SYNTHESIS AND CHARACTERIZATION OF CELLULOSE BASED BIO-POLYMER AEROGEL ISOLATED FROM WASTE OF BLUEBERRY TREE (VACCINIUM MYRTILLUS)

Year 2016, Volume: 3 Issue: 3, 765 - 776, 08.01.2017

Mehmet Kaya

https://doi.org/10.18596/jotcsa.57549

Cited By: 1

Abstract

Cellulose aerogel (CA) has highly porous structure, environmentally friendly, thermally stable and flame retardant properties. These properties in material worlds have attracted large interest as a potentially industrial material. In this paper, cellulose aerogel with flame retardant was produced from pruned branches and bushes of blueberries wastes (PBBW). Firstly, cellulose raw material these wastes was obtained and then, cellulose aerogel via freeze-drying, followed by cellulose hydrogel production. Our reports showed that three dimensionally network aerogel structure prepared from NaOH/Urea as scaffold solution. The present cellulose aerogel has excellent flame retardancy, which can extinguish within 140 s. By the way, it was inferred thermal stability performance of cellulose aerogel could be efficient potential thermal insulating material. Besides, this process are sustainable, easily available at low cost and suitable for industrial applications.

References

• REFERENCES
• Nishino T, Matsuda I, Hirao K. All-cellulose composite. Macromolecules. 2004;37(20):7683-7.
• Dormanns JW, Schuermann J, Mussig J, Duchemin BJC, Staiger MP. Solvent infusion processing of all-cellulose composite laminates using an aqueous NaOH/urea solvent system. Compos Part a-Appl S. 2016;82:130-40.
• Yang J, Zhang EW, Li XF, Zhang YT, Qu J, Yu ZZ. Cellulose/graphene aerogel supported phase change composites with high thermal conductivity and good shape stability for thermal energy storage. Carbon. 2016;98:50-7.
• Ahmadi M, Madadlou A, Sabouri AA. Isolation of micro- and nano-crystalline cellulose particles and fabrication of crystalline particles-loaded whey protein cold-set gel. Food Chem. 2015;174:97-103.
• Awal A, Sain M, Chowdhury M. Preparation of cellulose-based nano-composite fibers by electrospinning and understanding the effect of processing parameters. Compos Part B-Eng. 2011;42(5):1220-5.
• Duong HM, Nguyen ST. Nanocellulose Aerogels as Thermal Insulation Materials. In: Pacheco Torgal F, Buratti C, Kalaiselvam S, Granqvist C-G, Ivanov V, editors. Nano and Biotech Based Materials for Energy Building Efficiency. Cham: Springer International Publishing; 2016. p. 411-27.
• Postek MT, Vladar A, Dagata J, Farkas N, Ming B, Wagner R, et al. Development of the metrology and imaging of cellulose nanocrystals. Meas Sci Technol. 2011;22(2).
• Seantier B, Bendahou D, Bendahou A, Grohens Y, Kaddami H. Multi-scale cellulose based new bio-aerogel composites with thermal super-insulating and tunable mechanical properties. Carbohyd Polym. 2016;138:335-48.
• Kobayashi Y, Saito T, Isogai A. Aerogels with 3D Ordered Nanofiber Skeletons of Liquid-Crystalline Nanocellulose Derivatives as Tough and Transparent Insulators. Angew Chem Int Edit. 2014;53(39):10394-7.
• Liu J, Cheng F, Grenman H, Spoljaric S, Seppala J, Eriksson JE, et al. Development of nanocellulose scaffolds with tunable structures to support 3D cell culture. Carbohyd Polym. 2016;148:259-71.
• Shen XP, Shamshina JL, Berton P, Bandomir J, Wang H, Gurau G, et al. Comparison of Hydrogels Prepared with Ionic-Liquid-Isolated vs Commercial Chitin and Cellulose. Acs Sustain Chem Eng. 2016;4(2):471-80.
• Kwon GJ, Kim DY, Hwang JH, Kang JH. Structural properties and adsorption capacity of holocellulose aerogels synthesized from an alkali hydroxide-urea solution. J Korean Phys Soc. 2014;64(10):1470-3.
• Wang ZG, Liu SL, Matsumoto Y, Kuga S. Cellulose gel and aerogel from LiCl/DMSO solution. Cellulose. 2012;19(2):393-9.
• Beck-Candanedo S, Roman M, Gray DG. Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules. 2005;6(2):1048-54.
• Nguyen ST, Feng JD, Le NT, Le ATT, Hoang N, Tan VBC, et al. Cellulose Aerogel from Paper Waste for Crude Oil Spill Cleaning. Ind Eng Chem Res. 2013;52(51):18386-91.
• Han YY, Zhang XX, Wu XD, Lu CH. Flame Retardant, Heat Insulating Cellulose Aerogels from Waste Cotton Fabrics by in Situ Formation of Magnesium Hydroxide Nanoparticles in Cellulose Gel Nanostructures. Acs Sustain Chem Eng. 2015;3(8):1853-9.
• Jin H, Nishiyama Y, Wada M, Kuga S. Nanofibrillar cellulose aerogels. Colloid Surface A. 2004;240(1-3):63-7.
• Poletto M, Ornaghi HL, Zattera AJ. Native Cellulose: Structure, Characterization and Thermal Properties. Materials. 2014;7(9):6105-19.
• Zhang SQ, Wang J, Shen J, Deng ZS, Lai ZQ, Zhou B, et al. The investigation of the adsorption character of carbon aerogels. Nanostruct Mater. 1999;11(3):375-81.