pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties

Year 2020, Volume: 7 Issue: 1, 243 - 258, 15.02.2020

Burak Ay , Emel Yıldız , Jon Zubieta

https://doi.org/10.18596/jotcsa.565700

Cited By: 1

Abstract

Hydrothermal reactions of lanthanide(III) salt with
2,3-pyrazinedicarboxylic (2,3-pzdc) acid yielded the coordination polymers [La₂(2,3-pzdc)₃(H₂O)]_n.3nH₂O
(1) and [La₂(2,3-pzdc)₃(H₂O)]_n.2nH₂O
(2). 
Compounds
were obtained in a three dimensional form with different pH values under
subcritical water conditions. The structures had variable coordination numbers. In addition, pH values play an important role in
the structural chemistry of these materials. Different characterization techniques (Elemental
analysis, FT-IR, ICP-OES, TG/DTA, FESEM, PXRD, BET and single crystal X-ray)
were carried out to confirm crystallinity, porosity, purity and chemical
composition of the coordination polymers. Crystal structures of the polymers were
examined in detail. Their thermal stability, luminescence and electrical
conductivity properties were investigated in the solid state.

Keywords

pH effect, hydrothermal synthesis, lanthanum coordination polymer

Supporting Institution

ÇUKUROVA UNIVERSITY

Project Number

FEF2013D5

Thanks

The authors gratefully acknowledge financial support from the Research Unit of Çukurova University (Grant No. FEF2013D5).

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