. An efficient, selective, and environmentally friendly oxidation of alcohols with 1.1 equiv. periodic acid (H₅IO₆) catalyzed by QnCC (2 mol%) is described. The primary and secondary alcohols were oxidized to their corresponding aldehydes and ketones under solvent-free conditions at room temperature and MW irradiation in high to excellent yields.

Keywords

• alcohols,quinaldinium chlorochromate,periodic acid,solvent-free,microwave irradiation

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